Method for operating a top gas recycling blast furnace installation

Patent metadata

Field	Value
Publication number	US-10072312-B2
Application number	US-201415106575-A
Country	US
Kind code	B2
Filing date	Nov 27, 2014
Priority date	Dec 20, 2013
Publication date	Sep 11, 2018
Grant date	Sep 11, 2018

Abstract

Method of operating a blast furnace installation comprising a top gas recycle blast furnace and hot stones, whereby a hydrocarbon containing fuel is transformed into a transformed gas stream consisting mainly of CO and H2 and substantially devoid of hydrocarbon, whereby a low-heating-value gaseous fuel is generated comprising a mixture of the transformed gas with a portion of the CO2-rich tail gas obtained by decarbonatation of the blast furnace gas, and whereby the low-heating-value fuel is used to heat the hot furnace gas is heated before being injected into the blast-furnace.

First claim

What is claimed is:

1. A method of operating a blast furnace installation comprising a top gas recycle blast furnace generating blast furnace gas, comprising the steps of:
decarbonating the blast furnace gas so as to obtain a CO 2 -enriched rich tail gas stream and a decarbonated blast furnace gas stream containing not more than 3% vol CO 2 ;
transforming a hydrocarbon-containing gaseous fuel not generated by the blast furnace to generate a transformed gas stream containing at least 70% vol of CO and H 2 in total and at most 7% vol of hydrocarbon;
producing a low-heating-value gaseous fuel having a heating value of from 2.8 to 7.0 MJ/Nm 3 and containing (i) a portion of the tail gas stream and (ii) at least a first portion of the transformed gas stream and using said low-heating-value gaseous fuel for heating hot stoves;
heating at least 70% vol of the decarbonated blast furnace gas stream in the hot stoves to a temperature between 700° C. and 1300° C. to generate heated decarbonated blast furnace gas; and
injecting the heated decarbonated blast furnace gas into the blast furnace.

2. The method of claim 1 , wherein the hydrocarbon-containing gaseous fuel contains natural gas and/or coke oven gas.

3. The method of claim 1 , wherein partial combustion of the hydrocarbon-containing gaseous fuel is used to generate the transformed gas stream.

4. The method of claim 1 , wherein a fuel reforming process is used to generate the transformed gas stream.

5. The method of claim 4 , wherein the hydrocarbon-containing fuel is reformed using CO 2 as a reforming agent.

6. The method of claim 5 , wherein a part of the tail gas is used as a reforming agent.

7. The method of claim 1 , wherein at least a portion of the transformed gas stream is mixed with the decarbonated blast furnace gas so as to obtain a fortified decarbonated blast furnace gas stream upstream of the hot stoves.

8. The method of claim 7 , wherein the low-heating-value gaseous fuel contains a first portion of the fortified decarbonated blast furnace gas stream.

9. The method of claim 7 , wherein partial combustion of the hydrocarbon-containing gaseous fuel in a partial combustion reactor is used to generate the transformed gas stream and a second portion of the fortified decarbonated blast furnace gas stream is used to heat the partial combustion reactor.

10. The method of claim 7 , wherein a fuel reforming process is conducted in a reformer to generate the transformed gas stream and whereby a third portion of the fortified decarbonated blast furnace gas stream is used to heat the reformer.

11. The method of claim 10 , wherein combustion of said third portion with air is used to heat the reformer.

12. The method of claim 1 , whereby 80 to 90% vol of the decarbonated blast furnace gas stream is heated in the hot stoves and injected into the blast furnace.

13. The method of claim 1 , whereby the heated decarbonated blast furnace gas is injected into the blast furnace via hearth tuyeres.

14. The method of claim 13 , wherein the heated decarbonated blast furnace gas is injected into the blast furnace also via shaft tuyeres.

15. The method of claim 1 , whereby a vacuum pressure swing adsorption, a pressure swing adsorption or a chemical absorption unit is used to decarbonate the blast furnace gas.

16. The method of claim 1 whereby the hot stoves are heated by burning the low-heating-value gaseous fuel with air.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Grant Michael

Classifications

• C21B2100/26

  by adding additional fuel in recirculation pipes · CPC title

• C21B9/14

  Preheating the combustion air · CPC title

• C21B5/06 Primary

  using top gas in the blast furnace process · CPC title

• C21B2100/22

  by reforming · CPC title

• C21B7/002

  Evacuating and treating of exhaust gases · CPC title