Liquid-liquid extraction unit, multistage liquid-liquid extraction apparatus using the unit, and multistage continuous extraction system for rare earth elements

Patent metadata

Field	Value
Publication number	US-2016304986-A1
Application number	US-201615195382-A
Country	US
Kind code	A1
Filing date	Jun 28, 2016
Priority date	Jan 13, 2012
Publication date	Oct 20, 2016
Grant date	—

Abstract

A liquid-liquid extraction unit includes an extraction/separation tank ( 10 ) into which an aqueous phase in bubble form is admitted from an upper inlet ( 20 ) in one sidewall and an organic phase in bubble form is admitted from a lower inlet ( 30 ) in the one sidewall. The upward moving organic phase is contacted with the downward moving aqueous phase. After contact, the organic phase is discharged through an upper outlet ( 40 ) in an opposite sidewall and the aqueous phase is discharged through a lower outlet ( 50 ) in the opposite sidewall.

First claim

1 . A method of liquid-liquid extraction of a substance, comprising:
contacting an aqueous phase and an organic phase to each other in a tank by introducing aqueous phase into an upper portion of one sidewall of the tank, and introducing organic phase into a lower portion of one sidewall of the tank, wherein at least one of the aqueous phase and the organic phase is introduced in bubble form, the organic phase moves from the lower portion to the upper portion contacting with the aqueous phase, the aqueous phase moving from the upper portion to the lower portion contacting with the organic phase, thereby transferring the substance between the aqueous phase and the organic phase, the aqueous phase and the organic phase move horizontally while exchanging their position upward and downward, separating the aqueous phase and the organic phase by discharging the organic phase from the upper portion of the opposite sidewall of the tank, and discharging the aqueous phase from the lower portion of the opposite sidewall of the tank.

2 . The method of claim 1 , wherein at least one of the aqueous phase and the organic phase is introduced in bubble form through a spray nozzle.

3 . The method of claim 1 , further comprising recovering the substance from the organic phase discharged from the tank.

4 . The method of claim 1 , further comprising recovering the substance from the aqueous phase discharged from the tank.

5 . The method of claim 3 , further comprising recycling the organic phase after recovering the substance.

6 . The method of claim 4 , further comprising recycling the aqueous phase after recovering the substance.

7 . The method of claim 5 , wherein at least the contacting step is repeated before recovering the substance.

8 . The method of claim 6 , wherein at least the contacting step is repeated before recovering the substance.

9 . The method of claim 1 , wherein the tank comprises a partition disposed between horizontally opposed sidewalls thereby dividing the tank into a contact compartment and a separation/recovery compartment,
the aqueous phase and the organic phase are introduced into the contact compartment, the organic phase and the aqueous phase are discharged from the separation/recovery compartment, and the contact compartment and the separation/recovery compartment communicate each other in the upper portion and the lower portion providing fluid communication for the aqueous phase and the organic phase.

10 . The method of claim 1 , wherein the tank is a parallelepiped tank having a rectangular bottom and a pair of longitudinally opposed sidewalls as the pair of horizontally opposed sidewalls.

11 . A method of continuous extraction for extracting a rare earth element, comprising:
extracting at least one rare earth element by contacting an organic phase containing an extractant with a first aqueous phase in the form of an aqueous solution containing rare earth elements, and separating the first aqueous phase and the organic phase; back-extracting the rare earth element into a second aqueous phase for recovery by contacting the organic phase having the rare earth element extracted from the first aqueous phase with the second aqueous phase in the form of an acid aqueous solution and separating the second aqueous phase and the organic phase, wherein the organic phase after back-extracting is fed back to the extracting step, one or both of the extracting step and the back-extracting step is carried out by repeating the method of claim 1 .

12 . The method of claim 11 , wherein the rare earth element which remains in the first aqueous phase without being extracted into the organic phase is further recovered from the aqueous phase after extraction.

13 . A method of liquid-liquid extraction of rare earth element, comprising:
extracting a first rare earth element into an organic phase by contacting a first aqueous phase containing rare earth elements with the organic phase containing an extractant, and separating the organic phase and the first aqueous phase, a back-extracting the first rare earth element into a second aqueous phase by contacting the organic phase having the first rare earth element extracted therein with a second aqueous phase in the form of an acid aqueous solution and separating the organic phase and the second aqueous phase, and between the extracting step and the back-extracting step, scrubbing the organic phase to extract a second rare earth element, which is incidentally contained in the organic phase and should have remained in the first aqueous phase, into the second aqueous phase, by contacting the organic phase with a third aqueous phase in the form of an acid aqueous solution, and separating them, and delivering the organic phase after scrubbing to the back-extraction section, wherein the third aqueous phase having the second rare earth element extracted from the organic phase in the scrubbing step is fed back to the extracting step, the organic phase after back-extracting is fed back to the extraction step, the first aqueous phase discharged from the extracting step is recovered for thereby recovering a third rare earth element remaining in the first aqueous phase without being extracted into the organic phase, and at least one of the extracting step, the back-extracting step and the scrubbing step is carried out by repeating the method of claim 1 .

Assignees

• Shinetsu Chemical Co

Inventors

• Sugahara Hiroto
• Minowa Takehisa

Classifications

• B01D11/04

  of solutions which are liquid · CPC title

• B01D2011/002

  Counter-current extraction · CPC title

• C22B59/00

  Obtaining rare earth metals · CPC title

• B01D11/0449 Primary

  with stationary contacting elements · CPC title

• C22B3/0005 Primary

  Chemistry & Metallurgy · mapped topic