Diagnosis of Cause of Degradation of Lithium Secondary Battery

Patent metadata

Field	Value
Publication number	US-2022393257-A1
Application number	US-202117641225-A
Country	US
Kind code	A1
Filing date	Apr 28, 2021
Priority date	May 27, 2020
Publication date	Dec 8, 2022
Grant date	—

Abstract

Provided is a method of diagnosing the degradation of a lithium secondary battery in a non-destructive manner without disassembling the battery, which includes: obtaining, from X-ray diffraction (XRD) data obtained during first charging of the lithium secondary battery, a first graph showing the change of the c-axis d-spacing value of the layered positive electrode active material according to the number of moles of lithium ions deintercalated from the layered positive electrode active material during the charging; obtaining, from XRD data obtained during second charging of the lithium secondary battery, a second graph showing the change of the c-axis d-spacing value of the layered positive electrode active material according to the number of moles of lithium ions deintercalated from the layered positive electrode active material during the charging; and classifying a cause of degradation of the secondary battery by comparing the first graph and the second graph.

First claim

1 . A method of diagnosing a cause of degradation of a lithium secondary battery, comprising:
(A) manufacturing a lithium secondary battery including a positive electrode including a layered positive electrode active material, a negative electrode, separator interposed between the positive electrode and the negative electrode, and an electrolyte; (B) obtaining, from a first X-ray diffraction data obtained during first charging of the lithium secondary battery, a first graph showing the change of the c-axis d-spacing value of the layered positive electrode active material according to a number of moles of lithium ions deintercalated from the layered positive electrode active material during the first charging; (C) obtaining, from a second X-ray diffraction data obtained during second charging of the lithium secondary battery, a second graph showing the change of the c-axis d-spacing value of the layered positive electrode active material according to a number of moles of lithium ions deintercalated from the layered positive electrode active material during the second charging; and (D) classifying the cause of degradation of the secondary battery by comparing the first graph and the second graph.

2 . The method of claim 1 , wherein the cause of the degradation of the secondary battery is one or more of a loss of available lithium or a loss of positive electrode capacity.

3 . The method of claim 1 , wherein the step (D) includes:
classifying the cause of the degradation of the secondary battery as the loss of available lithium when a maximum value of the number of moles of deintercalated lithium ions in the second graph is smaller than a maximum value of the number of moles of deintercalated lithium ions in the first graph; and after horizontally shifting the second graph in an x-axis direction so that the number of moles of deintercalated lithium ions corresponding to the maximum c-axis d-spacing value of the layered positive electrode active material in the second graph is the same as the number of moles of deintercalated lithium ions corresponding to the maximum c-axis d-spacing value of the layered positive electrode active material in the first graph, classifying the cause of the degradation of the secondary battery as a loss of positive electrode capacity when a sum of the maximum number of moles of deintercalated lithium ions in the second graph and a degree by which the second graph is horizontally shifted is greater than the maximum number of moles of deintercalated lithium ions in the first graph.

4 . The method of claim 3 , wherein the step (D) includes quantifying an amount of the loss of the available lithium as a value obtained by subtracting the maximum number of moles of deintercalated lithium ions in the second graph from the maximum number of moles of deintercalated lithium ions in the first graph.

5 . The method of claim 3 , wherein the step (D) includes quantifying an amount of the loss of the positive electrode capacity as a value obtained by subtracting the maximum number of moles of deintercalated lithium ions in the first graph from a sum of the maximum number of moles of deintercalated lithium ions in the second graph and a degree by which the second graph is horizontally shifted.

6 . The method of claim 4 , wherein, determining that the degradation of the lithium secondary battery is due to the loss of the available lithium when a rate of the loss of the available lithium according to the following Equation 1 is 14% or more:
Rate of loss of available lithium=(Amount of loss of available lithium)/(Maximum number of moles of deintercalated lithium ions in first graph)×100.   [Equation 1]

7 . The method of claim 1 , wherein the layered positive electrode active material is a lithium transition metal oxide including nickel at 60 mol % or more relative to a total number of moles of transition metals excluding lithium.

8 . The method of claim 1 , wherein the layered positive electrode active material is represented by the following Chemical Formula 1:
Li 1+a Ni x Co y M z O 2 ,   [Chemical Formula 1]
wherein, in Chemical Formula 1, 0≤a≤0.3, 0.6≤x≤1.0, 0≤y≤0.2, 0≤z≤0.2, and x+y+z=1, and M is one or more of manganese or aluminum.

9 . The method of claim 1 , wherein the second charging is:
charging performed after discharging the lithium secondary battery subjected to the first charging and subsequently repeatedly charging and discharging the lithium secondary battery for one or more cycles; or charging performed after discharging the lithium secondary battery subjected to the first charging and subsequently storing the lithium secondary battery for a long period of time at a temperature of −20° C. to 70° C.

10 . The method of claim 1 , wherein the first charging and the second charging are performed in a voltage range of 2.5 V to 4.2 V.

11 . The method of claim 1 , wherein the X-ray diffraction data is obtained using a transmission X-ray diffraction analyzer.

12 . The method of claim 1 , wherein the d-spacing value is a d-spacing value in the (003) plane of the layered positive electrode active material.

Assignees

• Lg Energy Solution Ltd

Inventors

• Yoon Hyo Jung
• Lee Eun Ju
• Kim So Young

Classifications

• G01N2223/611

  patterned objects; electronic devices · CPC title

• G01N2223/056

  diffraction · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• G01N2223/632

  residual life, life expectancy · CPC title