Energy-efficient method for providing a purified phosgene vapor

Patent metadata

Field	Value
Publication number	US-2020180965-A1
Application number	US-201816621944-A
Country	US
Kind code	A1
Filing date	Jun 22, 2018
Priority date	Jun 29, 2017
Publication date	Jun 11, 2020
Grant date	—

Abstract

The present invention relates to a method for producing purified phosgene vapor, comprising the following steps: 1) providing a gas flow obtainable from the reaction of chlorine with carbon monoxide and comprising phosgene and carbon monoxide; 2) one-stage or multi-stage condensation of the gas flow and separation of non-condensable residue gases; 3) one-stage or multi-stage evaporation of the liquid phosgene obtained in step 2) and optional overheating of the produced phosgene vapour, wherein there is an energy integration between one or more of the condensation steps of step 2) and one or more of the evaporation steps in step 3) and the pressure in the last condensation step is between 0.2 and 6.0 bar higher than in the first evaporation step.

First claim

1 . A process for producing purified phosgene vapor,
comprising the steps of 1) providing a gas stream comprising phosgene and carbon monoxide, obtained from the reaction of chlorine with carbon monoxide, 2) condensing the gas stream in one or more stages and removing uncondensable residual gases, 3) evaporating the liquid phosgene obtained in step 2) in one or more stages and optionally superheating the phosgene vapor generated, wherein there is energy integration between one or more of the condensation stages of step 2) and one or more of the evaporation stages in step 3) and the pressure in the last condensation stage is between 0.2 and 6.0 bar higher than in the first evaporation stage.

2 . The process as claimed in claim 1 , wherein the pressure in the last condensation stage is between ≥0.3 and ≤4.5 bar, higher than in the first evaporation stage.

3 . The process as claimed in claim 1 , wherein the gas stream provided in step 1), as well as phosgene, contains ≥1% by volume to ≤20% by volume, of CO.

4 . The process as claimed in claim 1 , characterized in that the condensation in step 2) is effected at a pressure between ≥2.0 bar(a) and ≤10.0 bar(a), preferably between ≥2.5 bar(a) and ≤6.0 bar(a) and more preferably between ≥3.0 bar(a) and ≤5.0 bar(a).

5 . The process as claimed in claim 1 , wherein the condensation in step 2) is effected in at least 2 stages, where the last stage is implemented between ≥−60° C. and ≤0° C.

6 . The process as claimed in claim 1 , wherein the pressure in the evaporation in step 3) is above 1.5 bar(a).

7 . The process as claimed in claim 1 , wherein the uncondensable residual gases from step 2) are subjected to further conversion to phosgene in at least one recombiner with chlorine.

8 . The process as claimed in claim 1 , wherein the energy integration is effected by means of a heat transfer circuit between at least one condenser from step 2) and at least one evaporator from step 3).

9 . An apparatus for producing purified phosgene vapor from the reaction of chlorine with carbon monoxide, comprising
a condensation unit for partial compensation of a gas stream comprising phosgene and carbon monoxide, having at least a first inlet for the gas stream comprising phosgene and carbon monoxide and a first outlet for uncondensed gases, an evaporation unit for evaporating the liquid condensed in the condensation unit, having at least a second outlet for a gaseous phosgene stream, a connecting conduit that departs from the condensation unit and opens into the evaporation unit for conveying the liquid condensed in the condensation unit and a device for transfer of heat from the condensation unit to the evaporation unit, comprising at least one heat transfer surface which is formed by a wall common to the condensation unit and the evaporation unit or at least one secondary circuit having at least one common wall with each of the two spaces and set up to accommodate a heat transfer medium,
wherein the condensation unit is set up such that a positive pressure relative to the evaporation unit of ≥0.2 and ≤6.0 bar is attained.

10 . The apparatus as claimed in claim 9 , wherein a first pressure-retaining device is assigned to the connecting conduit.

11 . The apparatus as claimed in claim 9 , wherein a second pressure-retaining device is assigned to the first outlet for uncondensed gases.

12 . The apparatus as claimed in claim 9 , wherein a third pressure-retaining device is assigned to the second outlet for a gaseous phosgene stream.

13 . The apparatus as claimed in claim 9 , wherein the condensation unit and the evaporation unit are each the tube side of one or more shell and tube heat exchangers.

14 . The apparatus as claimed in claim 13 , wherein the heat transfer device comprises multiple conduits and at least one forced conveying unit, these being arranged, with inclusion of the shell sides of the shell and tube heat exchangers, in such a way as to result in a circuit in which a heat transfer medium can be circulated.

15 . The use of the purified phosgene vapor produced by a process as claimed in claim 1 for phosgenation of amines in the gas phase.

Assignees

• Covestro Deutschland Ag

Inventors

• Merkel Michael
• Ehrig Martin
• Kobylka Manfred
• Morbach Jan
• Carrascosa Mas Maria
• Jens Christian Morten

Classifications

• C07C263/10

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title

• C01B32/80 Primary

  Phosgene · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• B01J2219/00162

  controlling the pressure · CPC title

• B01J7/02

  by wet methods · CPC title