Methods for detecting end-points for cleaning processes of aerospace components

Patent metadata

Field	Value
Publication number	US-2022050051-A1
Application number	US-202117401061-A
Country	US
Kind code	A1
Filing date	Aug 12, 2021
Priority date	Aug 13, 2020
Publication date	Feb 17, 2022
Grant date	—

Abstract

Embodiments of the present disclosure generally relate to methods for detecting end-points of cleaning processes for aerospace components containing corrosion. The method includes exposing the aerospace component to a first solvent, exposing the aerospace component to a first water rinse, and analyzing a first aliquot of the first water rinse by absorbance spectroscopy to determine an intermediate solute concentration in the first aliquot, where the intermediate solute concentration is greater than a reference solute concentration. The method further includes exposing the aerospace component to an aqueous cleaning solution to remove corrosion from the aluminum oxide layer, exposing the aerospace component to a second solvent, and exposing the aerospace component to a second water rinse, and analyzing a second aliquot of the second water rinse by absorbance spectroscopy to determine a post-clean solute concentration in the second aliquot, where the post-clean solute concentration is less than the intermediate solute concentration.

First claim

What is claimed is:

1 . A method for detecting an end-point of a cleaning process for an aerospace component, comprising:
analyzing a reference solvent by absorbance spectroscopy to determine a reference solute concentration of the reference solvent; exposing the aerospace component to a first solvent, wherein the aerospace component comprises a nickel superalloy, an aluminide layer disposed on the nickel superalloy, and an aluminum oxide layer disposed on the aluminide layer, and wherein the corrosion is contained on the aluminum oxide layer; exposing the aerospace component to a first water rinse; analyzing a first aliquot of the first water rinse by absorbance spectroscopy to determine an intermediate solute concentration in the first aliquot, wherein the intermediate solute concentration is greater than the reference solute concentration; exposing the aerospace component containing corrosion to an aqueous cleaning solution to remove the corrosion from the aluminum oxide layer; exposing the aerospace component to a second solvent; exposing the aerospace component to a second water rinse; and analyzing a second aliquot of the second water rinse by absorbance spectroscopy to determine a post-clean solute concentration in the second aliquot, wherein the post-clean solute concentration is less than the intermediate solute concentration.

2 . The method of claim 1 , wherein each of the first aliquot and the second aliquot is independently analyzed by ultraviolet-visible (UV-vis) absorbance spectroscopy.

3 . The method of claim 1 , wherein the aqueous cleaning solution comprises water, a complexing agent, and a base, and wherein the complexing agent comprises ethylenediaminetetraacetic acid (EDTA) and/or a salt thereof, and wherein the base comprises a hydroxide.

4 . The method of claim 1 , wherein the aqueous cleaning solution comprises water, a complexing agent, and a base, and further comprising:
exposing the aerospace component to the aqueous cleaning solution for about 1 hour to about 5 hours; sonicating the aerospace component in the aqueous cleaning solution; and maintaining the aqueous cleaning solution at a temperature of about 20° C. to about 50° C.

5 . The method of claim 1 , wherein exposing the aerospace component to the first solvent further comprises:
exposing the aerospace component to the first solvent for about 5 minutes to about 60 minutes; sonicating the aerospace component in the first solvent; and maintaining the first solvent at a temperature of about 20° C. to about 50° C.

6 . The method of claim 1 , wherein exposing the aerospace component to the second solvent further comprises:
exposing the aerospace component to the second solvent for about 5 minutes to about 60 minutes; sonicating the aerospace component in the second solvent; and maintaining the second solvent at a temperature of about 20° C. to about 50° C.

7 . The method of claim 1 , wherein the aluminide layer comprises nickel aluminide, titanium aluminide, magnesium aluminide, iron aluminide, or combinations thereof.

8 . The method of claim 1 , wherein the aluminide layer has a thickness of about 20 μm to about 500 μm, wherein the aluminum oxide has a thickness of about 1 μm to about 50 μm, and wherein the aerospace component has a thickness of about 1 mm to about 5 mm.

9 . A method for detecting an end-point of a cleaning process for an aerospace component, comprising:
analyzing a reference solvent by absorbance spectroscopy to determine a reference solute concentration of the reference solvent; exposing the aerospace component to a first solvent, wherein the aerospace component comprises a nickel superalloy, an aluminide layer disposed on the nickel superalloy, and an aluminum oxide layer disposed on the aluminide layer, and wherein the corrosion is contained within at least one of the aluminum oxide layer or the aluminide layer; exposing the aerospace component to a first water rinse; analyzing a first aliquot of the first water rinse by absorbance spectroscopy to determine a first intermediate solute concentration in the first aliquot, wherein the first intermediate solute concentration is greater than the reference solute concentration; exposing the aerospace component to a first aqueous cleaning solution to remove the corrosion from the aluminum oxide layer; exposing the aerospace component to a first sonication in water; exposing the aerospace component to a second water rinse; and analyzing a second aliquot of the second water rinse by absorbance spectroscopy to determine a second intermediate solute concentration in the second aliquot, wherein the second intermediate solute concentration is less than the first intermediate solute concentration; exposing the aerospace component to an acidic cleaning solution to remove the corrosion from the aluminum oxide layer and/or or the aluminide layer; exposing the aerospace component to a second sonication in water; exposing the aerospace component to a third water rinse; and analyzing a third aliquot of the third water rinse by absorbance spectroscopy to determine a third intermediate solute concentration in the third aliquot, wherein the third intermediate solute concentration is less than the second intermediate solute concentration; exposing the aerospace component to a second aqueous cleaning solution to remove the corrosion from the aluminum oxide layer and/or or the aluminide layer; exposing the aerospace component to a second solvent; exposing the aerospace component to a fourth water rinse; and analyzing a fourth aliquot of the fourth water rinse by absorbance spectroscopy to determine a post-clean solute concentration in the fourth aliquot, wherein the post-clean solute concentration is less than the third intermediate solute concentration.

10 . The method of claim 9 , wherein each of the first aliquot, the second aliquot, the third aliquot, and the fourth aliquot is independently analyzed by ultraviolet-visible (UV-vis) absorbance spectroscopy.

11 . The method of claim 9 , wherein the acidic cleaning solution comprises water and about 10 volume percent (vol %) to about 40 vol % of sulfuric acid, and further comprising:
exposing the aerospace component to the acidic cleaning solution for about 30 minutes to about 90 minutes; stirring the acidic cleaning solution while exposing the aerospace component; and maintaining the acidic cleaning solution at a temperature of about 50° C. to about 150° C.

12 . The method of claim 9 , wherein the acidic cleaning solution comprises water, hydrogen fluoride, and nitric acid, and wherein the acidic cleaning solution comprises about 0.2 volume percent (vol %) to about 5 vol % of hydrogen fluoride and about 1 vol % to about 10 vol % of nitric acid.

13 . The method of claim 9 , wherein the acidic cleaning solution comprises water, hydrogen fluoride, and nitric acid, and further comprising:
exposing the aerospace component to the acidic cleaning solution for about 30 minutes to about 90 minutes; stirring the acidic cleaning solution while exposing the aerospace component; and maintaining the acidic cleaning solution at a temperature of about 20° C. to about 50° C.

14 . The method of claim 9 , wherein exposing the aerospace component to the first solvent further comprises:
exposing the aerospace component to the first solvent for about 5 minutes to about 60 minutes; sonicating the aerospace component in the first solvent; and maintaining the first solvent at a temperature of about 20° C. to about 50° C.

15 . The method of claim 9 , wherein exposing the aerospa

Assignees

• Applied Materials Inc

Inventors

• Mandal Abhishek
• Scudder Lance A
• Britz David Alexander
• Ohno Kenichi
• Deepak Nitin
• Goradia Prerna Sonthalia
• Kadam Ankur

Classifications

• C11D7/06

  Hydroxides · CPC title

• C11D7/3245

  Aminoacids · CPC title

• G01N2021/8411

  Application to online plant, process monitoring · CPC title

• B08B3/12

  by sonic or ultrasonic vibrations · CPC title

• G01N2201/1222

  Endpoint determination; reaction time determination · CPC title