Improved Supercapacitor With Electrolyte

Patent metadata

Field	Value
Publication number	US-2019228919-A1
Application number	US-201716334275-A
Country	US
Kind code	A1
Filing date	Sep 29, 2017
Priority date	Sep 29, 2016
Publication date	Jul 25, 2019
Grant date	—

Abstract

The invention relates to a supercapacitor comprising:
an electrolyte having a first end and a second end opposite the first end, a first electrode in contact with the first end of the electrolyte, and a second electrode in contact with the second end of the electrolyte.

In particular, the electrolyte is made of a solid material that is ion-conductive and electronically insulating.

First claim

1 . A device comprising at least one supercapacitor comprising:
an electrolyte having a first end and a second end opposite the first end, a first electrode in contact with the first end of the electrolyte, and a second electrode in contact with the second end of the electrolyte,
wherein the electrolyte is made of a solid, inorganic, ion-conductive material having an ionic conductivity that is greater than its electronic conductivity,3

and the solid material is crystalline and has a lamellar crystallographic structure formed of planes parallel to each other, ions of the material being able to move between said parallel planes, constituting said ionic conductivity of the material.

2 . The device according to claim 1 , wherein said planes are parallel to a defined direction between the first and second ends.

3 . The device according to claim 1 , wherein said solid material is of the A 2 B 2 O 5 type.

4 . The device according to claim 3 , wherein element A comprises hydrogen.

5 . The device according to claim 3 , wherein element A comprises an alkali.

6 . The device according to claim 5 , wherein the alkali comprises at least one element among rubidium and potassium.

7 . The device according to claim 3 , wherein element B comprises titanium.

8 . The device according to claim 7 , wherein element B comprises a mixture of titanium and niobium.

9 . The device according to claim 3 , wherein said planes have vacancies in oxygen sites.

10 . The device according to claim 1 , wherein it further comprises encapsulation of at least the solid material, in a cell sealed against at least humidity.

11 . The device according to claim 1 , further comprising at least one mechanical actuator in contact with the solid ion-conductive material, and a control unit for controlling the actuator by applying a control signal, and producing:
a first force applied to the solid ion-conductive material, corresponding to a state of locking the electric charges in the electrolyte, and a second force applied to the solid ion-conductive material, corresponding to a state of releasing the electric charges from the electrolyte, a difference of the first force minus the second force corresponding to a stressing of the atomic planes of the material.

12 . The device according to claim 11 , wherein the mechanical actuator comprises a piezoelectric component in contact with the solid ion-conductive material, and wherein the control unit is configured to control the piezoelectric component by application of an electrical signal.

13 . The device according to claim 1 , further comprising at least one member for adjusting the temperature of the solid ion-conductive material, and a control unit for controlling the temperature adjusting member by applying a control signal, and:
bringing the temperature of the solid ion-conductive material to a first temperature, in order to maintain the solid ion-conductive material in a state of locking the electric charge in the electrolyte, or bringing the temperature of the solid ion-conductive material to a second temperature, in order to maintain the solid ion-conductive material in a state of releasing electric charge from the electrolyte, the first temperature being higher than the second temperature.

14 . The device according to claim 1 , wherein the solid ion-conductive material has variable resistivity as a function of an electrical signal previously applied to the solid ion-conductive material,
and wherein the device is configured as memory for storing data, with:
a write mode in which a signal value, selected from at least two values, is applied to the electrolyte for at least a predetermined duration, and
a read mode in which an electrical resistance of the electrolyte is measured in order to determine the signal value previously applied in write mode.

15 . A method for fabricating a device with a supercapacitor, said supercapacitor comprising:
an electrolyte having a first end and a second end opposite the first end, a first electrode in contact with the first end of the electrolyte, and a second electrode in contact with the second end of the electrolyte,
the electrolyte being made of a solid, inorganic, ion-conductive material having an ionic conductivity that is greater than its electronic conductivity,

and the solid material being crystalline with a lamellar crystallographic structure formed of planes parallel to each other, ions of the material being able to move between said parallel planes, constituting said ionic conductivity of the material,
the method comprising a step of activating the material of the electrolyte.

16 . The method according to claim 15 , wherein the activation step comprises thermal annealing in an inert atmosphere at a temperature of about 400K.

17 . The method according to claim 15 , wherein the activation step comprises soaking the solid material in water.

18 . The method according to claim 15 , wherein the activation step comprises the application of a voltage greater than 5 kV/m.

Assignees

• Paris Sciences Lettres Quartier Latin
• Centre Nat Rech Scient
• Univ Pierre Et Marie Curie Paris 6
• Ecole Superieure De Physique Et De Chime Ind De La Ville De Paris

Inventors

• Leridon Brigitte
• Hole Stéphane
• Federicci Rémi

Classifications

• C04B2235/3201

  Alkali metal oxides or oxide-forming salts thereof · CPC title

• H01G11/84

  Processes for the manufacture of hybrid or EDL capacitors, or components thereof · CPC title

• G11C13/02

  using elements whose operation depends upon chemical change {(G11C13/0009 takes precedence)} · CPC title

• C04B35/462

  based on titanates · CPC title

• H01G11/30

  characterised by their material · CPC title