Liquid electrolyte fuel cell component with increased electrolyte storage capacity

Patent metadata

Field	Value
Publication number	US-2018375118-A1
Application number	US-201715634387-A
Country	US
Kind code	A1
Filing date	Jun 27, 2017
Priority date	Jun 27, 2017
Publication date	Dec 27, 2018
Grant date	—

Abstract

An illustrative example fuel cell component includes an electrode substrate including a plurality of pores. A first portion of the substrate includes a liquid electrolyte absorbing material in at least some of the pores in the first portion. Those pores respectively have a first unoccupied pore volume. Pores in a second portion of the substrate respectively have a second unoccupied pore volume. The first unoccupied pore volume is less than the second unoccupied pore volume.

First claim

We claim:

1 . A fuel cell component, comprising
an electrode substrate including a plurality of pores, a first portion of the substrate including a liquid electrolyte absorbing material in at least some of the pores in the first portion of the substrate, the at least some of the pores in the first portion respectively having a first unoccupied pore volume, pores in a second portion of the substrate respectively having a second unoccupied pore volume, the first unoccupied pore volume being less than the second unoccupied pore volume.

2 . The fuel cell component of claim 1 , wherein the liquid electrolyte absorbing material comprises carbon.

3 . The fuel cell component of claim 1 , wherein the liquid electrolyte absorbing material comprises graphite.

4 . The fuel cell component of claim 1 , wherein the first portion of the substrate is impregnated with the liquid electrolyte absorbing material.

5 . The fuel cell component of claim 1 , wherein
the pores in the second portion of the substrate have an average pore size of about 20 micrometers; and the at least some of the pores having the liquid electrolyte absorbing material have an average resulting pore size greater than about 2 micrometers and less than about 20 micrometers.

6 . A method of making a fuel cell component, the method comprising:
forming a substrate having a plurality of pores; and impregnating at least a first portion of the substrate with a liquid electrolyte absorbing material such that at least some of the pores within the first portion of the substrate respectively have a first unoccupied pore volume and the pores in a second portion of the substrate respectively have a second unoccupied pore volume, wherein the first unoccupied pore volume is less than the second unoccupied pore volume.

7 . The method of claim 6 , wherein the liquid electrolyte absorbing material comprises carbon.

8 . The method of claim 6 , wherein the liquid electrolyte absorbing material comprises graphite.

9 . The method of claim 6 , wherein
the pores in the second portion of the substrate have an average pore size of about 20 micrometers; and the at least some of the pores in the first portion having the liquid electrolyte absorbing material have an average resulting pore size greater than about 2 micrometers and less than about 20 micrometers after the impregnating.

10 . A fuel cell, comprising:
a matrix configured to contain a liquid electrolyte; a cathode electrode on one side of the matrix; an anode electrode on an opposite side of the matrix; and a substrate adjacent the cathode electrode, the substrate having a plurality of pores, a first portion of the substrate including a liquid electrolyte absorbing material in at least some of the pores in the first portion of the substrate, the at least some of the pores in the first portion respectively having a first unoccupied pore volume, pores in a second portion of the substrate respectively having a second unoccupied pore volume, the first unoccupied pore volume being less than the second unoccupied pore volume.

11 . The fuel cell of claim 10 , wherein the first portion of the substrate is in a condensation zone of the fuel cell.

12 . The fuel cell of claim 10 , wherein
the matrix includes a plurality of matrix pores; the matrix pores respectively have a third unoccupied pore volume; and the third unoccupied pore volume is less than the first unoccupied pore volume.

13 . The fuel cell of claim 10 , wherein
the at least some of the pores having the liquid electrolyte absorbing material respectively have a first resulting pore size; the pores in the second portion of the substrate respectively have a second pore size that is on average about 20 micrometers; the matrix includes a plurality of matrix pores; the matrix pores respectively have a third pore size that is on average about 1.8 micrometers; the first pore size is greater than the third pore size; and the first pore size is less than the second pore size.

14 . The fuel cell of claim 10 , wherein
the substrate is planar; at least the first portion of the substrate has a through plane conductivity and an in-plane conductivity; and the through plane conductivity is higher than the in-plane conductivity.

15 . The fuel cell of claim 10 , wherein the liquid electrolyte absorbing material comprises carbon.

16 . The fuel cell of claim 10 , wherein the liquid electrolyte absorbing material comprises graphite.

17 . The fuel cell of claim 10 , wherein the first portion of the substrate is impregnated with the liquid electrolyte absorbing material.

18 . The fuel cell of claim 10 , comprising another said substrate adjacent the anode electrode.

19 . The fuel cell of claim 10 , wherein
the first portion of the substrate has a first density; the second portion of the substrate has a second density; and the first density is greater than the second density.

20 . The fuel cell of claim 10 , wherein the first portion of the substrate is located near a cathode exhaust of the fuel cell.

Assignees

• Doosan Fuel Cell America Inc

Inventors

• Patterson Jr Timothy W
• Livaich Eric

Classifications

• H01M4/8605

  Porous electrodes · CPC title

• H01M2300/0008

  Phosphoric acid-based · CPC title

• H01M8/0293 Primary

  Matrices for immobilising electrolyte solutions · CPC title

• H01M8/086

  Phosphoric acid fuel cells [PAFC] · CPC title

• H01M8/0234

  Carbonaceous material · CPC title