Method for in-situ synthesis of tungsten carbide powder

Patent metadata

Field	Value
Publication number	US-2023193488-A1
Application number	US-202318168819-A
Country	US
Kind code	A1
Filing date	Feb 14, 2023
Priority date	Mar 10, 2021
Publication date	Jun 22, 2023
Grant date	—

Abstract

The present disclosure provides a method for in-situ synthesizing tungsten carbide powder. In this method, cemented carbide scrap is used as an electrode and the molten salt electrolysis process is used to in-situ synthesize tungsten carbide powder, where a bidirectional pulse is used in the molten salt electrolysis process. In the method provided by the present disclosure, by using the bidirectional pulse and using the cemented carbide scrap as electrode in the molten salt medium, when the tungsten carbide scrap is oxidized, tungsten is dissolved in ionic form, deposited after the direction of current changes, and reacted with the carbon anode sludge in situ to generate tungsten carbide powder. In the present disclosure, the carbon anode sludge is treated appropriately, the recycled product can be used in upmarket application, there is no need to apply complicated processes to process the tungsten powder into tungsten carbide, and the tungsten carbide nanopowder with high-performance can be recycled and prepared in a short process.

First claim

What is claimed is:

1 . A method for in-situ synthesizing tungsten carbide powder, comprising:
using at least one cemented carbide scrap as an electrode, and in-situ synthesizing tungsten carbide powder by a molten salt electrolysis process, wherein bidirectional pulse is used to electrolyse in a molten salt electrolysis process.

2 . The method for in-situ synthesizing tungsten carbide powder according to claim 1 , wherein a ratio of a height of a forward pulse to a height of a reverse pulse is 1:1 and a ratio of time of the forward pulse to time of the reverse pulse is 1:1.

3 . The method for in-situ synthesizing tungsten carbide powder according to claim 2 , wherein the height of the forward pulse is 150-250 mA and the time of the forward pulse is 30-50 s.

4 . The method for in-situ synthesizing tungsten carbide powder according to claim 1 , wherein in the molten salt electrolysis process, molten salt of fluoride and/or chloride is used as an electrolyte.

5 . The method for in-situ synthesizing tungsten carbide powder according to claim 4 , wherein the molten salt comprises a mixture of NaF and KF.

6 . The method for in-situ synthesizing tungsten carbide powder according to claim 1 , wherein the at least cemented carbide scrap includes two separate cemented carbide scrap as two electrodes.

7 . The method for in-situ synthesizing tungsten carbide powder according to claim 1 , wherein a purity of the tungsten carbide powder is more than 99%.

8 . The method for in-situ synthesizing tungsten carbide powder according to claim 1 , wherein the tungsten carbide powder has a particle size in a range of from about 1 nm to about 1,000 nm.

9 . The method for in-situ synthesizing tungsten carbide powder according to claim 1 , wherein the tungsten carbide powder has a particle size in a range of from about 80 nm to about 100 nm.

10 . The method for in-situ synthesizing tungsten carbide powder according to claim 2 , wherein a purity of the tungsten carbide powder is more than 99%.

11 . The method for in-situ synthesizing tungsten carbide powder according to claim 3 , wherein a purity of the tungsten carbide powder is more than 99%.

12 . The method for in-situ synthesizing tungsten carbide powder according to claim 4 , wherein a purity of the tungsten carbide powder is more than 99%.

Assignees

• Univ Beijing Technology

Inventors

• Xi Xiaoli
• Zhang Liwen
• Nie Zuoren

Classifications

• C01B32/949 Primary

  Tungsten or molybdenum carbides · CPC title

• C25B1/01

  Products · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• C25B11/042 Primary

  Electrodes formed of a single material · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title