Hydrogen gas production method, and steel production method

Patent metadata

Field	Value
Publication number	US-2019202692-A1
Application number	US-201716329338-A
Country	US
Kind code	A1
Filing date	Aug 25, 2017
Priority date	Sep 1, 2016
Publication date	Jul 4, 2019
Grant date	—

Abstract

A hydrogen gas production method includes a light irradiation step of applying light to a surface of a metal material immersed in water to produce gas containing hydrogen. In this hydrogen gas production method, the metal material contains iron, in the spectrum of the light, a wavelength at which the intensity is maximum is not less than 360 nm and less than 620 nm, and as the gas is produced, at least one of iron oxide and iron hydroxide is formed on the surface.

First claim

1 . A hydrogen gas production method comprising
a light irradiation step of applying light to a surface of a metal material immersed in water to produce gas containing hydrogen, wherein the metal material contains iron, in a spectrum of the light, a wavelength at which an intensity is maximum is not less than 360 nm and less than 620 nm, and as the gas is produced, at least one of iron oxide and iron hydroxide is formed on the surface.

2 . The hydrogen gas production method according to claim 1 , wherein the number of moles of oxygen in the gas is not less than 0 times and less than ½ times the number of moles of the hydrogen.

3 . The hydrogen gas production method according to claim 1 , further comprising a surface roughening step of roughening the surface before the light irradiation step.

4 . The hydrogen gas production method according to claim 3 , wherein the surface roughening step is performed by machining, chemical treatment, or discharge treatment in a liquid.

5 . The hydrogen gas production method according to claim 1 , wherein the metal material comprises pure iron or an iron alloy.

6 . The hydrogen gas production method according to claim 1 , wherein a content of iron in the metal material is 10.0 to 100% by mass based on a total mass of the metal material.

7 . The hydrogen gas production method according to claim 1 , wherein the light is sunlight or simulated sunlight.

8 . The hydrogen gas production method according to claim 1 , wherein the water is at least one selected from the group consisting of pure water, ion exchange water, rain water, tap water, river water, well water, filtered water, distilled water, reverse osmosis water, mineral water, spring water, dam water, and sea water.

9 . The hydrogen gas production method according to claim 1 , wherein pH of the water is 5.00 to 10.0.

10 . The hydrogen gas production method according to claim 1 , wherein electrical conductivity of the water is 0.05 to 80000 μS/cm.

11 . The hydrogen gas production method according to claim 1 , wherein in the light irradiation step, nanocrystals containing at least one of the iron oxide and the iron hydroxide are formed on the surface.

12 . The hydrogen gas production method according to claim 11 , wherein a shape of the nanocrystal is at least one selected from the group consisting of a needle shape, a columnar shape, a rod shape, a tubular shape, a scaly shape, a lump shape, a flower shape, a starfish shape, a branch shape, and a convex shape.

13 . The hydrogen gas production method according to claim 1 , wherein the metal material comprises iron scrap.

14 . A steel production method comprising:
a step of forming at least one of iron oxide and iron hydroxide on a surface of the metal material by the hydrogen gas production method according to claim 1 ; a step of removing at least one of the iron oxide and the iron hydroxide from the surface to recover the at least one of the iron oxide and the iron hydroxide; and a step of producing steel using the metal material from which at least one of the iron oxide and the iron hydroxide has been removed.

Assignees

• Hitachi Chemical Co Ltd
• National Univ Corp Hokkaido Univ

Inventors

• Adachi Shuichiro
• Kitagawa Masaki
• Watanabe Seiichi
• Zhang Lihua
• Okinaka Noriyuki

Classifications

• C25F3/06

  of iron or steel · CPC title

• C01P2004/16

  Nanowires or nanorods, i.e. solid nanofibres with two nearly equal dimensions between 1-100 nanometer · CPC title

• C01G49/04

  Ferrous oxide [FeO] · CPC title

• C01P2004/30

  extending in three dimensions · CPC title

• C01P2002/87

  by chromatography data, e.g. HPLC, gas chromatography · CPC title