Processes for producing biocarbon pellets with adjustable grindability index

Patent metadata

Field	Value
Publication number	US-2022228081-A1
Application number	US-202217580035-A
Country	US
Kind code	A1
Filing date	Jan 20, 2022
Priority date	Jan 21, 2021
Publication date	Jul 21, 2022
Grant date	—

Abstract

In some variations, the invention provides a biocarbon pellet comprising: 35 wt % to 99 wt % of a biogenic reagent, wherein the biogenic reagent comprises, on a dry basis, at least 60 wt % carbon; 0 wt % to 35 wt % water moisture; and 1 wt % to 30 wt % of a binder, wherein the biocarbon pellet is characterized by an adjustable Hardgrove Grindability Index (HGI) from about 30 to about 120, as shown in the Examples. The pellet HGI is adjustable by controlling process conditions and the pellet binder. The binder can be an organic binder or an inorganic binder. The carbon is renewable as determined from a measurement of the 14C/12C isotopic ratio. Many processes of making and using the biocarbon pellets are described. Applications of the biocarbon pellets include pulverized coal boilers, furnaces for making metals such as iron or silicon, and gasifiers for producing reducing gas.

First claim

I/We claim:

1 . A process of producing biocarbon pellets, the process comprising:
(a) providing a biomass feedstock; (b) pyrolyzing the biomass feedstock, thereby generating a biogenic reagent, wherein the biogenic reagent comprises at least about 50 wt % carbon and at least about 5 wt % moisture; (c) mechanically treating the biogenic reagent, thereby generating a plurality of carbon-containing particles; (d) combining the carbon-containing particles with a binder, thereby forming a carbon-binder mixture; (e) pelletizing the carbon-binder mixture, following step (d) or simultaneously with step (d), thereby generating biocarbon pellets; and (f) optionally, at least partially drying the biocarbon pellets, wherein the biocarbon pellets are characterized by an average Hardgrove Grindability Index of at least 30.

2 . The process of claim 1 , wherein the biogenic reagent comprises, on a dry basis, at least about 70 wt % carbon.

3 . The process of claim 1 , wherein the biogenic reagent comprises at least about 50 wt % fixed carbon.

4 . The process of claim 1 , wherein the carbon is at least 50% renewable as determined from a measurement of the 14 C/ 12 C isotopic ratio of the carbon.

5 . The process of claim 1 , wherein the carbon is fully renewable as determined from a measurement of the 14 C/ 12 C isotopic ratio of the carbon.

6 . The process of claim 1 , wherein the biogenic reagent comprises, on a dry basis, from about 75 wt % to about 94 wt % carbon, from about 3 wt % to about 15 wt % oxygen, and from about 1 wt % to about 10 wt % hydrogen.

7 . The process of claim 1 , wherein the biogenic reagent comprises at least about 10 wt % moisture in step (b).

8 . The process of claim 1 , wherein step (c), step (d), or step (e) is conducted at a lower moisture than the moisture of step (b).

9 . The process of claim 1 , wherein step (f) is conducted, and wherein the drying results in even lower moisture than the lower moisture conducted in step (c), step (d), or step (e).

10 . The process of claim 1 , wherein step (f) is conducted after step (e).

11 . The process of claim 1 , wherein step (f) is conducted and is integrated with step (e).

12 . The process of claim 1 , wherein the biogenic reagent is not dried during step (c).

13 . The process of claim 1 , wherein the biogenic reagent is not dried during step (d).

14 . The process of claim 1 , wherein the biogenic reagent is not dried during step (e).

15 . The process of claim 1 , wherein the biocarbon pellet comprises from about 1 wt % to about 30 wt % moisture.

16 . The process of claim 1 , wherein step (c) utilizes a mechanical-treatment apparatus selected from a hammer mill, an extruder, an attrition mill, a disc mill, a pin mill, a ball mill, a cone crusher, a jaw crusher, or a combination thereof.

17 . The process of claim 1 , wherein step (c) and step (d) are integrated.

18 . The process of claim 1 , wherein the biocarbon pellet comprises from about 2 wt % to about 25 wt % of the binder.

19 . The process of claim 1 , wherein the binder comprises starch, thermoplastic starch, crosslinked starch, starch polymers, cellulose, cellulose ethers, hem icellulose, methylcellulose, chitosan, lignin, lactose, sucrose, dextrose, maltodextrin, banana flour, wheat flour, wheat starch, soy flour, corn flour, wood flour, coal tars, coal fines, met coke, asphalt, coal-tar pitch, petroleum pitch, bitumen, pyrolysis tars, gilsonite, bentonite clay, borax, limestone, lime, waxes, vegetable waxes, baking soda, baking powder, sodium hydroxide, potassium hydroxide, iron ore concentrate, silica fume, gypsum, Portland cement, guar gum, polyvidones, polyacrylam ides, polylactides, phenol-formaldehyde resins, vegetable resins, recycled shingles, recycled tires, or a derivative thereof, or a combination of the foregoing.

20 . The process of claim 19 , wherein the binder comprises starch, thermoplastic starch, crosslinked starch, starch polymers, or a derivative thereof, or a combination of the foregoing.

21 . The process of claim 1 , wherein the binder reduces the reactivity of the biocarbon pellet compared to an otherwise-equivalent biocarbon pellet without the binder.

22 . The process of claim 21 , wherein the reactivity is thermal reactivity.

23 . The process of claim 22 , wherein the biocarbon pellet has lower self-heating compared to the otherwise-equivalent biocarbon pellet without the binder.

24 . The process of claim 21 , wherein the reactivity is chemical reactivity.

25 . The process of claim 1 , wherein the biogenic reagent comprises pores, and wherein the binder is comprised within the pores.

26 . The process of claim 1 , wherein the binder is disposed on the surface of the biocarbon pellet.

27 . The process of claim 1 , wherein step (e) utilizes a pelletizing apparatus selected from an extruder, a ring die pellet mill, a flat die pellet mill, a roll compactor, a roll briquetter, a wet agglomeration mill, a dry agglomeration mill, or a combination thereof.

28 . The process of claim 1 , wherein step (d) and step (e) are integrated.

29 . The process of claim 1 , wherein the Hardgrove Grindability Index is at least 40.

30 . The process of claim 1 , wherein the Hardgrove Grindability Index is at least 70.

31 . The process of claim 1 , wherein the Hardgrove Grindability Index is from about 30 to about 120.

32 . The process of claim 1 , wherein the Hardgrove Grindability Index is from about 40 to about 70.

33 . The process of claim 1 , wherein the biocarbon pellet is characterized by a Pellet Durability Index of at least 90%.

34 . The process of claim 1 , wherein the process comprises pre-selecting a Hardgrove Grindability Index, adjusting process conditions based on the pre-selected Hardgrove Grindability Index, and achieving within ±20% of the pre-selected Hardgrove Grindability Index for the biocarbon pellets, wherein the adjusting process conditions comprises adjusting one or more of pyrolysis temperature, pyrolysis time, mechanical-treatment conditions, pelletizing conditions, binder type, binder concentration, binding conditions, and drying.

35 . The process of claim 34 , wherein the process achieves within ±10% of the pre-selected Hardgrove Grindability Index for the biocarbon pellets.

Assignees

• Carbon Tech Holdings Llc

Inventors

• Mennell James A
• Daugaard Daren
• Slack Dustin
• Graham Forrest S

Classifications

• C10B57/10

  Drying · CPC title

• C10B57/06

  containing additives · CPC title

• C10B57/02

  Multi-step carbonising or coking processes · CPC title

• C21B2200/00

  Recycling of non-gaseous waste material · CPC title

• C21B13/0066

  Preliminary conditioning of the solid carbonaceous reductant · CPC title