Porous Molding

Patent metadata

Field	Value
Publication number	US-2020360915-A1
Application number	US-201816959783-A
Country	US
Kind code	A1
Filing date	Dec 21, 2018
Priority date	Jan 4, 2018
Publication date	Nov 19, 2020
Grant date	—

Abstract

Provided is a porous molding which is capable of removing ions in water to be treated, in particular, phosphorus ions at a very high liquid-permeation rate of at least SV 120 hr−1, and which has a large adsorption capacity. The porous molding according to the present invention comprises an organic polymer resin and an inorganic ion adsorbent, and is characterized in that a total volume of pores having a pore diameter of 1-80 nm as measured by a nitrogen adsorption method is 0.05-0.7 cm3/g per unit mass of the inorganic ion adsorbent.

First claim

1 . A porous shaped body in which an organic polymer resin and an inorganic ion adsorbent are included, and the sum total of the volumes of pores having a pore diameter of from 1 nm to 80 nm measured by a nitrogen gas adsorption method is per unit mass of the inorganic ion adsorbent from 0.05 cm 3 /g to 0.7 cm 3 /g.

2 . The porous shaped body according to claim 1 , wherein the sum total of the volumes of pores having a pore diameter of from 1 nm to 80 nm measured by a nitrogen gas adsorption method is per unit mass of the porous shaped body from 0.02 cm 3 /g to 0.6 cm 3 /g.

3 . The porous shaped body according to claim 1 , wherein the specific surface area measured by a nitrogen gas adsorption method is from 50 m 2 /g to 400 m 2 /g.

4 . The porous shaped body according to claim 1 , wherein the supported amount of the inorganic ion adsorbent included in the porous shaped body is from 30% by mass to 95% by mass.

5 . The porous shaped body according to claim 1 , in a form of spherical particles with an average particle diameter of from 100 μm to 2500 μm.

6 . The porous shaped body according to claim 1 , wherein the flatness ratio of the porous shaped body particles is from 0 to 0.3.

7 . The porous shaped body according to claim 1 , wherein the bulk density of the porous shaped body is from 0.2 g/mL to 0.7 g/mL.

8 . The porous shaped body according to claim 1 , wherein the average particle diameter of an inorganic ion adsorbent included in the porous shaped body is from 0.08 μm to 10 μm, and the ratio of (maximum particle diameter)/(minimum particle diameter) of the inorganic ion adsorbent is from 1 to 500.

9 . The porous shaped body according to claim 1 , wherein the pore volume measured by a mercury intrusion method in a range of pore diameter of from 5.5 nm to 120 μm is from 0.6 to 2.0 cm 3 /g.

10 . The porous shaped body according to claim 1 , wherein the modal pore diameter measured by a mercury intrusion method is from 0.08 μm to 0.7 μm.

11 . The porous shaped body according to claim 1 , wherein the elastic modulus of the porous shaped body is from 1000 mN/m 2 to 12000 mN/m 2 .

12 . The porous shaped body according to claim 1 , wherein the anion concentration in an aqueous solution prepared by immersing the porous shaped body in pure water in an amount 10 times the bulk volume of the same at 70° C. for 1 hour is less than 2.0 mg/L.

13 . The porous shaped body according to claim 1 , wherein the value of absorbance in a UV measurement of an aqueous solution prepared by immersing the porous shaped body in pure water in an amount 10 times the bulk volume of the same at 70° C. for 1 hour is less than 0.2.

14 . The porous shaped body according to claim 1 , wherein the metal ion concentration in an aqueous solution prepared by immersing the porous shaped body in pure water in an amount 10 times the bulk volume of the same at 70° C. for 1 hour is less than 1.0 mg/L.

15 . The porous shaped body according to claim 1 , wherein the pH of an aqueous solution prepared by immersing the porous shaped body in pure water in an amount 10 times the bulk volume of the same at 70° C. for 1 hour is 5 or more, and the amount of change in pH is from 0 to 1.5.

16 . The porous shaped body according to claim 1 , wherein the abrasion rate of the porous shaped body is from 0% to 0.1%.

17 . The porous shaped body according to claim 1 , wherein the inorganic ion adsorbent comprises at least one metal oxide represented by the following Formula (I):
MN x O n ·mH 2 O   (I)

[wherein x is 0 to 3, n is 1 to 4, m is 0 to 6, and M and N are metal elements that are different from each other, and selected from the group consisting of Ti, Zr, Sn, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Si, Cr, Co, Ga, Fe, Mn, Ni, V, Ge, Nb, and Ta]; and/or
at least one metal carbonate represented by the following Formula (III):
Q y R z (CO 3 ) 5 ·tH 2 O   (III)

[wherein y is 1 to 2, z is 0 to 1, s is 1 to 3, t is 0 to 8, and Q and R are metal elements that are different from each other, and selected from the group consisting of Mg, Ca , Sr, Ba, Sc, Mn, Fe, Co, Ni, Ag, Zn, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu].

18 . The porous shaped body according to claim 17 , wherein the metal oxide is selected from the following groups (a) to (c):
(a) hydrated titanium oxide, hydrated zirconium oxide, hydrated tin oxide, hydrated cerium oxide, hydrated lanthanum oxide, and hydrated yttrium oxide; (b) a composite metal oxide between at least one metal element selected from the group consisting of titanium, zirconium, tin, cerium, lanthanum, and yttrium, and at least one metal element selected from the group consisting of aluminum, silicon, and iron; and (c) activated alumina.

19 . The porous shaped body according to claim 17 , wherein the metal carbonate is selected from the following group (d):
(d) magnesium carbonate, calcium carbonate, strontium carbonate, barium carbonate, scandium carbonate, manganese carbonate, iron carbonate, cobalt carbonate, nickel carbonate, silver carbonate, zinc carbonate, yttrium carbonate, lanthanum carbonate, cerium carbonate, praseodymium carbonate, neodymium carbonate, samarium carbonate, europium carbonate, gadolinium carbonate, terbium carbonate, dysprosium carbonate, holmium carbonate, erbium carbonate, thulium carbonate, ytterbium carbonate, and lutetium carbonate.

20 . The porous shaped body according to claim 1 , wherein the organic polymer resin is at least one selected from the group consisting of an ethylene/vinyl alcohol copolymer (EVOH), polyacrylonitrile (PAN), polysulfone (PS), polyethersulfone (PES), poly(vinylidene fluoride) (PVDF), poly(methyl methacrylate) (PMMA), poly(aryl ether sulfone), polypropylene, polystyrene, polycarbonate, cellulose, and cellulose triacetate.

21 - 24 . (canceled)

Assignees

• Asahi Chemical Ind

Inventors

• Kogawa Masashi
• Suzumura Keitaro
• Koyama Yutaka

Classifications

• B01J20/0277 Primary

  Carbonates of compounds other than those provided for in B01J20/043 · CPC title

• B01J47/018 Primary

  Granulation; Incorporation of ion-exchangers in a matrix; Mixing with inert materials · CPC title

• C01F17/235

  Cerium oxides or hydroxides · CPC title

• C02F2101/105

  Phosphorus compounds · CPC title

• C02F2303/16

  Regeneration of sorbents, filters · CPC title