Hydrogen production method and hydrogen production system

Patent metadata

Field	Value
Publication number	US-2016318761-A1
Application number	US-201415108465-A
Country	US
Kind code	A1
Filing date	Dec 26, 2014
Priority date	Dec 27, 2013
Publication date	Nov 3, 2016
Grant date	—

Abstract

A hydrogen production method and hydrogen production system using the reaction of water and aluminum, the hydrogen production method and system being capable of continuously generating hydrogen for a long period of time without causing a decrease in the total amount of hydrogen generation. A hydrogen generation system according to one embodiment of the present invention includes aluminum sheet placed in a container and calcium hydroxide contained in the same container. In the hydrogen production system having the previously described configuration, water is poured in the container to dissolve the calcium hydroxide so that an aqueous solution is prepared, and the aluminum sheet is immersed in this aqueous solution. As a result, the hydrogen generation reaction begins, generating hydrogen gas. The amount, rate and duration of the generation of hydrogen gas can be controlled by adjusting the area and thickness of the aluminum sheet.

First claim

1 . A hydrogen production method, wherein hydrogen gas is produced by immersing one or a plurality of aluminum sheets in a vertically set state in an aqueous solution of calcium hydroxide.

2 . The hydrogen production method according to claim 1 , wherein the plurality of the aluminum sheets are placed in the vertically set state, and a spacer is inserted between the neighboring the aluminum sheets.

3 . A hydrogen production method, wherein hydrogen gas is produced by immersing a roll of aluminum in a vertically set state in an aqueous solution of calcium hydroxide, the roll of aluminum including an aluminum sheet wound a plurality of times.

4 . The hydrogen production method according to claim 3 , wherein a spacer is inserted between layers of the roll of aluminum.

5 . The hydrogen production method according to claim 2 , wherein the spacer is made of a water-absorbing material, and particulate calcium hydroxide is held in the spacer.

6 . A hydrogen production system, comprising:
a) a container for holding water; b) a roll of aluminum, placed in a vertically set state in the container, including an aluminum sheet wound a plurality of times; and c) particulate calcium hydroxide contained in the container.

7 . The hydrogen production system according to claim 6 , wherein a spacer is inserted between layers of the roll of aluminum.

8 . The hydrogen production system according to claim 7 , wherein the spacer is made of a water-absorbing material, and particulate calcium hydroxide is held in the spacer.

9 . The hydrogen production system according to claim 6 , further comprising:
d) a folder to be placed in the container, for holding the roll of aluminum.

10 . A hydrogen production method, including steps of:
preparing an aqueous solution by dissolving calcium hydroxide in water; and immersing an aluminum sheet having a total surface area within a range from 150 cm 2 to 3000 cm 2 in the aqueous solution to generate hydrogen gas.

11 . The hydrogen production method according to claim 10 , further including the steps of:
preparing a plurality of kinds of aluminum sheet with different thicknesses; and selecting one kind of aluminum sheet having a thickness corresponding to an amount of hydrogen gas to be generated, and immersing that selected kind of aluminum sheet in the aqueous solution to generate hydrogen gas.

12 . The hydrogen production method according to claim 11 , wherein the plurality of kinds of aluminum sheet have thicknesses ranging from 6.5 μm to 100 μm.

13 . The hydrogen production method according to claim 11 , wherein one kind of aluminum sheet having an appropriate thickness for the amount of hydrogen gas to be generated is selected based on a previously determined correlation between the thickness of the aluminum sheet and the amount of hydrogen generation.

14 . The hydrogen production method according to claim 10 , wherein the aqueous solution further contains glucose.

15 . A hydrogen production system, comprising:
a) a container for holding water; b) an aluminum sheet, placed in the container, having a total surface area within a range from 150 cm 2 to 3000 cm 2 ; and c) particulate calcium hydroxide contained in the container.

16 . The hydrogen production system according to claim 15 , wherein:
the container is provided with a holding part capable of holding a plurality of aluminum sheets in a mutually separated form; and a plurality of the aluminum sheets are held in the holding part.

17 . The hydrogen production system according to claim 16 , wherein:
a plurality of aluminum sheets having an appropriate thickness for an amount of hydrogen gas to be generated among a plurality of kinds of aluminum sheet with different thicknesses are held in the holding part.

18 . The hydrogen production system according to claim 17 , wherein the plurality of kinds of aluminum sheet have thicknesses ranging from 6.5 μm to 100 μm.

19 . The hydrogen production system according to claim 15 , wherein glucose is further contained in the container.

20 . The hydrogen production method according to claim 4 , wherein the spacer is made of a water-absorbing material, and particulate calcium hydroxide is held in the spacer.

Assignees

• Univ Kyoto
• Aquafairy Corp
• Rohm Co Ltd

Inventors

• Hirao Kazuyuki
• Nagashima Kohji
• Ishizaka Hitoshi
• Okada Kazuo
• Saeki Takashi

Classifications

• C01B3/08 Primary

  by reaction of inorganic compounds with metals · CPC title

• B01J7/02

  by wet methods · CPC title

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title