Method for recycling li-ion batteries

Patent metadata

Field	Value
Publication number	US-2022411896-A1
Application number	US-202017754586-A
Country	US
Kind code	A1
Filing date	Oct 5, 2020
Priority date	Oct 10, 2019
Publication date	Dec 29, 2022
Grant date	—

Abstract

A method for recycling a battery including the following steps: a) dissolution of a battery waste, for example an electrode, including lithium and a metal selected from cobalt and manganese, such that a solution to be treated containing lithium ions and metal ions is formed, b) addition of a peroxymonosulfate salt to the solution to be treated, the solution to be treated being regulated at a pH ranging from 1 to 4 when the metal is cobalt or at a pH ranging from 0.1 to 2.5 when the metal is manganese, such that the metal ions are selectively precipitated in the form of metal oxyhydroxide, c) separation of the lithium ions from the solution to be treated. Advantageously, the solution further comprises nickel ions.

First claim

What is claimed is:

1 .- 10 . (canceled)

11 . A method for recycling a battery including the following steps:
a) dissolution of a battery waste, including lithium and a metal selected from cobalt and manganese, such that a solution to be treated containing lithium ions and metal ions is formed, b) addition of a peroxymonosulfate salt to the solution to be treated, the solution to be treated being regulated at a pH ranging from 1 to 4 when the metal is cobalt or at a pH ranging from 0.1 to 2.5 when the metal is manganese, such that the metal ions are selectively precipitated in the form of metal oxyhydroxide, c) separation of the lithium ions from the solution to be treated.

12 . The method according to claim 11 , wherein the battery waste includes both cobalt and manganese.

13 . The method according to claim 12 , wherein step b) is repeated twice: one time to selectively make the manganese ions precipitate and the other time to selectively make the cobalt ions precipitate.

14 . The method according to claim 13 , wherein it includes the following successive steps:
step a), a step during which the pH of the solution to be treated in increased and set between 7 and 10, by addition of a base such as NaOH, NH 4 OH or Na 2 CO 3 , such that a precipitate comprising cobalt and manganese is formed, step c), dissolution of the precipitate comprising cobalt and manganese, implementation of step b) by addition of a peroxymonosulfate salt at a pH ranging from 0.1 to 2.5 to selectively make the manganese ions precipitate in the form of manganese oxyhydroxide, implementation of step b) by addition of a peroxymonosulfate salt at a pH ranging from 1 to 4 to selectively make the cobalt ions precipitate in the form of cobalt oxyhydroxide.

15 . The method according to claim 11 , wherein the battery waste further includes nickel, the dissolution of the battery waste leading to the formation of nickel ions.

16 . The method according to claim 15 , wherein the method includes a step during which the pH is increased between 7 and 10, by addition of a base such as NaOH, NH 4 OH or Na 2 CO 3 , such that the nickel ions are precipitated.

17 . The method according to claim 16 , wherein the base is NaOH, NH 4 OH or Na 2 CO 3 .

18 . The method according to claim 11 , wherein the temperature ranges from 20° C. to 95° C.

19 . The method according to claim 18 , wherein the temperature ranges from 40° C. to 80° C.

20 . The method according to claim 11 , wherein the peroxymonosulfate salt is potassium peroxymonosulfate.

21 . The method according to claim 11 , wherein the peroxymonosulfate salt is potassium peroxymonosulfate triple salt.

22 . The method according to claim 11 , wherein step c) is carried out by adding carbonate or with a resin.

23 . The method according to claim 11 , wherein the battery waste is a nickel-manganese-cobalt electrode.

24 . The method according to claim 11 , wherein the battery waste is an electrode.

Assignees

• Commissariat Energie Atomique

Inventors

• Billy Emmanuel
• Barthelemy Sandrine

Classifications

• C22B23/0461

  by chemical methods · CPC title

• C22B47/00 Primary

  Obtaining manganese · CPC title

• C22B26/12

  Obtaining lithium · CPC title

• H01M10/54

  Reclaiming serviceable parts of waste accumulators · CPC title

• C22B7/006 Primary

  Wet processes · CPC title