Hexagonal boron nitride powder, production method therefor, resin composition and resin sheet

Patent metadata

Field	Value
Publication number	US-2018354792-A1
Application number	US-201716060113-A
Country	US
Kind code	A1
Filing date	Feb 14, 2017
Priority date	Feb 22, 2016
Publication date	Dec 13, 2018
Grant date	—

Abstract

A hexagonal boron nitride powder having an average longer diameter (L) of primary particles in the hexagonal boron nitride powder of 10 μm or less, an average thickness (D) of the primary particles in the hexagonal boron nitride powder of 0.20 μm or more, a ratio of the average longer diameter (L) to the average thickness (D), [L/D], of 3.0 or more and 5.0 or less, and a content of primary particles having a ratio of a longer diameter (l) to a thickness (d), [l/d], of 3.0 or more and 5.0 or less of 25% or more. Also disclosed is a method for producing the hexagonal boron nitride powder, and a resin composition and a resin sheet each containing the hexagonal boron nitride powder.

First claim

1 . A hexagonal boron nitride powder having: an average longer diameter (L) of primary particles in the hexagonal boron nitride powder of 10 μm or less; an average thickness (D) of the primary particles in the hexagonal boron nitride powder of 0.20 μm or more;
a ratio of the average longer diameter (L) to the average thickness (D), [L/D], of 3.0 or more and 5.0 or less; and a content of primary particles having a ratio of a longer diameter (l) to a thickness (d), [l/d], of 3.0 or more and 5.0 or less of 25% or more.

2 . The hexagonal boron nitride powder according to claim 1 , wherein the content is 50% or more.

3 . The hexagonal boron nitride powder according to claim 1 , having a content of CaB 6 of 0.01% by mass or less.

4 . The hexagonal boron nitride powder according to claim 1 , wherein the hexagonal boron nitride powder comprises an aggregate of two or more primary particles, and when the hexagonal boron nitride powder is put through a sieve having an opening of 106 μm, the hexagonal boron nitride powder passing through the sieve has a 50% volume cumulative particle size D 50 (1) of 25 μm or more and 100 μm or less, and a dispersion liquid obtained by dispersing in water the hexagonal boron nitride powder passing through the sieve has a 50% volume cumulative particle size D 50 (2) of 15 μm or less after the dispersion liquid is subjected to an ultrasonic treatment for 3 minutes.

5 . A resin composition comprising:
the hexagonal boron nitride powder according to claim 1 ; and an organic matrix, wherein the composition has a content of the hexagonal boron nitride powder of 10% by volume or more and 90% by volume or less based on a total amount of the hexagonal boron nitride powder and the organic matrix.

6 . A resin sheet comprising the resin composition according to claim 5 or a cured product thereof.

7 . A method for producing the hexagonal boron nitride powder according to claim 1 , the method comprising the following steps 1 to 3:
Step 1: a step of firing a boron carbide powder at 1600° C. or more and 2200° C. or less under a nitrogen gas atmosphere; Step 2: a step of heating a fired product obtained in the step 1 at 500° C. or more and less than 1500° C. under an oxygen gas-containing gas atmosphere, thereby decarbonizing the fired product; and Step 3: a step of firing again a product after decarbonization, the product obtained in the step 2, at 1500° C. or more and 2200° C. or less under a nitrogen gas atmosphere.

8 . The method for producing the hexagonal boron nitride powder according to claim 7 , wherein 10 parts by mass or more and 80 parts by mass or less of a boron compound represented by a formula (B 2 O 3 ).(H 2 O) x wherein X=0 to 3 based on 100 parts by mass of the product after decarbonization is added in the step 3.

Assignees

• Showa Denko Kk

Inventors

• Otsuka Yuki
• Fukasawa Masaru

Classifications

• C08K3/38

  Boron-containing compounds · CPC title

• C08K2003/385

  Binary compounds of nitrogen with boron · CPC title

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title

• C01P2004/51

  Particles with a specific particle size distribution · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title