Material for a Thermoelectric Element and Method for Producing a Material for a Thermoelectric Element

Patent metadata

Field	Value
Publication number	US-2017158563-A1
Application number	US-201515327012-A
Country	US
Kind code	A1
Filing date	Jul 7, 2015
Priority date	Jul 17, 2014
Publication date	Jun 8, 2017
Grant date	—

Abstract

A material for a thermoelectric element and a method for producing a material for a thermoelectric element are disclosed. In an embodiment the thermoelectric element includes a material comprising calcium manganese oxide that is partially doped with Fe atoms in positions of Mn atoms.

First claim

1 - 15 . (canceled)

16 . A thermoelectric element comprising:
a material comprising calcium manganese oxide that is partially doped with Fe atoms in positions of Mn atoms.

17 . The thermoelectric element according to claim 16 , wherein a doping with Fe atoms provides a content of z≦20% at the positions of Mn atoms.

18 . The thermoelectric element according to claim 16 , wherein the material is further doped with an element that provides electrons for electrical conductivity in positions of Ca 2+ atoms.

19 . The thermoelectric element according to claim 18 , wherein the element is selected from the group consisting of rare earth metals, Sb 3+ , and Bi 3+ .

20 . The thermoelectric element according to claim 18 , wherein a doping with the element provides a content of 0<y≦0.5 at the positions of Ca atoms.

21 . The thermoelectric element according to claim 16 , wherein the material is further doped with a divalent element in positions of Ca 2+ atoms.

22 . The thermoelectric element according to claim 21 , wherein the divalent element is selected from a group consisting of Mg 2+ , Sr 2+ , Ba 2+ , Zn 2+ , Pb 2+ , Cd 2+ and Hg 2+ .

23 . The thermoelectric element according to claim 21 , wherein a doping with the divalent element provides a content of 0<x≦0.5 at the positions of Ca atoms.

24 . The thermoelectric element according to claim 23 , wherein the doping with the divalent element provides a content of x≧0.05.

25 . The thermoelectric element according to claim 16 , wherein the material is represented by the general formula Ca 1-x-y ISO x DON y Mn 1-z Fe z O n , wherein ISO denotes a divalent element that can replace Ca 2+ in a crystal lattice, wherein DON denotes an element that can replace Ca 2+ in the crystal lattice and provides electrons for electrical conductivity, and wherein 0≦x≦0.5; 0<y≦0.5; 0.0001≦z<0.2; n≧2.

26 . The thermoelectric element according to claim 16 , further comprising a second material based on the composition (Ca 3-x Na x )Co 4 O 9-δ , wherein 0.1≦x≦2.9 and 0<δ≦2.

27 . A method for producing a material for a thermoelectric element, the method comprising: firing a material, wherein, for a maximum temperature T max , T max ≧T S −75° C. is true, wherein T S denotes a melting temperature of the material, and wherein a maintenance time of at least 30 minutes is observed on cooling at a preset temperature.

28 . The method according to claim 27 , wherein the temperature during the maintenance time is in a range of 700° C. to 800° C.

29 . The method according to claim 27 , wherein the maximum temperature is greater than or equal to T S −75° C. for at least 10 hours.

30 . The method according to claim 27 , wherein a cooling rate of less than or equal to 1° C./min is used in cooling.

Assignees

• Epcos Ag

Inventors

• Gruenbichler Hermann
• Wang Yongli
• Schweinzger Manfred

Classifications

• C04B35/62675

  characterised by the treatment temperature · CPC title

• C04B2235/3274

  Ferrites · CPC title

• C04B2235/3268

  Manganates, manganites, rhenates or rhenites, e.g. lithium manganite, barium manganate, rhenium oxide · CPC title

• C04B2235/3298

  Bismuth oxides, bismuthates or oxide forming salts thereof, e.g. zinc bismuthate · CPC title

• C04B2235/661

  Multi-step sintering · CPC title