Semiconductor devices and methods of manufacturing
US-12166025-B2 · Dec 10, 2024 · US
US2018174991A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2018174991-A1 |
| Application number | US-201715832905-A |
| Country | US |
| Kind code | A1 |
| Filing date | Dec 6, 2017 |
| Priority date | Dec 7, 2016 |
| Publication date | Jun 21, 2018 |
| Grant date | — |
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A core material including a core and a solder plating layer of a (Sn—Bi)-based solder alloy made of Sn and Bi on a surface of the core. Bi in the solder plating layer is distributed in the solder plating layer at a concentration ratio in a predetermined range of, for example, 91.7% to 106.7%. Bi in the solder plating layer is homogeneous, and thus, a Bi concentration ratio is in a predetermined range over the entire solder plating layer including an inner circumference side and an outer circumference side in the solder plating layer.
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1 . A core material, comprising: a core; and an electric solder plating layer of an (Sn—Bi)-based solder alloy made of Sn and Bi on a surface of the core, the electric solder plating layer being subjected to electric solder plating, wherein the core includes a metal simple substance of Cu, Ni, Ag, Bi, Pb, Al, Sn, Fe, Zn, In, Ge, Sb, Co, Mn, Au, Si, Pt, Cr, La, Mo, Nb, Pd, Ti, Zr, or Mg, or an alloy of two or more types thereof, a metal oxide thereof, or a metal mixed oxide thereof, and when a concentration ratio of Bi contained in the solder plating layer is set to Concentration Ratio (%)=(Measured Value of Bi (mass %)/Target Bi Content (mass %)*100, or Concentration Ratio (%)=(Average Value of Measured Values of Bi (mass %)/Target Bi Content (mass %)*100, the concentration ratio is in a range of 91.4% to 106.7%. 2 . A core material, comprising: a core; and an electric solder plating layer of an (Sn-58Bi)-based solder alloy made of Sn and Bi in amount of 58 mass % on a surface of the core, the electric solder plating layer being subjected to electric solder plating, wherein the core includes a metal simple substance of Cu, Ni, Ag, Bi, Pb, Al, Sn, Fe, Zn, In, Ge, Sb, Co, Mn, Au, Si, Pt, Cr, La, Mo, Nb, Pd, Ti, Zr, or Mg, or an alloy of two or more types thereof, a metal oxide thereof, or a metal mixed oxide thereof, and when a concentration ratio of Bi contained in the solder plating layer is set to Concentration Ratio (%)=(Measured Value of Bi (mass %)/Target Bi Content (mass %)*100, or Concentration Ratio (%)=(Average Value of Measured Values of Bi (mass %)/Target Bi Content (mass %))*100, the concentration ratio is in a range of 91.4% to 108.6%. 3 . A core material, comprising: a core; and an electric solder plating layer of an (Sn-40Bi)-based solder alloy made of Sn and Bi in amount of 40 mass % on a surface of the core, the electric solder plating layer being subjected to electric solder plating, wherein the core includes a metal simple substance of Cu, Ni, Ag, Bi, Pb, Al, Sn, Fe, Zn, In, Ge, Sb, Co, Mn, Au, Si, Pt, Cr, La, Mo, Nb, Pd, Ti, Zr, or Mg, or an alloy of two or more types thereof, a metal oxide thereof, or a metal mixed oxide thereof, and when a concentration ratio of Bi contained in the solder plating layer is set to Concentration Ratio (%)=(Measured Value of Bi (mass %)/Target Bi Content (mass %))*100, or Concentration Ratio (%)=(Average Value of Measured Values of Bi (mass %)/Target Bi Content (mass %))*100, the concentration ratio is in a range of 90% to 107.5%. 4 . A core material, comprising: a core; and an electric solder plating layer of an (Sn-3Bi)-based solder alloy formed of Sn and Bi in amount of 3 mass % on a surface of the core, the electric solder plating layer being subjected to electric solder plating, wherein the core includes a metal simple substance of Cu, Ni, Ag, Bi, Pb, Al, Sn, Fe, Zn, In, Ge, Sb, Co, Mn, Au, Si, Pt, Cr, La, Mo, Nb, Pd, Ti, Zr, or Mg, or an alloy of two or more types thereof, a metal oxide thereof, or a metal mixed oxide thereof, and when a concentration ratio of Bi contained in the solder plating layer is set to Concentration Ratio (%)=(Measured Value of Bi (mass %)/Target Bi Content (mass %)*100, or Concentration Ratio (%)=Average Value of Measured Values of Bi (mass %)/Target Bi Content (mass %)*100, the concentration ratio is in a range of 90% to 106.7%. 5 . The core material according to claim 1 , wherein the core material further includes a base plating layer of one or more elements selected from the group of Ni and Co, between the surface of the core and the electric solder plating layer in this order. 6 . The core material according to claim 1 , wherein a Cu ball or a Cu column is used as the core. 7 . (canceled) 8 . A semiconductor package in which the core material according to claim 1 is used as a solder bump. 9 . A method of forming a bump electrode, characterized in that the method comprises the steps of: mounting on an electrode a core material including a core and an electric solder plating layer of an (Sn—Bi)-based solder alloy made of Sn and Bi on a surface of the core, the electric solder plating layer being subjected to electric solder plating, in which the core includes a metal simple substance of Cu, Ni, Ag, Bi, Pb, Al, Sn, Fe, Zn, In, Ge, Sb, Co, Mn, Au, Si, Pt, Cr, La, Mo, Nb, Pd, Ti, Zr, or Mg, or an alloy of two or more types thereof, a metal oxide thereof, or a metal mixed oxide thereof, and when a concentration ratio of Bi contained in the solder plating layer is set to Concentration Ratio (%)=(Measured Value of Bi (mass %)/Target Bi Content (mass %)*100, or Concentration Ratio (%)=(Average Value of Measured Values of Bi (mass %)/Target Bi Content (mass %))*100, the concentration ratio is in a range of 91.4% to 106.7%; and forming the bump electrode by heating the mounted core material. 10 . The core material according to claim 5 , wherein a Cu ball or a Cu column is used as the core. 11 . The core material according to claim 2 , wherein the core material further includes a base plating layer of one or more elements selected from the group of Ni and Co, between the surface of the core and the electric solder plating layer in this order. 12 . The core material according to claim 2 , wherein a Cu ball or a Cu column is used as the core. 13 . The core material according to claim 11 , wherein a Cu ball or a Cu column is used as the core. 14 . The core material according to claim 3 , wherein the core material further includes a base plating layer of one or more elements selected from the group of Ni and Co, between the surface of the core and the electric solder plating layer in this order. 15 . The core material according to claim 3 , wherein a Cu ball or a Cu column is used as the core. 16 . The core material according to claim 14 , wherein a Cu ball or a Cu column is used as the core. 17 . The core material according to claim 4 , wherein the core material further includes a base plating layer of one or more elements selected from the group of Ni and Co, between the surface of the core and the electric solder plating layer in this order. 18 . The core material according to claim 4 , wherein a Cu ball or a Cu column is used as the core. 19 . The core material according to claim 17 , wherein a Cu ball or a Cu column is used as the core. 20 . A semiconductor package in which the core material according to claim 2 is used as a solder bump. 21 . A semiconductor package in which the core material according to claim 3 is used as a solder bump. 22 . A semiconductor package in which the core material according to claim 4 is used as a solder bump.
by reflowing · CPC title
by plating, e.g. electroless plating or electroplating · CPC title
of outermost layers of multilayered bumps, e.g. material of a coating · CPC title
comprising solid metals or solid metalloids, e.g. PbSn, Ag or Cu · CPC title
of outermost layers of multilayered bumps, e.g. bump coating being only on a part of a bump core · CPC title
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