Separation of a phosgene- and hydrogen chloride-comprising stream

Patent metadata

Field	Value
Publication number	US-10252912-B2
Application number	US-201615557187-A
Country	US
Kind code	B2
Filing date	Mar 10, 2016
Priority date	Mar 12, 2015
Publication date	Apr 9, 2019
Grant date	Apr 9, 2019

Abstract

The invention relates to a method of separating a phosgene- and hydrogen chloride-comprising stream (5), wherein said method comprises conveying the hydrogen chloride- and phosgene-comprising stream (5) into a distillation column (1), withdrawing at the bottom of the distillation column (1) a phosgene-comprising stream (7) and withdrawing at the top of the column an essentially hydrogen chloride-comprising stream (9). At least a portion of the stream (9) withdrawn at the top is compressed and at least partially condensed and at least a portion of the liquid and compressed essentially hydrogen chloride-comprising stream is decompressed and recycled into the top of distillation column (1) as reflux.

First claim

The invention claimed is:

1. A method of separating a phosgene- and hydrogen chloride-comprising stream comprising:
conveying the hydrogen chloride- and phosgene-comprising stream into a distillation column,
withdrawing at the bottom of the distillation column a phosgene-comprising stream, and
withdrawing at the top of the distillation column an essentially hydrogen chloride-comprising stream,
wherein at least a portion of the essentially hydrogen-chloride comprising stream withdrawn at the top is compressed and at least partially condensed and at least a portion of the partially condensed liquid and compressed essentially hydrogen chloride-comprising stream is decompressed and recycled into the top of the distillation column as reflux.

2. The method according to claim 1 , wherein the essentially hydrogen chloride-comprising stream is withdrawn at the top at a pressure in the range of from 1 to 10 bar and is compressed to a pressure in the range of from 5 to 25 bar before condensation.

3. The method according to claim 1 , wherein the distillation column comprises a rectifying section and a stripping section and the phosgene- and hydrogen chloride-comprising stream is supplied as a side feed between the rectifying section and the stripping section.

4. The method according to claim 1 , wherein after compression the essentially hydrogen chloride-comprising stream withdrawn from the top is supplied to a rectifying column and the stream obtained at the bottom of the rectifying column is recycled into the top of the distillation column.

5. The method according to claim 1 , wherein in a heat exchanger the at least partially condensed and essentially hydrogen chloride-comprising stream gives off heat to the hydrogen chloride-comprising stream that is to be condensed, this giving-off of heat occurring before said stream is compressed.

6. The method according to claim 1 , wherein in a heat exchanger the uncondensed portion of the essentially hydrogen chloride-comprising stream absorbs heat from the compressed and hydrogen chloride-comprising stream that is to be condensed.

7. The method according to claim 1 , wherein a gas stream is withdrawn from the distillation column via a side takeoff, said stream is at least partially condensed in a first cooler, a liquid fraction is recycled into the distillation column and a gaseous portion is supplied to a second cooler, wherein in the second cooler the gas stream gives off heat to the essentially hydrogen chloride-comprising stream withdrawn from the top.

8. The method according to claim 7 , wherein the essentially hydrogen chloride-comprising stream withdrawn from the top is heated up in a heat exchanger before being fed into the second cooler.

9. The method according to claim 8 , wherein in the heat the essentially hydrogen chloride-comprising stream withdrawn from the top absorbs heat from the condensed stream recycled into the top of the distillation column.

Assignees

• Basf Se

Inventors

• Schelling Heiner
• Mattke Torsten
• Pallasch Hans-Juergen
• Thiele Kai

Classifications

• B01D53/002

  by condensation · CPC title

• C07C263/20

  Separation; Purification · CPC title

• C01B7/0712 Primary

  by distillation · CPC title

• C01B7/0731 Primary

  by extraction · CPC title

• C01B32/80

  Phosgene · CPC title