Dehydrogenation of ethylbenzene to styrene

Patent metadata

Field	Value
Publication number	US-2018244592-A1
Application number	US-201615769395-A
Country	US
Kind code	A1
Filing date	Oct 24, 2016
Priority date	Oct 28, 2015
Publication date	Aug 30, 2018
Grant date	—

Abstract

A reactor system for dehydrogenation of ethylbenzene to styrene in a given temperature range T upon bringing a reactant stream including ethylbenzene into contact with a catalytic mixture. The reactor system includes a reactor unit arranged to accommodate the catalytic mixture, the catalytic mixture including catalyst particles in intimate contact with a ferromagnetic material, where the catalyst particles are arranged to catalyze the dehydrogenation of ethylbenzene to styrene. The reactor system moreover includes an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalytic mixture is heated to a temperature within the temperature range T by means of the alternating magnetic field. Also, a catalytic mixture and a method of dehydrogenating ethylbenzene to styrene.

First claim

1 . A reactor system for dehydrogenation of ethylbenzene to styrene in a given temperature range T upon bringing a reactant stream comprising ethylbenzene into contact with a catalytic mixture, said reactor system comprising:
a reactor unit arranged to accommodate said catalytic mixture, said catalytic mixture comprising catalyst particles in intimate contact with a ferromagnetic material, where said catalyst particles are arranged to catalyze the dehydrogenation of ethylbenzene to styrene, an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalytic mixture is heated to a temperature within said temperature range T by means of said alternating magnetic field.

2 . A reactor system according to claim 1 , wherein the given temperature range T is the range between about 450° C. and about 650° C.

3 . A reactor system according to claim 1 , wherein the Curie temperature of the ferromagnetic material equals an operating temperature at substantially the upper limit of the given temperature range T of the dehydrogenation reaction.

4 . A reactor system according to claim 1 , wherein the Curie temperature of the ferromagnetic material is above 450° C.

5 . A reactor system according to claim 1 , wherein the induction coil is placed within the reactor unit or around the reactor unit.

6 . A reactor system according to claim 1 , wherein said catalyst particles are supported on said ferromagnetic material.

7 . A reactor system according to claim 6 , wherein said ferromagnetic material comprises one or more ferromagnetic macroscopic supports susceptible for induction heating, where said one or more ferromagnetic macroscopic supports are ferromagnetic at temperatures up to an upper limit of the given temperature range T, where said one or more ferromagnetic macroscopic supports is/are coated with an oxide and where the oxide is impregnated with said catalyst particles.

8 . A reactor system according to claim 1 , wherein catalyst particles and ferromagnetic particles are mixed and treated to provide bodies of catalytic mixture.

9 . A reactor system according to claim 1 , wherein said catalytic mixture comprises bodies of catalyst particles mixed with bodies of ferromagnetic material, wherein the smallest outside dimension of the bodies are in the order of about 1-2 mm or larger.

10 . A reactor system according to claim 1 , wherein the catalytic mixture has a predetermined ratio between said catalyst particles and said ferromagnetic material.

11 . A reactor system according to claim 10 , wherein the predetermined ratio between said catalyst particles and said ferromagnetic material is a predetermined graded ratio varying along a flow direction of said reactor.

12 . A catalytic mixture arranged for catalyzing dehydrogenation of ethylbenzene in a reactor in a given temperature range T upon bringing a reactant stream comprising ethylbenzene into contact with said catalytic mixture, said catalytic mixture comprising catalyst particles in intimate contact with a ferromagnetic material, where said catalyst particles are arranged to catalyze the dehydrogenation of ethylbenzene to styrene.

13 . A catalytic mixture according to claim 12 , wherein the Curie temperature of the ferromagnetic material substantially equals an operating temperature at substantially the upper limit of the given temperature range T of the dehydrogenation reaction.

14 . A catalytic mixture according to claim 12 , wherein the ferromagnetic material is an alloy comprising iron, an alloy comprising iron and chromium, an alloy comprising iron, chromium and aluminum, an alloy comprising iron and cobalt, an alloy comprising iron, aluminum, nickel and cobalt, or magnetite.

15 . A catalytic mixture according to claim 12 , wherein the catalyst particles comprise a carrier impregnated with an iron oxide and/or a potassium oxide, optionally promoted by a cerium oxide and/or a molybdenum oxide.

16 . A catalytic mixture according to claim 12 , wherein said catalyst particles are supported on said ferromagnetic material.

17 . A catalytic mixture according to claim 16 , wherein said ferromagnetic material comprises one or more ferromagnetic macroscopic supports susceptible for induction heating, where said one or more ferromagnetic macroscopic supports are ferromagnetic at temperatures up to an upper limit of the given temperature range T, where said one or more ferromagnetic macroscopic supports is/are coated with an oxide and where the oxide is impregnated with catalyst particles.

18 . A catalytic mixture according to claim 12 , wherein catalyst particles and ferromagnetic particles are mixed and treated to provide bodies of catalytic mixture.

19 . A catalytic mixture according to claim 12 , wherein said catalytic mixture comprises bodies of catalyst particles mixed with bodies of ferromagnetic material.

20 . A catalytic mixture according to claim 12 , wherein the catalytic mixture has a predetermined ratio between said catalyst particles and said ferromagnetic material.

21 . A catalytic mixture according to claim 20 , wherein the predetermined ratio between said catalyst particles and said ferromagnetic material is a predetermined graded ratio varying along a flow direction of said reactor.

22 . A method for dehydrogenating of ethylbenzene in a given temperature range T in a reactor system, said reactor system comprising a reactor unit arranged to accommodate a catalytic mixture, said catalytic mixture comprising catalyst particles in intimate contact with a ferromagnetic material, where said catalyst particles are arranged to catalyze the dehydrogenation of ethylbenzene to styrene, and an induction coil arranged to be powered by a power source supplying alternating current and positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalytic mixture is heated to a temperature within the given temperature range T by means of said alternating magnetic field, said method comprising the steps of:
Generating an alternating magnetic field within the reactor unit upon energization by a power source supplying alternating current, said alternating magnetic field passing through the reactor unit, thereby heating catalytic mixture by induction of a magnetic flux in the material; bringing a reactant stream comprising ethylbenzene into contact with said catalyst particles; heating said reactant stream within said reactor by the generated alternating magnetic field; and letting the reactant stream react in order to provide a styrene product stream to be outlet from the reactor.

23 . A method according to claim 22 , wherein the temperature range T is the range from between about 450° C. and about 650° C. or a subrange thereof.

24 . A method according to claim 22 , wherein the reactant stream is preheated in a heat exchanger prior to step (ii).

25 . A method according to claim 22 , wherein the reactant stream comprises steam and wherein the mass ratio between steam and ethylbenzene in the reactant stream is a ratio of steam/ethylbenzene between 0.5 and 1.5 (wt/wt).

Assignees

• Haldor Topsoe As

Inventors

• Højlund Nielsen Poul Erik
• Nielsen Rasmus Munksgård
• Hansen John Bøgild
• Temel Mckenna Burcin

Classifications

• B01J23/83

  with rare earths or actinides · CPC title

• B01J2208/00442

  Microwaves · CPC title

• B01J23/78

  with alkali- or alkaline earth metals · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• C07C2523/745

  Iron · CPC title