Electrolyser system of water electrolysis and process therefor

Patent metadata

Field	Value
Publication number	US-2022290317-A1
Application number	US-202217692397-A
Country	US
Kind code	A1
Filing date	Mar 11, 2022
Priority date	Mar 12, 2021
Publication date	Sep 15, 2022
Grant date	—

Abstract

An electrolyser system having an electrolysis stack and a direct current source, in order to generate oxygen and hydrogen as electrolysis gas by electrolysis of a water containing electrolysis medium. The electrolysis stack includes an anode section configured to generate oxygen and a cathode section configured to generate oxygen. Furthermore, the electrolyser system has an anode gas separator configured to separate oxygen from the electrolysis medium and a cathode gas separator configured to separate hydrogen from the electrolysis medium, wherein at least one of the gas separators includes a gas separating section and a gas cooling section, wherein the gas cooling section has a water inlet connected with a water supply, in order to supply cooling water to the gas cooling section of the gas separator, for the direct cooling of the electrolysis gas separated in the gas separating section of the gas separator within the gas cooling section.

First claim

What is claimed is:

1 . An electrolyser system for water electrolysis, comprising
an electrolysis stack and a direct current source, in order to generate oxygen and hydrogen as electrolysis gas by electrolysis of a water containing electrolysis medium, the electrolysis stack comprising an anode section configured to generate oxygen and a cathode section configured to generate hydrogen; an anode gas separator configured to separate oxygen from the electrolysis medium and a cathode gas separator configured to separate hydrogen from the electrolysis medium; wherein, at least one of the gas separators comprises a gas separating section and a gas cooling section, wherein the gas cooling section comprises a water inlet connected with a water supply, in order to supply cooling water to the gas cooling section of the gas separator, for the direct cooling of the electrolysis gas separated in the gas separating section of the gas separator within the gas cooling section.

2 . The electrolyser system according to claim 1 , wherein the cooling water supplied to the gas cooling section is used at least in part in order to balance out the water consumption resulting from the electrolysis.

3 . The electrolyser system according to claim 1 , wherein the gas separating section and the gas cooling section are arranged within one common housing.

4 . The electrolyser system according to claim 1 , wherein the water inlet of the gas cooling section is arranged in order to conduct the electrolysis gas to be cooled and the cooling water supplied to the gas cooling section in counter-flow.

5 . The electrolyser system according to claim 1 , wherein the gas cooling section of the gas separator is arranged vertically with respect to the perpendicular mediated by gravity, so that a stream of the cooling water can be conducted from top to bottom within the gas cooling section of the gas separator and a stream of the electrolysis gas can be conducted from bottom to top within the gas cooling section of the gas separator.

6 . The electrolyser system according to claim 1 , wherein the electrolyser system is operated at elevated pressure of 10 bar or more, and wherein the water supplied to the gas cooling section of the gas separator is used to fully balance out the water consumption resulting from the electrolysis.

7 . The electrolyser system according to claim 1 , wherein the electrolyser system is operated at elevated pressure of 10 bar or more, and wherein solely an amount of water required to fully balance out the water consumption resulting from electrolysis is supplied as the cooling water to the gas cooling section of the gas separator.

8 . The electrolyser system according to claim 6 , wherein the electrolyser system comprises an alkaline electrolyser, and the electrolyser system is operated at a pressure of 18 bar or more.

9 . The electrolyser system according to claim 6 , wherein the electrolyser system comprises a proton exchange membrane electrolyser, and the electrolyser system is operated at a pressure of 23 bar or more.

10 . The electrolyser system according to claim 1 , wherein the electrolyser system does not comprise a separator vessel to separate condensed water from cooled electrolysis gases.

11 . The electrolyser system according to claim 1 , wherein the water inlet comprises a nozzle to introduce the cooling water as a spray into the gas cooling section of the gas separator.

12 . The electrolyser system according to claim 1 , wherein a chiller is arranged between the water supply and the water inlet to pre-cool the cooling water supplied to the gas cooling section.

13 . A process for performing electrolysis of a water containing electrolysis medium to generate oxygen and hydrogen as electrolysis gas, comprising:
supplying a direct current to an electrolysis stack; subjecting the water containing electrolysis medium to electrolysis in the electrolysis stack, wherein the electrolysis stack comprises an anode section and a cathode section, wherein oxygen is generated in the anode section and hydrogen is generated in the cathode section; separating the generated oxygen from the electrolysis medium in an anode gas separator and separating the generated hydrogen from the electrolysis medium in a cathode gas separator; introducing cooling water from a water supply into at least one of the gas separators, for the direct cooling of the electrolysis gas separated in a gas separating section of the gas separator by the cooling water within a gas cooling section of the gas separator.

14 . The process according to claim 13 , wherein the electrolysis gas is cooled by the cooling water to 10° C. above ambient temperature or less.

15 . The process according to claim 13 , wherein the cooling water is heated to 10° C. below the operating temperature of the electrolyser system or less.

Assignees

• Air Liquide

Inventors

• Tadiello Jean-Philippe
• Svitnic Tibor
• Nesselberger Markus

Classifications

• C25B9/67 Primary

  Heating or cooling means · CPC title

• C25B1/042

  by electrolysis of steam · CPC title

• C25B9/60

  Constructional parts of cells · CPC title

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• C25B9/05

  Pressure cells · CPC title