Resin composition, molded product, and plumbing mechanical component

Patent metadata

Field	Value
Publication number	US-2018079902-A1
Application number	US-201615554214-A
Country	US
Kind code	A1
Filing date	Mar 25, 2016
Priority date	Mar 27, 2015
Publication date	Mar 22, 2018
Grant date	—

Abstract

Disclosed is a resin composition including: a resin mixture (a) containing a polyphenylene ether resin and atactic homopolystyrene in an amount of above 50 mass % and below 94 mass %; a hydrogenated block copolymer (b) obtained by hydrogenating at least part of a block copolymer containing polymer blocks A and B in an amount of 1 to 20 mass %; a functional group-containing compound (c) having a specific functional group in an amount of 0.01 to 0.5 mass %; and a surface-treated inorganic filler (d) in an amount of 5 mass % or more and less than 30 mass %, in which the resin composition does not substantially contain a polymer having a hydrogenation ratio of less than 98% in a conjugated diene compound portion, the component (a-1) has a weight average molecular weight of less than 70,000, and the component (b) has a number average molecular weight of 150,000 to 300,000.

First claim

1 . A resin composition comprising the following components:
a resin mixture (a) containing a component (a-1) and a component (a-2) in a total amount of the components (a-1) and (a-2) of more than 50 mass % and less than 94 mass %, the component (a-1) being a polyphenylene ether resin (a-1) and the component (a-2) being atactic homopolystyrene (a-2); a hydrogenated block copolymer (b) in an amount of 1 mass % or more and 20 mass % or less, the hydrogenated block copolymer (b) being obtained by hydrogenating at least part of a block copolymer containing a polymer block A composed mainly of a vinyl aromatic compound and a polymer block B composed mainly of a conjugated diene compound; a functional group-containing compound (c) in an amount of 0.01 mass % or more and 0.5 mass % or less, the functional group-containing compound (c) having at least one functional group selected from the group consisting of a carboxyl group and a group derived from a carboxyl group; and a surface-treated inorganic filler (d) in an amount of 5 mass % or more and less than 30 mass %,
wherein
the resin composition does not substantially contain a polymer having a hydrogenation ratio of less than 98% in a conjugated diene compound portion,
the component (a-1) has a weight average molecular weight, Mw, of less than 70,000, and
the component (b) has a number average molecular weight, Mn, of 150,000 or more and 300,000 or less.

2 . The resin composition according to claim 1 , wherein the component (a-1) exhibits a melting point.

3 . The resin composition according to claim 1 , wherein the component (a-2) is contained in an amount of 0.1 parts by mass or more and 95 parts by mass or less per 100 parts by mass in total of the components (a-1) and (a-2).

4 . The resin composition according to claim 1 , wherein the component (c) is at least one compound selected from the group consisting of fumaric acid, maleic acid and maleic anhydride, succinic acid, citric acid, aconitic acid, itaconic acid, citraconic acid, and mesaconic acid.

5 . The resin composition according to claim 1 , wherein the component (d) is an inorganic filler surface-treated with aminosilane or epoxysilane.

6 . The resin composition according to claim 1 , wherein
the component (d) is a surface-treated glass fiber, and a ratio of an average fiber length L to an average fiber diameter D of the glass fiber, as expressed by L/D, is from 24 to 50.

7 . The resin composition according to claim 1 , wherein
the component (d) is a surface-treated glass fiber, and an area of peaks at 3570 cm −1 in an FT-IR spectrum, as measured on the surface of the glass fiber using a diffusive reflector, is 9 or less when calcium fluoride powder is used as a blank.

8 . The resin composition according to claim 1 , wherein
the component (d) is a surface-treated glass fiber, and the surface of the glass fiber contains nitrogen atoms in an amount of 1 mass ppm or more and 500 mass ppm or less relative to the mass of the glass fiber.

9 . The resin composition according to claim 8 , wherein
the component (d) is a surface-treated glass fiber, and the surface of the glass fiber contains nitrogen atoms in an amount of 10 mass ppm or more and 80 mass ppm or less relative to the mass of the glass fiber.

10 . A molded product comprising the resin composition as recited in claim 1 .

11 . A plumbing mechanical component formed from the molded product as recited in claim 10 .

12 . The plumbing mechanical component according to claim 11 , wherein the plumbing mechanical component is used in contact with drinking water.

13 . The resin composition according to claim 2 , wherein the component (a-2) is contained in an amount of 0.1 parts by mass or more and 95 parts by mass or less per 100 parts by mass in total of the components (a-1) and (a-2).

14 . The resin composition according to claim 2 , wherein the component (c) is at least one compound selected from the group consisting of fumaric acid, maleic acid and maleic anhydride, succinic acid, citric acid, aconitic acid, itaconic acid, citraconic acid, and mesaconic acid.

15 . The resin composition according to claim 3 , wherein the component (c) is at least one compound selected from the group consisting of fumaric acid, maleic acid and maleic anhydride, succinic acid, citric acid, aconitic acid, itaconic acid, citraconic acid, and mesaconic acid.

16 . The resin composition according to claim 15 , wherein the component (d) is an inorganic filler surface-treated with aminosilane or epoxysilane.

17 . The resin composition according to claim 15 , wherein
the component (d) is a surface-treated glass fiber, and a ratio of an average fiber length L to an average fiber diameter D of the glass fiber, as expressed by L/D, is from 24 to 50.

18 . The resin composition according to claim 15 , wherein
the component (d) is a surface-treated glass fiber, and an area of peaks at 3570 cm −1 in an FT-IR spectrum, as measured on the surface of the glass fiber using a diffusive reflector, is 9 or less when calcium fluoride powder is used as a blank.

19 . The resin composition according to claim 15 , wherein
the component (d) is a surface-treated glass fiber, and the surface of the glass fiber contains nitrogen atoms in an amount of 1 mass ppm or more and 500 mass ppm or less relative to the mass of the glass fiber.

20 . The resin composition according to claim 15 , wherein
the component (d) is a surface-treated glass fiber, and the surface of the glass fiber contains nitrogen atoms in an amount of 10 mass ppm or more and 80 mass ppm or less relative to the mass of the glass fiber.

Assignees

• Asahi Chemical Ind

Inventors

• Sakata Minoru

Classifications

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L25/06

  Polystyrene · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L2201/02

  Flame or fire retardant/resistant · CPC title

• C08L71/123 Primary

  not modified by chemical after-treatment · CPC title