Method for treating alloy

Patent metadata

Field	Value
Publication number	US-2023071697-A1
Application number	US-202117797212-A
Country	US
Kind code	A1
Filing date	Feb 10, 2021
Priority date	Feb 21, 2020
Publication date	Mar 9, 2023
Grant date	—

Abstract

Provided is a method for treating an alloy by which nickel and/or cobalt can be selectively isolated from an alloy that contains copper as well as nickel and/or cobalt, in a waste lithium ion battery. The present invention is a method for treating an alloy, by which a solution that contains nickel and/or cobalt is obtained from an alloy that contains copper as well as nickel and/or cobalt, the method including: a leaching step in which a leachate is obtained by subjecting an alloy to an acid-based leaching treatment under conditions in which a sulfurizing agent is also present; a reduction step in which a reduced solution is obtained by subjecting the leachate to a reduction treatment using a reducing agent; and an oxidation/neutralization step in which a solution that contains nickel and/or cobalt is obtained by adding an oxidizing agent and also a neutralizing agent to the reduced solution.

First claim

1 . An alloy processing method for producing a nickel- and/or cobalt-containing solution from an alloy comprising copper and nickel and/or cobalt, the method comprising:
a leaching step that comprises subjecting the alloy to a leaching treatment with an acid in the presence of a sulfurizing agent to produce a leachate; a reduction step that comprises subjecting the leachate to a reduction treatment with a reducing agent to produce a reduced solution; and an oxidation and neutralization step that comprises adding an oxidizing agent and a neutralizing agent to the reduced solution to produce a solution containing nickel and/or cobalt.

2 . The alloy processing method according to claim 1 , wherein the alloy is a product obtained through melting a discarded lithium ion battery.

3 . The alloy processing method according to claim 1 , wherein the alloy is in the form of a powder.

4 . The alloy processing method according to claim 1 , wherein the reducing agent used in the reduction step is a metallic material comprising nickel and/or cobalt, and the reduction treatment comprises bringing the leachate into contact with the metallic material.

5 . The alloy processing method according to claim 1 , wherein the oxidation and neutralization step comprises
adding the oxidizing agent and the neutralizing agent simultaneously to the reduced solution or adding the oxidizing agent to the reduced solution and then adding the neutralizing agent to the mixture.

6 . The alloy processing method according to claim 1 , wherein the leaching step comprises performing the leaching treatment at an oxidation-reduction potential being controlled within a range of 240 mV or more and 300 mV or less with respect to a silver-silver chloride electrode as a reference electrode during the leaching treatment with an acid solution.

7 . The alloy processing method according to claim 6 , wherein the leaching step comprises adding an oxidizing agent to control the oxidation-reduction potential.

8 . The alloy processing method according to claim 1 , wherein the leaching step comprises performing the leaching treatment at a pH being controlled within a range of 0.8 or more and 2.0 or less using an acid solution.

9 . The alloy processing method according to claim 8 , wherein the acid solution used in the leaching step is a sulfuric acid-containing solution.

10 . The alloy processing method according to claim 1 , wherein the leaching step comprises performing the leaching treatment with an acid solution at a leaching temperature being controlled within a range of 50° C. or more and 80° C. or less.

11 . The alloy processing method according to claim 1 , wherein the alloy is in the form of particles with a particle size of less than 500 μm.

12 . The alloy processing method according to claim 11 , wherein the alloy is in the form of an atomized powder resulting from an atomization process.

13 . The alloy processing method according to claim 11 , wherein the alloy is in the form of a powder with a particle size of less than 150 μm.

14 . The alloy processing method according to claim 1 , wherein the alloy contains zinc,
the method further comprising a zinc removal step that comprises subjecting a post-neutralization solution resulting from the oxidation and neutralization step to an ion-exchange treatment or a solvent extraction treatment to remove the zinc.

15 . The alloy processing method according to claim 1 , wherein the alloy is in the form of an atomized powder obtained through a pyrometallurgical process comprising:
introducing a discarded lithium ion battery into a roasting furnace to produce an oxidatively roasted product; introducing the oxidatively roasted product and a reducing agent into a reduction furnace for reductive melting to produce a molten metallic material and a reduced slag; and
subjecting the molten metallic material to an atomization process to solidify the molten metallic material into a fine powder.

16 . The alloy processing method according to claim 2 , wherein the alloy is in the form of a powder.

17 . The alloy processing method according to claim 2 , wherein the reducing agent used in the reduction step is a metallic material comprising nickel and/or cobalt, and the reduction treatment comprises bringing the leachate into contact with the metallic material.

18 . The alloy processing method according to claim 3 , wherein the reducing agent used in the reduction step is a metallic material comprising nickel and/or cobalt, and the reduction treatment comprises bringing the leachate into contact with the metallic material.

19 . The alloy processing method according to claim 2 , wherein the oxidation and neutralization step comprises
adding the oxidizing agent and the neutralizing agent simultaneously to the reduced solution or adding the oxidizing agent to the reduced solution and then adding the neutralizing agent to the mixture.

20 . The alloy processing method according to claim 3 , wherein the oxidation and neutralization step comprises
adding the oxidizing agent and the neutralizing agent simultaneously to the reduced solution or adding the oxidizing agent to the reduced solution and then adding the neutralizing agent to the mixture.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Takenouchi Hiroshi
• Asano Satoshi
• HEGURI Shin-ichi
• Shouji Hirofumi
• Kudou Keiji
• Matsuoka Itsumi
• Sanjo Shota
• MATSUGI Takumi

Classifications

• H01M10/54

  Reclaiming serviceable parts of waste accumulators · CPC title

• B22F9/08

  by casting, e.g. through sieves or in water, by atomising or spraying (using electric discharge B22F9/14) · CPC title

• C22B1/02

  Roasting processes (C22B1/16 takes precedence) · CPC title

• C22B15/00

  Obtaining copper · CPC title

• C22B23/02

  by dry processes · CPC title