Battery including beta-delithiated layered nickle oxide electrochemically active cathode material

Patent metadata

Field	Value
Publication number	US-2022209233-A1
Application number	US-202217698670-A
Country	US
Kind code	A1
Filing date	Mar 18, 2022
Priority date	Mar 28, 2014
Publication date	Jun 30, 2022
Grant date	—

Abstract

The invention is directed towards a battery. The battery includes a cathode, an anode, a separator between the cathode and the anode, and an electrolyte. The cathode includes a conductive additive and an electrochemically active cathode material. The electrochemically active cathode material includes a beta-delithiated layered nickel oxide. The beta-delithiated layered nickel oxide has a chemical formula. The chemical formula is LixAyNi1+a−zMzO2.nH2O where x is from about 0.02 to about 0.20; y is from about 0.03 to about 0.20; a is from about 0 to about 0.2; z is from about 0 to about 0.2; and n is from about 0 to about 1. Within the chemical formula, A is an alkali metal. The alkali metal includes potassium, rubidium, cesium, and any combination thereof. Within the chemical formula, M comprises an alkaline earth metal, a transition metal, a non-transition metal, and any combination thereof. The anode includes an electrochemically active anode material. The electrochemically active anode material includes zinc, zinc alloy, and any combination thereof.

First claim

1 . (canceled)

2 . A battery comprising:
a cathode comprising an electrochemically active cathode material, the electrochemically active cathode material comprising a beta-delithiated layered nickel oxide and the cathode having an initial porosity at the time of manufacture of the cathode in a range of about 20% to about 40%; an anode; a separator between the cathode and the anode; an electrolyte comprising a hydroxide; and the beta-delithiated layered nickel oxide comprising a chemical formula, the chemical formula comprising LixAyNi1+a−zMzO2.nH2O wherein: x is from about 0.02 to about 0.20; y is from about 0.03 to about 0.20; a is from about 0 to about 0.2; z is from about 0 to about 0.2; n is from about 0 to about 1; A comprising an alkali metal comprising potassium, rubidium, cesium, and any combination thereof; and M comprising an alkaline earth metal, a transition metal, a non-transition metal, and any combination thereof.

3 . The battery of claim 2 , further comprising an additional electrochemically active cathode material selected from the group consisting of manganese oxide, manganese dioxide, electrolytic manganese dioxide, chemical manganese dioxide, high power electrolytic manganese dioxide, lambda manganese dioxide, gamma manganese dioxide, beta manganese dioxide, silver oxide, nickel oxide, nickel oxyhydroxide, copper oxide, copper iodate, bismuth oxide, and combinations thereof.

4 . The battery of claim 2 , wherein y is from about 0.08 to about 0.13.

5 . The battery of claim 2 , wherein A comprises potassium.

6 . The battery of claim 5 , wherein y is from about 0.08 to about 0.13.

7 . The battery of claim 2 , wherein a is from about 0.09 to about 0.10.

8 . The battery of claim 2 , the beta-delithiated layered nickel oxide comprising a gravimetric capacity of greater than about 350 mAh/g.

9 . The battery of claim 2 , the beta-delithiated layered nickel oxide comprising a gravimetric capacity from about 350 mAh/g to about 400 mAh/g.

10 . The battery of claim 2 , wherein x is from about 0.03 to about 0.12.

11 . The battery of claim 2 , wherein the beta-delithiated layered nickel oxide comprises water such that n is greater than 0.

12 . The battery of claim 2 , comprising an open circuit voltage of from about 1.7 volts to about 1.8 volts.

13 . The battery of claim 2 , wherein the anode comprises an electrochemically active anode material, the electrochemically active anode material comprising zinc, zinc alloy, or any combination thereof.

14 . The battery of claim 2 , further comprising:
a housing, the housing comprising an outer surface; and a label, the label comprising a voltage tester; wherein the label is affixed to the outer surface of the housing.

Assignees

• Duracell Us Operations Inc

Inventors

• Anglin David Lloyd
• Nelson Jennifer Anne
• Christian Paul Albert
• Richards Thomas C

Classifications

• H01M10/488

  Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density · CPC title

• H01M6/505

  Cells combined with indicating means for external visualization of the condition, e.g. by change of colour or of light intensity · CPC title

• H01M4/06 Primary

  Electrodes for primary cells · CPC title

• H01M4/38

  of elements or alloys · CPC title

• F02M51/02

  specially for low-pressure fuel-injection ({F02M51/005 takes precedence;} pumpsper se F02M51/04; injectors per se F02M51/08) · CPC title