Method and apparatus for recycling lithium iron phosphate batteries

Patent metadata

Field	Value
Publication number	US-10741890-B2
Application number	US-201815976981-A
Country	US
Kind code	B2
Filing date	May 11, 2018
Priority date	Apr 4, 2012
Publication date	Aug 11, 2020
Grant date	Aug 11, 2020

Abstract

Cathode material from exhausted lithium ion batteries are dissolved in a solution for extracting the useful elements Co (cobalt), Ni (nickel), Al (Aluminum) and Mn (manganese) to produce active cathode materials for new batteries. The solution includes compounds of valuable charge materials such as cobalt, nickel, aluminum and manganese dissolved as compounds from the exhausted cathode material of spent cells. However, LiFePO4 is a waste stream charge material often discarded due to infeasibility of recycling. LiFePO4 is precipitated as FePO4 and remains as a by-product, along with graphite and carbon, which are not dissolved into the solution. FePO4 can be separated from graphite and carbon, FePO4 can be used to synthesize LiFePO4 as cathode materials and graphite can be regenerated as anode materials.

First claim

What is claimed is:

1. In a battery recycling process for acidic leaching of charge materials from a waste stream of crushed and shredded battery contents, aA method for recycling lithium iron phosphate from residual iron phosphate after acidic leaching, comprising:
removing solid battery components including casing and electrode materials from exhausted lithium ion batteries (LIBs) by physical separation from an acidic leach solution resulting in a granular mass of exhausted charge materials including carbon, graphite and iron phosphate;
adding hydrochloric acid to the granular mass to separate graphite and carbon from the iron phosphate to yield a solution of iron chloride and phosphoric acid with undissolved carbon and graphite;
adjust the pH of the solution of iron chloride and phosphoric acid to precipitate iron phosphate;
combining and agitating lithium carbonate with the precipitated iron phosphate; and
sintering the combined and agitated lithium carbonate and iron phosphate to yield cathode powder.

2. The method of claim 1 further comprising sintering the combined mixture to generate LiFePO 4 .

3. The method of claim 1 further comprising precipitating the iron phosphate by circulating and heating a reactor containing the iron chloride and phosphoric acid solution to precipitate iron phosphate in a powder form.

4. The method of claim 1 further comprising combining a carbon source and lithium carbonate with the precipitated iron phosphate, the carbon source including at least glucose or sucrose.

5. The method of claim 4 further comprising adding the carbon source in an amount based on 20% by weight of the iron phosphate.

6. The method of claim 1 wherein the hydrochloric acid acid is 5M hydrochloric acid.

7. The method of claim 1 further comprising adding ammonium hydroxide to the solution of iron chloride and phosphoric acid for maintaining the pH substantially at 2 .

8. The method of claim 7 further comprising controlling the pH in a range between 1.5-4.5.

9. The method of claim 1 further comprising adding a stoichiometric amount of lithium carbonate to the yield the lithium iron phosphate.

10. The method of claim 1 further comprising acid leaching charge material compounds other than iron phosphate from the granular mass prior to adding the inorganic acid.

11. The method of claim 1 further comprising adjusting the pH by adding ammonium hydroxide or sodium hydroxide.

12. A method for recycling lithium iron phosphate batteries, comprising
removing solid battery components including casing and electrode materials from exhausted lithium ion batteries (LIBs) by physical separation resulting in a granular mass, the granular mass having exhausted charge materials including carbon, graphite and residual cathode materials;
adding a first inorganic acid to the granular mass for leaching charge materials other than iron phosphate from the exhausted charge materials;
directing a first leach solution resulting from the leached charge materials to a recycling stream;
adding hydrochloric acid to the granular mass remaining after directing the first leach solution to the recycling stream to generate a second leach solution including iron chloride and phosphoric acid;
adjusting the pH of the generated leach solution to precipitate iron phosphate for adding lithium carbonate and sintering for forming lithium iron phosphate.

13. The method of claim 12 wherein the first inorganic acid is sulfuric acid, and the leached charge materials include nickel, manganese and cobalt.

14. The method of claim 12 wherein the physical separation includes:
agitation and crushing to separate casing and containment materials;
sorting and magnetic separation to remove casing and current collector metals from the charge material.

15. The method of claim 12 further comprising removing exhausted charge materials including nickel, manganese and cobalt from dissolution in the leached charge materials.

16. The method of claim 12 further comprising forming the first leach solution by adding an inorganic acid to crushed battery materials defining the granular mass to form a leach solution including compounds of nickel, manganese and cobalt reacted with the inorganic acid.

17. The method of claim 16 further comprising processing the leach solution for forming a parallel recycling stream for recycling the leached charge materials.

18. The method of claim 12 wherein the first inorganic acid dissolves at least one of nickel, manganese and cobalt charge materials and is substantially nonreactive with the iron phosphate.

Assignees

• Worcester Polytech Inst

Inventors

• Wang Yan
• Ma Xiaotu

Classifications

• C01B25/45 Primary

  containing plural metal, or metal and ammonium · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• C22B3/02

  Apparatus therefor · CPC title

• H01M4/5825

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title