Liquid crystal composition, optical element, and light guide element

Patent metadata

Field	Value
Publication number	US-2023124399-A1
Application number	US-202218065339-A
Country	US
Kind code	A1
Filing date	Dec 13, 2022
Priority date	Jun 19, 2020
Publication date	Apr 20, 2023
Grant date	—

Abstract

A liquid crystal composition includes: at least one of a compound represented by Formula (I) or a compound represented by Formula (II); and a rod-like liquid crystal compound having a polymerizable group that does not correspond to both of Formula (I) and Formula (II)

First claim

What is claimed is:

1 . A liquid crystal composition comprising:
at least one of a compound represented by Formula (I) or a compound represented by Formula (II); and a rod-like liquid crystal compound having a polymerizable group that does not correspond to both of Formula (I) and Formula (II),

in Formula (I),
P 1 and P 2 each independently represent a hydrogen atom or a substituent,
S 1 and S 2 each independently represent a single bond or a divalent linking group,
A 1 , A 2 , A 3 , and A 4 each independently represent a non-aromatic ring, an aromatic ring, or an aromatic heterocycle which may have a substituent,
in a case where a plurality of A 1 's are present, the plurality of A 1 's may be the same as or different from each other, and in a case where a plurality of A 4 's are present, the plurality of A 4 's may be the same as or different from each other,
Y 1 and Y 2 each independently represent —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —CH═CH—COO—, —CH═CH—OCO—, —COO—CH═CH—, —OCO—CH═CH—, —CH═CH—, —N═N—, —CH═N—N═CH—, —CF═CF—, —C≡C—, or a single bond,
in a case where a plurality of Y 1 's are present, the plurality of Y 1 's may be the same as or different from each other, and in a case where a plurality of Y 2 's are present, the plurality of Y 2 's may be the same as or different from each other,
m1 and m2 each independently represent an integer of 0 to 5,
Z represents a linear or branched alkylene group,
the number of atoms in a bond where A 2 and A 3 are bonded by a shortest distance is 3 or 5 or more, and one —CH 2 — or two or more non-adjacent —CH 2 —'s that form the alkylene group may be substituted with —O—, —COO—, —OCO—, —OCOO—, —NRCO—, —CONR—, —NRCOO—, —OCONR—, —CO—, —S—, —SO 2 —, —NR—, —NRSO 2 —, or —SO 2 NR—, and
R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms,

in Formula (II),
P 3 and P 4 each independently represent a hydrogen atom or a substituent,
S 3 and S 4 each independently represent a single bond or a divalent linking group,
A 5 and A 6 each independently represent a non-aromatic ring, an aromatic ring, or an aromatic heterocycle which may have a substituent,
in a case where a plurality of A 5 's are present, the plurality of A 5 's may be the same as or different from each other, and in a case where a plurality of A 6 's are present, the plurality of A 6 's may be the same as or different from each other,
Y 3 and Y 4 each independently represent —O—, —S—, —OCH 2 —, —CH 2 O—, —CH 2 CH 2 —, —CO—, —COO—, —OCO—, —CO—S—, —S—CO—, —O—CO—O—, —CO—NH—, —NH—CO—, —SCH 2 —, —CH 2 S—, —CF 2 O—, —OCF 2 —, —CF 2 S—, —SCF 2 —, —CH═CH—COO—, —CH═CH—OCO—, —COO—CH═CH—, —OCO—CH═CH—, —COO—CH 2 CH 2 —, —OCO—CH 2 CH 2 —, —CH 2 CH 2 —COO—, —CH 2 CH 2 —OCO—, —COO—CH 2 —, —OCO—CH 2 —, —CH 2 —COO—, —CH 2 —OCO—, —CH═CH—, —N═N—, —CH═N—N═CH—, —CF═CF—, —C≡C—, or a single bond,
in a case where a plurality of Y 3 's are present, the plurality of Y 3 's may be the same as or different from each other, and in a case where a plurality of Y 4 's are present, the plurality of Y 4 's may be the same as or different from each other,
m3 and m4 each independently represent an integer of 1 to 5, and
B represents any one of groups represented by Formulas (B-1) to (B-11) which may have a substituent,

a carbon atom in Formulas (B-1) to (B-11) may be substituted with a nitrogen atom, an oxygen atom, or a sulfur atom,
X in Formulas (B-4) to (B-8), (B-10), and (B-11) represents a nitrogen atom, an oxygen atom, or a sulfur atom, two X's in Formula (B-5) may each independently represent the same atom or different atoms, and two X's in Formula (B-6) may each independently represent the same atom or different atoms, and
in a case where B represents a group represented by Formula (B-11), both Y 3 and Y 4 bonded to B represent a single bond.

2 . The liquid crystal composition according to claim 1 ,
wherein at least one of P 1 or P 2 in Formula (I) represents a polymerizable group.

3 . The liquid crystal composition according to claim 1 ,
wherein at least one of P 3 or P 4 in Formula (II) represents a polymerizable group.

4 . The liquid crystal composition according to claim 1 ,
wherein a total content of the compound represented by Formula (I) and the compound represented by Formula (II) is 50 mass % or less with respect to the mass of the rod-like liquid crystal compound.

5 . The liquid crystal composition according to claim 1 ,
wherein a difference Δn 550 in refractive index generated by refractive index anisotropy of the liquid crystal composition is 0.2 or more.

6 . The liquid crystal composition according to claim 1 ,
wherein a phase transition temperature between a liquid crystal phase and an isotropic phase is 50° C. or higher.

7 . An optical element comprising:
an optically-anisotropic layer that is formed of the liquid crystal composition according to claim 1 , wherein the optically-anisotropic layer has a liquid crystal alignment pattern in which a direction of an optical axis derived from a rod-like liquid crystal compound in the liquid crystal composition changes while continuously rotating in at least one in-plane direction.

8 . The optical element according to claim 7 ,
wherein the directions of the optical axes in the optically-anisotropic layer match each other in a thickness direction.

9 . The optical element according to claim 7 ,
wherein the optically-anisotropic layer has a region where the direction of the optical axis is twisted in the thickness direction and rotates.

10 . The optical element according to claim 7 ,
wherein in a case where a length over which the direction of the optical axis rotates by 180° in a plane is set as a single period, the optically-anisotropic layer has regions having different lengths of the single periods in the liquid crystal alignment pattern.

11 . The optical element according to claim 7 ,
wherein the single period in the liquid crystal alignment pattern gradually decreases in the one in-plane direction in which the direction of the optical axis changes while continuously rotating in the liquid crystal alignment pattern.

12 . The optical element according to claim 7 ,
wherein the liquid crystal alignment pattern of the optically-anisotropic layer is a concentric circular pattern having a concentric circular shape where the one in-plane direction in which the direction of the optical axis changes while continuously rotating moves from an inner side toward an outer side.

13 . A light guide element comprising:
the optical element according to claim 7 ; and a light guide plate.

Assignees

• Fujifilm Corp

Inventors

• Fukushima Yuki
• Kodama Keisuke
• Ichihashi Mitsuyoshi
• Katoh Shunya
• Saitoh Yukito
• Yonemoto Takashi
• Sato Hiroshi

Classifications

• C08F20/30 Primary

  containing aromatic rings in the alcohol moiety · CPC title

• C09D129/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C08F216/06

  Polyvinyl alcohol {; Vinyl alcohol} · CPC title

• G02B5/3016 Primary

  involving passive liquid crystal elements (optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528) · CPC title

• G02F1/1337

  Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers · CPC title