Sensor interrogation
US-9410940-B2 · Aug 9, 2016 · US
US2021255135A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2021255135-A1 |
| Application number | US-201817273553-A |
| Country | US |
| Kind code | A1 |
| Filing date | Oct 17, 2018 |
| Priority date | Oct 17, 2018 |
| Publication date | Aug 19, 2021 |
| Grant date | — |
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An electrochemical oxygen sensor with a long service life is provided. The electrochemical oxygen sensor according to the present invention includes a positive electrode, a negative electrode, and an electrolyte solution, and the electrolyte solution contains a chelating agent and ammonia, and a concentration of the ammonia in the electrolyte solution is 0.01 mol/L or higher. Citric acid is preferable as the chelating agent contained in the electrolyte solution. Also, the negative electrode preferably contains an Sn alloy.
Opening claim text (preview).
1 . An electrochemical oxygen sensor comprising: a positive electrode; a negative electrode; and an electrolyte solution, wherein the electrolyte solution comprises a chelating agent and ammonia, and wherein a concentration of the ammonia in the electrolyte solution is 0.01 mol/L or higher. 2 . The electrochemical oxygen sensor according to claim 1 , wherein a concentration of the chelating agent in the electrolyte solution is 2.3 mol/L or higher. 3 . The electrochemical oxygen sensor according to claim 1 , wherein the electrolyte solution further comprises an alkali metal salt of the chelating agent. 4 . The electrochemical oxygen sensor according to claim 1 , wherein citric acid is included as the chelating agent. 5 . The electrochemical oxygen sensor according to claim 4 , wherein the electrolyte solution has a pH of 3.5 to 5.75. 6 . The electrochemical oxygen sensor according to claim 1 , wherein the negative electrode comprises Sn an Sn alloy. 7 . The electrochemical oxygen sensor according to claim 1 , wherein the negative electrode comprises an Sn alloy, and wherein the Sn alloy comprises at least one element selected from the group consisting of Ag, Cu, and Sb. 8 . The electrochemical oxygen sensor according to claim 1 , wherein the electrolyte solution further comprises at least one selected from the group consisting of acetic acid, boric acid, phosphoric acid, and salts thereof.
Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid {, e.g. Clark-type oxygen sensors} · CPC title
Electrodes, e.g. test electrodes; Half-cells (G01N27/414 takes precedence) · CPC title
Concentration cells using liquid electrolytes {measuring currents or voltages in voltaic cells} · CPC title
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