Electrical component comprising insulating resin molded article, and method for stabilizing flame retardance

Patent metadata

Field	Value
Publication number	US-2016372853-A1
Application number	US-201414901215-A
Country	US
Kind code	A1
Filing date	Jun 30, 2014
Priority date	Jul 5, 2013
Publication date	Dec 22, 2016
Grant date	—

Abstract

Provided is an electric component equipped with a live electrical part and an insulating resin molded article that is molded from a thermoplastic resin composition and is in contact with the live electrical part, wherein: the thermoplastic resin composition includes (A) 60 to 80 parts by mass of a polyphenylene ether resin or a mixture of a polyphenylene ether resin and a styrene resin, (B) 60 to 80 parts by mass of a hydrogenated block copolymer, (C) 5 to 30 parts by mass of a flame retardant, and (D) 0.1 to 3 parts by mass of titanium oxide (in an amount corresponding to 100 parts by mass of the total of (A) to (C)).

First claim

1 . An electrical component comprising:
a live electrical part, and an insulating resin molded article in contact with the live electrical part, the molded article being a molded article of a thermoplastic resin composition, wherein the thermoplastic resin composition comprises:
(A) a polyphenylene ether-based resin or a mixed resin of a polyphenylene ether-based resin and a styrene-based resin,
(B) a hydrogenated block copolymer,
(C) a flame retardant, and
(D) titanium oxide,
a content of the (A) is 60 to 80 parts by mass, a content of the (B) is 5 to 30 parts by mass, a content of the (C) is 9 to 25 parts by mass, and a content of the (D) is 0.1 to 3 parts by mass, based on the total of 100 parts by mass of the (A), (B) and (C), and at least one creepage distance, which is a length between the live electrical part and an outer surface part of the electrical component that is electrically separated from the live electrical part by the insulating resin molded article, and which includes a length along a surface of the insulating resin molded article, is 15 mm or more and 40 mm or less.

2 . The electrical component according to claim 1 , wherein the flame retardant (C) is a phosphoric acid-base flame retardant.

3 . The electrical component according to claim 1 , wherein the hydrogenated block copolymer (B) is dispersed in the form of a particle, in the thermoplastic resin composition, and
an average particle size of the dispersed particles of the hydrogenated block copolymer (B) is 0.2 to 1.0 μm.

4 . The electrical component according to claim 1 , wherein a value obtained by dividing a Charpy impact strength (kJ/m 2 ) at 23° C. of the thermoplastic resin composition by a flexural modulus (GPa) at 23° C. of the thermoplastic resin composition (Charpy impact strength/flexural modulus) is 10 or more, and
a burning level of the thermoplastic resin composition (thickness: 1.5 mm), measured according to UL94 vertical burning test, is V-0.

5 . The electrical component according to claim 1 , further comprising 0.01 to 1 part by mass of (E) a carbonate and/or sulfate of an alkaline earth metal based on the total of 100 parts by mass of the (A), (B) and (C).

6 . The electrical component according to claim 1 , wherein the content of the (A) is 65 to 75 parts by mass, the content of the (B) is 10 to 25 parts by mass and the content of the (C) is 10 to 20 parts by mass based on the total of 100 parts by mass of the (A), (B) and (C).

7 . The electrical component according to claim 1 , wherein a content of the (D) is 0.7 to 2.0 parts by mass based on the total of 100 parts by mass of the (A), (B) and (C).

8 . The electrical component according to claim 1 , wherein the mixed resin (A) of the polyphenylene ether-based resin and the styrene-based resin comprises 20% by mass or less of the styrene-based resin.

9 . An electrical component comprising:
a live electrical part, and an insulating resin molded article in contact with the live electrical part, the molded article being a molded article of a thermoplastic resin composition, wherein the thermoplastic resin composition comprises:
(A) a polyphenylene ether-based resin or a mixed resin of a polyphenylene ether-based resin and a styrene-based resin, and
(B) a hydrogenated block copolymer,
a burning level of the thermoplastic resin composition (thickness: 1.5 mm), measured according to UL94 vertical burning test, is V-0, an amount of the thermoplastic resin composition (test piece of 30 mm×30 mm) dropped until the occurrence of tracking in all of 300 V, 400 V, 500 V and 600 V in a tracking resistance test according to IEC60112 is 80 drops or more, and at least one creepage distance, which is a length between the live electrical part and an outer surface part of the electrical component that is electrically separated from the live electrical part by the insulating resin molded article, and which includes a length along a surface of the insulating resin molded article, is 15 mm or more and 40 mm or less.

10 . The electrical component according to claim 1 , for use in a connector for a solar battery.

11 . The electrical component according to claim 1 , for use in a junction box for a solar battery.

12 . The electrical component according to claim 1 , for use in a wall adapter.

13 . A method for stabilizing flame retardance according to UL94 vertical burning test of a thermoplastic resin composition comprising (A) a polyphenylene ether-based resin or a mixed resin of a polyphenylene ether-based resin and a styrene-based resin, (B) a hydrogenated block copolymer and (C) a flame retardant, comprising:
adding (D) a titanium oxide in the thermoplastic resin.

14 . The method for stabilizing flame retardance according to UL94 vertical burning test of a thermoplastic resin composition according to claim 13 , wherein the (C) is a phosphoric acid-base flame retardant.

15 . The method for stabilizing flame retardance according to claim 13 , wherein the flame retardance recited in claim 13 is flame retardance after heat ageing (after 500 hours at 150° C.), according to UL94 vertical burning test.

16 . The method for stabilizing flame retardance according to UL94 vertical burning test of a thermoplastic resin composition according to any one of claims 13 to 15 , wherein, in the thermoplastic resin composition,
a content of the (A) is 60 to 80 parts by mass
a content of the (B) is 5 to 30 parts by mass,
a content of the (C) is 9 to 25 parts by mass, and
a content of the (D) is 0.1 to 3 parts by mass, based on the total of 100 parts by mass of the (A), (B) and (C).

Assignees

• Asahi Kasei Chemicals Corp

Inventors

• Kono Hiroyuki
• Ogata Kazuyuki
• Ishii Tadayuki

Classifications

• C08L53/025

  modified · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08K3/22

  of metals · CPC title

• H01R13/405 Primary

  Securing in non-demountable manner, e.g. moulding, riveting · CPC title

• C08L25/06

  Polystyrene · CPC title