Ultrathin graphene piece, apparatus for preparing ultrathin graphene pieces, method for preparing ultrathin graphene pieces, capacitor, and method of manufacturing capacitor

Patent metadata

Field	Value
Publication number	US-2018244526-A1
Application number	US-201815966539-A
Country	US
Kind code	A1
Filing date	Apr 30, 2018
Priority date	Oct 24, 2012
Publication date	Aug 30, 2018
Grant date	—

Abstract

The problem addressed by the present invention is to provide an apparatus for preparing ultrathin graphene pieces capable of preparing ultrathin graphene pieces in which less than 10 pieces of graphene are overlapped in large quantities, a method for preparing ultrathin graphene pieces capable of preparing the ultrathin graphene pieces with high yield, an ultrathin graphene piece in which less than 10 pieces of graphene are overlapped, a capacitor having high performance by using the ultrathin graphene piece as an electrode, and an efficient method of manufacturing the capacitor. The above-described problem can be solved by using an apparatus 20 for preparing ultrathin graphene pieces, the apparatus comprising: a graphite electrode 21 ; a counter electrode 22 which is made of graphite, a corrosion resistant alloy, or a precious metal; an electrolytic solution 25 in which one end sides of the two electrodes 21 and 22 are immersed; a container 24 which stores the electrolytic solution 25 ; and a power source 28 which is connected to the two electrodes 21 and 22 via wirings 26 and 27 . The apparatus is also provided with a porous filter 23 so as to cover at least the immersed part of the graphite electrode 21 that is immersed in the electrolytic solution 25.

First claim

1 - 22 . (canceled)

23 . A method for preparing an ultrathin graphene piece, comprising sequentially applying:
a first voltage of +0.1 V to +10 V between a graphite electrode used as an anode and a counter electrode used as a cathode for 1 minute to 10 minutes, a second voltage of +1 V to +10 V between the graphite electrode and counter electrode for 1 minute to 10 minutes, a third voltage of +5 V to +15 V between the graphite electrode and counter electrode for 1 hour to 2 hours, and an activation processing step of applying a voltage of +5 V to +15 V between the graphite electrode and counter electrode for 60 minutes to 120 minutes, to obtain an ultrathin graphene piece comprising less than 10 overlapped graphene layers and at least one through hole penetrating a front and a rear side of the graphene piece.

24 . The method for preparing the ultrathin graphene piece according to claim 23 , further comprising, after applying the third voltage, an organic solvent dispersion step of dispersing powder which is obtained by filtering, washing, and drying the electrolytic solution in an organic solvent, and irradiating ultrasonic waves.

25 . The method for preparing the ultrathin graphene piece according to claim 24 , wherein the organic solvent is at least one selected from the group consisting of N-methylpyrrolidone (NMP), dimethylformamide (DMF), N,N-Dimethylacetamide (DMA), γ-buthyrolactone (GBL), and 1,3-dimethyl-2-imidazolidinone (DMEU).

26 . The method for preparing the ultrathin graphene piece according to claim 23 , further comprising, after the activation processing step, a modifying molecule removing step of applying a voltage in a reverse direction with the same value of the voltage applied in the activation processing step.

27 . The method for preparing the ultrathin graphene piece according to claim 26 , further comprising repeating the activation processing step and the modifying molecule removing step at least two times.

28 . The method for preparing the ultrathin graphene piece according to claim 23 ,
wherein the first voltage, the second voltage and the third voltage are applied between the graphite electrode and the counter electrode with an apparatus comprising: the graphite electrode; the counter electrode made of graphite, a corrosion resistant alloy, or a precious metal; an electrolytic solution, wherein one side of the graphite electrode and one side of the counter electrode are immersed in the electrolytic solution; a container storing the electrolytic solution; a power source connected to the graphite electrode and counter electrode via wirings, and a porous filter covering at least the immersed side of the graphite electrode immersed in the electrolytic solution.

Assignees

• Nat Inst Materials Science

Inventors

• Tang Jie
• Cheng Qian
• Shinya Norio
• Qin Luchang

Classifications

• C01B32/184

  Preparation · CPC title

• C25B13/02

  characterised by shape or form · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• H01G11/36

  Nanostructures, e.g. nanofibres, nanotubes or fullerenes · CPC title

• C01B32/19 Primary

  by exfoliation · CPC title