Polymer compositions comprising a polyaryletherketone and a polycarbonate polymer and formed articles obtainable therefrom

Patent metadata

Field	Value
Publication number	US-2018346714-A1
Application number	US-201615757911-A
Country	US
Kind code	A1
Filing date	Sep 9, 2016
Priority date	Sep 9, 2015
Publication date	Dec 6, 2018
Grant date	—

Abstract

A composition [composition (C)] including: a) an aromatic polycarbonate polymer [PC polymer (P1)]; b) a polaryletherketone polymer [PAEK polymer (P2) and c) an impact modifier [impact modifier (IM)] is herein disclosed. A method for the manufacture of composition (C) and the use of composition (C) for the manufacture of formed articles, in particular parts of electronic devices, more particularly parts of portable or mobile electronic devices are also herein disclosed. Composition (C) may exhibit the following combination of properties: —high impact resistance; —good aesthetic characteristics (colorability); and —high chemical resistance.

First claim

1 - 15 . (canceled)

16 . A melt-mixed composition (C) comprising:
a) an aromatic polycarbonate polymer, PC polymer (P1); b) a polyaryletherketone polymer, PAEK polymer (P2); and c) an impact modifier (IM).

17 . The melt-mixed composition (C) according to claim 16 , wherein the PC polymer (P1) comprises more than 50 wt. % of recurring units (R1), and the recurring units (R1) comprise at least one optionally substituted arylene group and at least one carbonate group (—O—C(═O)—O).

18 . The melt-mixed composition (C) according to claim 16 , wherein the PAEK polymer (P2) comprises more than 50% moles of recurring units (R2) and the recurring units (R2) comprise a —Ar—C(═O)—Ar′— group, wherein Ar and Ar′, equal to or different from each other, are aromatic groups.

19 . The melt-mixed composition (C) according to claim 18 , wherein recurring units (R2) are selected from the group consisting of formulae (J-A) to (J-O):

wherein: each of R′, equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; and
j′ is zero or is an integer from 0 to 4.

20 . The melt-mixed composition (C) according to claim 18 , wherein the recurring units (R2) are selected from formulae (J′-A) to (J′-O):

21 . The melt-mixed composition (C) according to claim 20 , wherein the PAEK polymer (P2) is a homopolymer of recurring units (J′-A).

22 . The melt-mixed composition (C) according to claim 16 further comprising a PAEK polymer (P2*) that is a copolymer of recurring units (J′-A) and (J′-D):

23 . The melt-mixed composition (C) according to claim 16 , wherein the impact modifier (IM) is selected from:
a block copolymer comprising styrene units and rubber monomer units, impact modifier (IM-1); and an acrylic elastomeric copolymer, impact modifier (IM-2).

24 . The melt-mixed composition (C) according to claim 16 comprising an impact modifier (IM-1) which is an ethylene/butylene-styrene triblock copolymer.

25 . The melt-mixed composition (C) according to claim 16 comprising an impact modifier (IM-2) which is selected from the following copolymers:
(i) elastomeric copolymers having a glass transition temperature below 25° C., as measured in accordance to ASTM D 3418, and comprising recurring units derived from one or more than one acrylic monomer selected from the group consisting of alkyl(meth)acrylates and acrylonitrile; and
(ii) core-shell elastomers, including a central core and a shell at least partially surrounding the core, said core and said shell having different monomeric composition, and at least one of them being of elastomeric nature with a glass transition temperature below 25° C., as measured in accordance to according to ASTM D 3418, and at least one of the central core and/or shell comprises recurring units derived from one or more than one acrylic monomer selected from the group consisting of alkyl(meth)acrylates and acrylonitrile.

26 . The melt-mixed composition (C) according to claim 16 further comprising a polyetherimide polymer, PEI polymer (P3), and TiO 2 .

27 . The melt-mixed composition (C) according to claim 26 , wherein the PEI polymer (P3) comprises more than 50 wt. % of recurring units (R3), and the recurring units (R3) comprise at least one aromatic ring, at least one imide group, as such and/or in its amic acid form, and at least one ether group.

28 . The melt-mixed composition (C) according to claim 16 , wherein the recurring units (R3) are units of formula (R3-a′):
(R3-a′)

29 . A method of making the melt-mixed composition (C) according to claim 16 , which comprises melt-mixing:
a) an aromatic polycarbonate polymer, PC polymer (P1); b) a polyaryletherketone polymer, PAEK polymer (P2); c) an impact modifier (IM); and any other optional ingredients at a temperature above the melting temperature of the PAEK polymer (P2) to form a molten mixture; extruding the molten mixture; and cooling the molten mixture.

30 . A formed article comprising the melt-mixed composition (C) according to claim 16 .

31 . The formed article according to claim 30 , wherein the article is part of an electronic device.

Assignees

• Solvay Specialty Polymers Usa

Inventors

• Bushelman Corinne
• El-Hibri Mohammad Jamal

Classifications

• C08L2203/20

  use in electrical or conductive gadgets · CPC title

• B29C47/0004

  Operations & Transport · mapped topic

• C08L2207/53

  Core-shell polymer · CPC title

• C08J3/201

  Pre-melted polymers · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title