Method for Synchronously Recovering Metal and Elemental Sulfur

Patent metadata

Field	Value
Publication number	US-2019338426-A1
Application number	US-201816141473-A
Country	US
Kind code	A1
Filing date	Sep 25, 2018
Priority date	May 2, 2018
Publication date	Nov 7, 2019
Grant date	—

Abstract

The present disclosure discloses a method for synchronously recovering metal and elemental sulfur, particularly to a method for synchronously recovering metal and elemental sulfur in sulfide ore tailings, and belongs to the technical field of waste recycling. According to the present disclosure, metal and sulfur element are transferred from a solid phase to a liquid phase in the form of ions respectively by leaching the sulfide ore tailings in an anode chamber, then metal ions are recovered in the form of hydroxide precipitate in a first cathode chamber, and sulfate ions are recovered in the form of elemental sulfur precipitate in a second cathode chamber. The method of the present disclosure can synchronously realize the recovery of metal and elemental sulfur in sulfide ore tailings, such that a metal recovery rate is up to 89.4%, and an elemental sulfur recovery rate is up to 45.7%, meanwhile, a process flow is simple, operating cost is low, recovery rates of metal and sulfur element in tailings are high, corrosion of equipment is alleviated, and secondary pollution is avoid.

First claim

1 . A method for synchronously recovering metal and elemental sulfur in sulfide ore tailings, characterized by:
constructing a three-chamber microbial fuel cell comprising an anode chamber, a first cathode chamber and a second cathode chamber; inoculating a mixed bacterium solution in the anode chamber; placing a sulfide ore tailings solution into the anode chamber of the three-chamber microbial fuel cell; placing pH buffer solutions in the first cathode chamber and the second cathode chamber of the three-chamber microbial fuel cell; operating the three-chamber microbial fuel cell, and oxidizing, by an anode, divalent sulfur in the sulfide ore tailings into sulfate ions to release electrons, and meanwhile, dissolving and leaching metal ions, and transferring metal and sulfur element in the sulfide ore tailings from a solid phase to a liquid phase in the forms of metal ions and sulfate ions, respectively; arranging a closed circuit between the anode and a first cathode, arranging an open circuit between the anode and a second cathode, and under action of an electric field, enabling the metal ions leached from the anode chamber to penetrate through a cation exchange membrane to reach the first cathode chamber, and combining with hydroxyl to be precipitated in a precipitate form, such that the metal element in the tailings is recovered; arranging an open circuit between the anode and the first cathode, arranging a closed circuit between the anode and the second cathode, and under the action of an electric field, enabling sulfate ions leached from the anode chamber to penetrate through an anion exchange membrane to reach the second cathode chamber, and be precipitated out in the form of elemental sulfur, such that the sulfur element in the tailings is recovered; and wherein the anode chamber of the three-chamber microbial fuel cell being located between the first cathode chamber and the second cathode chamber, the anode chamber and the first cathode chamber being separated by the cation exchange membrane, the anode chamber and the second cathode chamber being separated by the anion exchange membrane, and the anode being connected with the first cathode and the second cathode through titanium wires.

2 . The method for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 1 , wherein the mixed bacterium solution is a mixed bacterium solution comprising Thiobacillus thiooxidans and Thiobacillus ferrooxidans.

3 . The method for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 1 , wherein a concentration of the sulfide ore tailings solution placed into the anode chamber is 1 to 100 g/L.

4 . The method for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 1 , wherein a pH value of the pH buffer solution in the first cathode chamber is 4.0 to 5.5.

5 . The method for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 1 , wherein a pH value of the pH buffer solution in the second cathode chamber is 2.9 to 4.1.

6 . The method for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 1 , wherein a metal element recovery process in the first cathode chamber and a sulfur element recovery process in the second cathode chamber are alternately operated.

7 . A device for synchronously recovering metal and elemental sulfur in sulfide ore tailings, wherein the device is used for implementing the method for synchronously recovering metal and elemental sulfur in sulfide ore tailings of claim 1 ; wherein the device comprises an anode chamber ( 1 ), a first cathode chamber ( 2 ) and a second cathode chamber ( 3 ); wherein the anode chamber ( 1 ) is separated from the first cathode chamber ( 2 ) through a cation exchange membrane ( 4 ); wherein the anode chamber ( 1 ) is separated from the second cathode chamber ( 3 ) through an anion exchange membrane ( 5 ); wherein the anode chamber ( 1 ) comprises an anode ( 6 ), a first solution ( 7 ) and a mixed bacterium solution ( 8 ); wherein the first cathode chamber ( 2 ) comprises a first cathode ( 9 ) and a second solution ( 10 ); wherein the second cathode chamber ( 3 ) comprises a second cathode ( 11 ) and a third solution ( 12 ); wherein the anode ( 6 ) is connected with the first cathode ( 9 ) and the second cathode ( 11 ) through a first titanium wire ( 13 ) and a second titanium wire ( 14 ) respectively.

8 . The device for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 7 , wherein the first solution ( 7 ) is an acid solution and/or an alkali solution.

9 . The device for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 7 , wherein the second solution ( 10 ) and the third solution ( 12 ) are pH buffer solutions.

10 . A method for using the device for synchronously recovering metal and elemental sulfur in sulfide ore tailings according to claim 7 in recovering metal and managing environment.

Assignees

• Univ Jiangnan

Inventors

• Li Xiufen
• Qi Xiguang
• Wang Xinhua
• Ren Yueping

Classifications

• H01M8/16 Primary

  Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts · CPC title

• C25B5/00

  Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously · CPC title

• H01M8/22

  Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen · CPC title

• C12P3/00 Primary

  Preparation of elements or inorganic compounds except carbon dioxide {(recovery of carbon dioxides as by-products C12F3/02)} · CPC title

• C22B3/18

  with the aid of microorganisms or enzymes, e.g. bacteria or algae · CPC title