Plant complex for pig iron production and a method for operating the plant complex

Patent metadata

Field	Value
Publication number	US-2021123110-A1
Application number	US-201716638502-A
Country	US
Kind code	A1
Filing date	Sep 29, 2017
Priority date	Aug 23, 2017
Publication date	Apr 29, 2021
Grant date	—

Abstract

A plant complex for pig iron production may include a furnace and a furnace gas conduit system for a furnace gas quantity stream that comprises nitrogen, carbon monoxide, and carbon dioxide. The plant complex may also include a hydrogen source, an H2 gas conduit system for a hydrogen-containing gas quantity stream emitted from the hydrogen source, a mixing apparatus for establishing a mixed gas formed from the furnace gas stream and the hydrogen-containing gas quantity stream. The mixing apparatus may be connected to the furnace gas conduit system and to the H2 gas conduit system. The mixed gas established may have a stoichiometric mixing quotient formed from a dividend with a difference value between molar amounts of hydrogen as minuend and carbon dioxide as subtrahend and of a divisor with a sum value of molar amounts of carbon monoxide and carbon dioxide. The plant complex may also include a mixed gas conduit system and a chemical plant connected to the mixed gas conduit system.

First claim

1 .- 17 . (canceled)

18 . A plant complex for pig iron production, the plant comprising:
a furnace for pig iron production; a furnace gas conduit system for a furnace gas quantity stream obtained in the pig iron production, wherein the furnace gas quantity stream comprises carbon monoxide and carbon dioxide; a hydrogen source; an H 2 gas conduit system for a hydrogen-containing gas quantity stream emitted from the hydrogen source; a mixing apparatus for establishing a mixed gas formed from the furnace gas quantity stream and the hydrogen-containing gas quantity stream, wherein the mixing apparatus is connected to the furnace gas conduit system and to the H 2 gas conduit system, wherein the mixed gas comprises a stoichiometric mixing quotient formed from a dividend with a difference value between molar amounts of hydrogen as minuend and carbon dioxide as subtrahend and of a divisor with a sum value of molar amounts of carbon monoxide and carbon dioxide; a mixed gas conduit system for the mixed gas that is obtained in establishing the stoichiometric mixing quotient; and a chemical plant connected to the mixed gas conduit system.

19 . The plant complex of claim 18 wherein the furnace gas quantity stream comprises nitrogen.

20 . The plant complex of claim 18 wherein the mixed gas has a mixing quotient in a range from 1 to 10.

21 . The plant complex of claim 18 comprising a plant for gas cleaning, wherein the plant for gas cleaning is connected to at least one of the furnace gas conduit system, the H 2 gas conduit system, or the mixed gas conduit system.

22 . The plant complex of claim 18 comprising a plant for gas compression, wherein the plant for gas compression is connected to at least one of the furnace gas conduit system, the H 2 gas conduit system, or the mixed gas conduit system.

23 . The plant complex of claim 18 comprising a plant that is for at least one of carbon monoxide separation or carbon dioxide separation and is connected to at least one of the furnace gas conduit system, the H 2 gas conduit system, or the mixed gas conduit system.

24 . The plant complex of claim 18 comprising a carbon dioxide source that is connected to at least one of the furnace gas conduit system, the H 2 gas conduit system, or the mixed gas conduit system.

25 . The plant complex of claim 18 wherein the chemical plant is at least one of:
a plant for preparation of methanol;
a plant for preparation of alkanes;
a plant for preparation of alkenes;
a plant for preparation of alkynes;
a plant for preparation of ethers;
a plant for preparation of aldehydes;
a plant for preparation of ketones; or
a plant for preparation of carboxylic acids.

26 . The plant complex of claim 18 wherein the chemical plant is at least one of:
a plant for preparation of ethanol, n-propanol, isopropanol, n-butanol, isobutanol, sec-butanol, tert-butanol, butane-1,4-diol, or a combination thereof;
a plant for preparation of methane, ethane, propane, n-butane, isobutane, cyclohexane, or a combination thereof;
a plant for preparation of ethene, propene, but-1-ene, (Z)-but-2-ene, (E)-but-2-ene, 2-methylprop-1-ene, 1,3-butadiene, or a combination thereof;
a plant for preparation of ethyne, propyne, 1-butyne, 2-butyne, or a combination thereof;
a plant for preparation of linear ethers, cyclic ethers, branched ethers, saturated ethers, unsaturated ethers, dimethyl ether (DME), isopropyl methyl ether, oxacyclohexane, polyoxymethylene dimethyl ether (OME), or a combination thereof;
a plant for preparation of formaldehyde, acetaldehyde, propanal, butanal, or a combination thereof;
a plant for preparation of acetone, butanone, 2-pentanone, 3-pentanone, methyl isopropyl ketone, or a combination thereof; or
a plant for preparation of formic acid, acetic acid, propionic acid, oxalic acid, or a combination thereof.

27 . A method of operating the plant complex of claim 18 , the method comprising:
providing the furnace gas quantity stream; providing the hydrogen-containing gas quantity stream emitted from the hydrogen source; producing the mixed gas by mixing the furnace gas quantity stream with the hydrogen-containing gas quantity stream, wherein the stoichiometric mixing quotient is established with the dividend with the difference value between the molar amounts of hydrogen as the minuend and carbon dioxide as the subtrahend and of the divisor with the sum value of the molar amounts of carbon monoxide and carbon dioxide; and feeding the mixed gas through the mixed gas conduit system to the chemical plant connected to the mixed gas stream.

28 . A method of producing pig iron in a plant complex, the method comprising:
providing a furnace gas quantity stream; providing a hydrogen-containing gas quantity stream emitted from a hydrogen source; producing a mixed gas by mixing the furnace gas quantity stream with the hydrogen-containing gas quantity stream, wherein a stoichiometric mixing quotient is established with a dividend with a difference value between molar amounts of hydrogen as a minuend and carbon dioxide as a subtrahend and of a divisor with a sum value of molar amounts of carbon monoxide and carbon dioxide; and feeding the mixed gas through a mixed gas conduit system to a chemical plant connected to the mixed gas stream.

29 . The method of claim 28 wherein the furnace gas quantity stream comprises nitrogen.

30 . The method of claim 28 comprising adjusting the mixed gas to a stoichiometric mixing quotient with a dividend with a difference value between molar amounts of hydrogen as minuend and carbon dioxide as subtrahend and a divisor with a sum value of molar amounts of carbon monoxide and carbon dioxide in a range from 1.2 to 10.

31 . The method of claim 28 comprising cleaning at least one of the furnace gas quantity stream, the hydrogen-containing gas quantity stream, or the mixed gas.

32 . The method of claim 28 comprising compressing at least one of the furnace gas quantity stream, the hydrogen-containing gas quantity stream, or the mixed gas.

33 . The method of claim 32 wherein the compressing is performed at a pressure in a range from 1 to 400 bar.

34 . The method of claim 28 comprising at least partially separating carbon monoxide and/or carbon dioxide.

35 . The method of claim 28 wherein establishing the stoichiometric mixing quotient of the mixed gas comprises supplying carbon dioxide from a carbon dioxide source.

Assignees

• Thyssenkrupp Ind Solutions Ag
• Thyssenkrupp Ag

Inventors

• Krüger Matthias

Classifications

• F27D17/20

  Arrangements for treatment or cleaning of waste gases · CPC title

• Y02P10/134

  by avoiding CO2, e.g. using hydrogen · CPC title

• C21B2100/22

  by reforming · CPC title

• Y02P10/122

  by capturing or storing CO2 · CPC title

• C21B7/002 Primary

  Evacuating and treating of exhaust gases · CPC title