Systems and processes for making a poly(vinyl acetal) resin with enhanced particle transport and recovery

Patent metadata

Field	Value
Publication number	US-2016347885-A1
Application number	US-201514725933-A
Country	US
Kind code	A1
Filing date	May 29, 2015
Priority date	May 29, 2015
Publication date	Dec 1, 2016
Grant date	—

Abstract

Processes and systems for making a poly(vinyl acetal) resin particles are provided. The processes and systems described herein utilize one or more methods, including, for example, slurry dilution and/or filtration of various process streams, to optimize the transport and recovery of the poly(vinyl acetal) resin particles. Systems and processes described herein facilitate increased production of the final resin product by minimizing product loss and maximizing on-line operation time and production flexibility.

First claim

What is claimed is:

1 . A process for producing a poly(vinyl acetal) resin, said process comprising:
(a) reacting a poly(vinyl alcohol) with at least one aldehyde to produce a reaction slurry comprising a plurality of poly(vinyl acetal) resin particles; (b) contacting at least a portion of said poly(vinyl acetal) resin particles with a wash liquid to thereby provide a plurality of washed particles and a spent wash liquid; (c) withdrawing at least a portion of said washed particles and spent wash liquid from said wash vessel as a solids-containing slurry; (d) passing a portion of said solids-containing slurry through at least one filtration device to thereby provide a solids-enriched retentate stream and a solids-depleted permeate stream, wherein said passing increases the concentration of solids in said solids-enriched retentate stream as compared to the solids content of said solids-containing slurry introduced into said filtration device; and (d) reintroducing at least a portion of said solids-enriched retentate stream back into said process at a location at or downstream of said contacting step.

2 . The process of claim 1 , wherein said passing is performed continuously and wherein the average cross-flow velocity of said portion of said solids-containing slurry passing through said filtration device is at least 0.5 ft/s, and wherein the maximum cross-membrane pressure drop is not more than 10 psi/ft 2 .

3 . The process of claim 1 , wherein the difference between the total solids content of said solids-enriched retentate stream and said portion of said solids-containing slurry introduced into said filtration device is not more than 5 weight percent.

4 . The process of claim 1 , wherein said solids-enriched retentate stream comprises at least 60 percent of the total amount of solids present in said portion of said solids-containing slurry introduced into said filtration device.

5 . The process of claim 1 , wherein said filtration device is a multi-stage filtration device comprising two or more filtration stages.

6 . The process of claim 1 , further comprising, passing at least a portion of said washed particles and/or said spent wash liquid within said wash vessel through at least one filtration device located within the interior of said wash vessel to provide a solids-enriched retentate phase and a solids-depleted permeate phase, wherein at least a portion of said solids-depleted permeate phase is withdrawn from said wash vessel.

7 . The process of claim 1 , further comprising reintroducing at least a portion of said solids-depleted permeate stream back into said process at a location at or upstream of said contacting step.

8 . The process of claim 1 , wherein during at least a portion of said passing, the average temperature of said solids-containing slurry introduced into said filtration device is at least 40° C.

9 . A process for producing a poly(vinyl acetal) resin, said process comprising:
(a) introducing a reaction slurry comprising a plurality of poly(vinyl acetal) resin particles into a wash vessel; (b) contacting at least a portion of said poly(vinyl acetal) resin particles in said wash vessel via contact with at least one wash liquid; (c) removing a solids-containing slurry from said wash vessel; (d) passing at least a portion of said solids-containing slurry through at least one filtration element to provide a solids-enriched stream and a solids-depleted stream; and (e) recovering at least a portion of the poly(vinyl acetal) resin solids in said solids-enriched stream.

10 . The process of claim 9 , wherein the difference between the total solids content of said solids-containing slurry and the total solids content of said solids-enriched slurry is not more than 5 weight percent.

11 . The process of claim 9 , wherein said solids-containing slurry has a total solids content of at least 5 weight percent, based on the total weight of the stream, and said solids-depleted stream has a total solids content of less than 1 weight percent, based on the total weight of the stream.

12 . The process of claim 11 , wherein the average particle size of the poly(vinyl acetal) resin particles present in said solids-depleted stream is less than 30 microns.

13 . The process of claim 9 , wherein the average permeate flux across said filtration element is at least 0.2 gpm/ft 2 .

14 . The process of claim 9 , wherein the temperature of said reaction slurry introduced into said wash vessel is at least 60° C.

15 . The process of claim 9 , wherein said poly(vinyl acetal) resin particles comprise poly(vinyl n-butyral) resin particles and wherein, during at least a portion of said passing, the average temperature of said slurry passed through said filtration element is at least 40° C.

16 . The process of claim 9 , further comprising reintroducing at least a portion of said solids-enriched stream into said wash vessel, and wherein said recovering comprises separating at least a portion of the washed poly(vinyl acetal) resin particles from at least a portion of said wash liquid in a solid-liquid separator to provide a solids-enriched material, and drying said solids-enriched material in a dryer to provide dried resin particles.

17 . A system for producing a poly(vinyl acetal) resin, said system comprising:
a reaction vessel for reacting a poly(vinyl alcohol) and at least one aldehyde to form a reaction slurry comprising solid poly(vinyl acetal) resin particles, wherein said reaction vessel comprises at least one reactor inlet and at least one reactor outlet; a wash vessel for receiving at least a portion of said reaction slurry from said reaction vessel and for contacting at least a portion of said poly(vinyl acetal) resin particles with a wash liquid, wherein said wash vessel comprises a slurry inlet, a slurry outlet, a wash fluid inlet, and a wash fluid outlet; a wash liquid line for introducing said wash liquid into said wash vessel, wherein said wash liquid line is in fluid flow communication with said wash fluid inlet of said wash vessel; a washed slurry line for removing at least a portion of the solids-containing washed slurry from the wash vessel, wherein said washed slurry line is in fluid flow communication with said slurry outlet of said wash vessel; and at least one filtration device external to said wash vessel for removing at least a portion of said poly(vinyl acetal) resin particles from the washed slurry, wherein said filter element comprises a fluid inlet, a solids-enriched fluid outlet, a solids-depleted fluid outlet, and at least one filter surface, wherein said fluid inlet of said filtration device is in fluid flow communication with said slurry outlet of said wash vessel via said washed slurry line, and wherein said filter surface is disposed between said fluid inlet and said solids-depleted fluid outlet within said filtration device, wherein said filter surface is oriented generally parallel to the direction of flow of said washed slurry as it passes from said fluid inlet to said solids-enriched fluid outlet in said filtration device.

18 . The system of claim 17 , further comprising an agitation device at least partially disposed within said wash vessel, wherein said agitation device comprises at least one impeller and is configured to agitate said reaction slurry within said wash vessel.

19 . The system of claim 17 , further comprising at least one filter element disposed within the interior of said wash vessel for removing at least a portion of said poly(vinyl acetal) resin particles from

Assignees

• Solutia Inc

Inventors

• Parker Kenny
• D'Haene Pol
• Ukidwe Nandan

Classifications

• C08F116/38 Primary

  by a acetal or ketal radical · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• B01J19/18 Primary

  Stationary reactors having moving elements inside (B01J19/08, B01J19/26 take precedence) · CPC title

• C08F8/28

  Condensation with aldehydes or ketones · CPC title