High-performance, filler-reinforced, recyclable composite materials

Patent metadata

Field	Value
Publication number	US-2016304348-A1
Application number	US-201615195763-A
Country	US
Kind code	A1
Filing date	Jun 28, 2016
Priority date	Aug 5, 2014
Publication date	Oct 20, 2016
Grant date	—

Abstract

Polyhexahydrotriazine (PHT) and polyhemiaminal (PHA) materials form highly cross-linked polymers which can be used as binder resins in composite materials. A filler element functionalized with a primary amine group can be covalently bonded to the PHA/PHT polymer resins. Example filler elements include, without limitation, carbon nanotubes, silica materials, carbon and glass fibers, and nanoparticles. Filler materials are incorporated into polymeric materials to improve the mechanical strength or other characteristics of the polymeric material for various applications. Typical composite materials use thermosetting materials that, once set, are intractable. PHT and PHA materials can be reverted to starting materials by exposure to acids. Thus, composite components formed using these materials are recyclable.

First claim

What is claimed is:

1 . A method of recycling a composite component, comprising:
obtaining a composite component including:
a polyhexahydrotriazine (PHT) resin, and
a filler element covalently bonded to the PHT resin; and
exposing the composite component to an acid.

2 . The method of claim 1 , further comprising:
recovering the filler element.

3 . The method of claim 1 , wherein the filler element is a nanoparticle.

4 . The method of claim 1 , wherein the filler element is a carbon fiber.

5 . The method of claim 1 , wherein the filler element is a glass fiber.

6 . The method of claim 1 , wherein the filler element is a single-wall nanotube.

7 . The method of claim 1 , wherein the filler element is a fullerene.

8 . The method of claim 1 , wherein the PHT resin comprises:
a plurality of trivalent hexahydrotriazine groups having the structure:

and
a plurality of divalent bridging groups of formula:

wherein L′ is a divalent linking group selected from the group consisting of —O—, —S—, —N(R′)—, —N(H)—, —R″—, and combinations thereof, wherein R′ comprises at least 1 carbon and R″ comprises at least one carbon, each starred bond of a given hexahydrotriazine group is covalently linked to a respective one of the divalent bridging groups or the filler element, and each starred bond of a given bridging group is linked to a respective one of the hexahydrotriazine groups.

9 . The method of claim 8 , wherein L′ is one of —O— and —S—.

10 . The method of claim 8 , wherein L′ is —N(R′)—, wherein R′ is selected from the group consisting of methyl, ethyl, propyl, isopropyl, phenyl, and combinations thereof.

11 . The method of claim 8 , wherein L′ is —CH 2 —.

12 . The method of claim 8 , wherein L′ is 9-fluorenylidenyl.

13 . The method of claim 8 , wherein the PHT resin includes a trivalent bridging group.

14 . The method of claim of claim 8 , wherein the PHT resin includes least one diluent group selected from the group consisting of

and combinations thereof, wherein W′ is a monovalent radical selected from the group consisting of —H, —NH(R 1 ), —N(R 2 )(R 3 ), —OH, —O(R 4 ), —S(R 5 ), —P(R 6 ), —R 7 , —CF 3 , and combinations thereof, wherein R 1 , R 2 , R 3 , R 4 , R 5 , R6, and R 7 each comprise at least 1 carbon and each of R 1 -R 7 may be independent or the same, and the starred bond in each of the at least one diluents group linked to a nitrogen of a hexahydrotriazine group of the PHT resin.

15 . A method of recycling a composite component, comprising:
obtaining a composite component including:
a polyhexahydrotriazine (PHT) resin, and
a carbon nanotube covalently bonded to the PHT resin; and
exposing the composite component to an acid.

17 . The method of claim 15 , further comprising:
recovering the carbon nanotube.

18 . The method of claim 15 , wherein the PHT resin comprises:
a plurality of trivalent hexahydrotriazine groups having the structure:

and
a plurality of divalent bridging groups of formula:

wherein L′ is a divalent linking group selected from the group consisting of —O—, —S—, —N(R′)—, —N(H)—, —R″—, and combinations thereof, wherein R′ comprises at least 1 carbon and R″ comprises at least one carbon, each starred bond of a given hexahydrotriazine group is covalently linked to a respective one of the divalent bridging groups or the filler element, and each starred bond of a given bridging group is linked to a respective one of the hexahydrotriazine groups.

Assignees

• IBM

Inventors

• Boday Dylan J
• Garcia Jeannette M
• Hedrick James L
• Wojtecki Rudy J

Classifications

• Y02P20/582

  Recycling of unreacted starting or intermediate materials · CPC title

• D01F9/12

  Carbon filaments; Apparatus specially adapted for the manufacture thereof · CPC title

• C08J11/00

  Recovery or working-up of waste materials (recovery of plastics B29B17/00; polymerisation processes involving purification or recycling of waste polymers or their depolymerisation products C08B, C08C, C08F, C08G, C08H) · CPC title

• C08J2379/04

  Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors · CPC title

• C03C13/00

  Fibre or filament compositions (manufacture of fibres or filaments C03B37/00) · CPC title