Multicomponent fecosim soft magnetic alloy and preparation method thereof

Patent metadata

Field	Value
Publication number	US-2023203626-A1
Application number	US-202217683716-A
Country	US
Kind code	A1
Filing date	Mar 1, 2022
Priority date	Dec 27, 2021
Publication date	Jun 29, 2023
Grant date	—

Abstract

A multicomponent FeCoSiM soft magnetic alloy is provided. M of the alloy is one or more of V, Cr and Ni. A sum of atomic percentages of alloy elements in the alloy is 100%. The atomic percents of the alloy elements meet the following conditions: Fe, 68˜78 at %; Co, 4˜12 at %; Si, 14˜18 at %; V, 0˜4 at %; Cr, 0˜4 at %; and Ni, 0˜4 at %. The preparation method of the alloy includes weighing raw materials according to the atomic percentages of the alloy elements and then performing melting and annealing heat treatment each in vacuum or a protective atmosphere. The alloy is obtained by a reasonable design of compositions and contents. A magnetocrystalline anisotropy constant of the alloy is low, a magnetostrictive coefficient of the alloy approaches zero and the alloy has characteristics of high saturation flux density and low coercivity.

First claim

1 . (canceled)

2 . A preparation method of a multicomponent FeCoSiM soft magnetic alloy, comprising:
proportioning: selecting raw materials according to components of the multicomponent FeCoSiM soft magnetic alloy to obtain selected raw materials, cleaning the selected raw materials to obtain cleaned raw materials, and weighing the cleaned raw materials according to percentages of the components to obtain weighed raw materials, wherein the components of the multicomponent FeCoSiM soft magnetic alloy essentially consist of iron (Fe), cobalt (Co), silicon (Si) and a transition metal element M; melting: performing arc melting or induction melting to the weighed raw materials in vacuum or a protective atmosphere to obtain alloy ingots; and annealing: performing annealing heat treatment to the alloy ingots in vacuum or another protective atmosphere.

3 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 2 , wherein in the proportioning, each of the raw materials is a metal with a purity no less than 99.9% or a nonmetallic material with a purity no less than 99.9%.

4 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 2 , wherein the cleaning the selected raw materials comprises:
placing the selected raw materials in absolute ethanol or acetone to remove oil stains and organic matters on surfaces of the selected raw materials by an ultrasonic cleaning.

5 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 2 , wherein in the melting, an air pressure of the vacuum is less than 5×10 −3 pascals (Pa), and the protective atmosphere is an argon gas or a nitrogen gas with a purity no less than 99.9 volume percent (vol %).

6 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 2 , wherein in the melting, an electromagnetic stirring is used and each of the alloy ingots is melted repeatedly for 4˜6 times to reduce component segregation.

7 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 2 , wherein the annealing comprises: performing the annealing heat treatment to the alloy ingots at 700 Celsius degrees (° C.)˜900° C. for 1 hour (h)˜3 h and then cooling with a furnace.

8 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 2 , wherein in the annealing, an air pressure of the vacuum is less than 5×10 −3 Pa and the protective atmosphere is a mixture gas of an argon gas or a nitrogen gas with a purity no less than 99.9 vol % and a hydrogen gas of 5˜10 vol %.

9 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 2 , wherein the transition metal element M is one or more selected from the group consisting of vanadium (V), chromium (Cr) and nickel (Ni).

10 . The preparation method of the multicomponent FeCoSiM soft magnetic alloy according to claim 9 , wherein the percentages of respective components of the multicomponent FeCoSiM soft magnetic alloy meet the following conditions:
Fe, 68˜78 atomic percent (at %); Co, 4˜12 at %; Si, 14˜18 at %; V, 0˜4 at %; Cr, 0˜4 at %; and

Assignees

• Univ Zhejiang

Inventors

• Yan Mi
• Wu Chen
• Chen Qiming
• Jin Jiaying
• Jiang Yinzhu

Classifications

• C22C38/34 Primary

  with more than 1.5% by weight of silicon · CPC title

• C22C2202/02

  Magnetic · CPC title

• C22C38/46

  with vanadium · CPC title

• C22C38/52

  with cobalt · CPC title

• H01F1/14766 Primary

  Fe-Si based alloys · CPC title