Conductive adhesive and method of forming same

Patent metadata

Field	Value
Publication number	US-9446539-B2
Application number	US-201113309845-A
Country	US
Kind code	B2
Filing date	Dec 2, 2011
Priority date	Dec 2, 2011
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

A method of forming a conductive adhesive includes condensation-polymerizing a carrier onto a plurality of carbon nanotubes each disposed on a substrate and having a first end and a second end spaced opposite the first end. The carrier is spaced apart from the substrate so that each of the plurality of carbon nanotubes extends continuously through the carrier such that the first end and the second end are spaced apart from the carrier. After condensation-polymerizing, the method includes removing the substrate from the plurality of carbon nanotubes without removing the carrier from the plurality of carbon nanotubes to thereby form the conductive adhesive. A conductive adhesive for removably joining a first surface and a second surface is also disclosed.

First claim

The invention claimed is:

1. A method of forming a conductive adhesive for removably joining a first surface and a second surface, the method comprising:
condensation-polymerizing a carrier onto a plurality of carbon nanotubes, each of the carbon nanotubes being disposed on a substrate and having a first portion with a first end and a second portion with a second end spaced opposite the first end, the condensation-polymerizing including:
forming a first layer of a first polymer precursor on the first portions of the carbon nanotubes,
forming a second layer of a second polymer precursor on the second portions of the carbon nanotubes, and
reacting the first polymer precursor with the second polymer precursor at an interface between the first layer and the second layer to create the carrier such that the carrier is spaced apart from the substrate, each of the plurality of carbon nanotubes extends continuously through the carrier, and the first ends and the second ends are spaced apart from the carrier,

removing unreacted portions of the first and second layers; and
after condensation-polymerizing, removing the substrate from the plurality of carbon nanotubes without removing the carrier from the plurality of carbon nanotubes to thereby form the conductive adhesive.

2. The method of claim 1 , wherein condensation-polymerizing includes surrounding a portion of each of the plurality of carbon nanotubes with the carrier.

3. The method of claim 2 , wherein condensation-polymerizing includes forming the carrier from a polyamide between adjacent ones of the plurality of carbon nanotubes.

4. The method of claim 1 , wherein the first polymer precursor includes a dicarboxylic acid and the second polymer precursor includes a diamide that is reactive with the first polymer precursor.

5. The method of claim 1 , wherein each of the plurality of carbon nanotubes has a length, and further wherein condensation-polymerizing includes forming the carrier at about a midpoint of the length so that the carrier does not contact the substrate.

6. The method of claim 5 , further including attaching the conductive adhesive to the first surface, wherein the first end of each of the plurality of carbon nanotubes is attached to the first surface.

7. The method of claim 6 , further including, after attaching the conductive adhesive to the first surface, attaching the second end of each of the plurality of carbon nanotubes to the second surface.

8. The method of claim 7 , further including separating the first surface or the second surface from the conductive adhesive.

9. The method of claim 8 , further including, after separating, reattaching the separated first surface or second surface to the conductive adhesive to thereby removably join the first surface and the second surface.

10. The method of claim 1 , further including, before condensation-polymerizing, depositing the plurality of carbon nanotubes onto the substrate.

11. The method of claim 10 , wherein depositing includes aligning adjacent ones of the plurality of carbon nanotubes substantially parallel to one another and substantially perpendicular to the substrate.

12. A method of forming a conductive adhesive for removably joining a first surface and a second surface, the method comprising:
applying a dicarboxylic acid onto a plurality of carbon nanotubes, each disposed on a substrate and having a first end and a second end spaced opposite the first end, to form a first layer adjacent to the substrate;
applying a diamide onto the first layer to form a second layer, wherein the first layer is sandwiched between the second layer and the substrate;
after applying the diamide, condensation-polymerizing a carrier onto the plurality of carbon nanotubes such that the carrier is spaced apart from the substrate, each of the plurality of carbon nanotubes extends continuously through the carrier, and the first end and the second end are spaced apart from the carrier;
after condensation-polymerizing, washing unreacted portions of the diamide from the carrier without removing the carrier from the plurality of carbon nanotubes;
after washing, removing the substrate from the plurality of carbon nanotubes without removing the carrier from the plurality of carbon nanotubes; and
after removing, washing unreacted portions of the dicarboxylic acid from the carrier without removing the carrier from the plurality of carbon nanotubes to thereby form the conductive adhesive.

13. The method of claim 1 , wherein forming the first layer includes disposing the first polymer precursor in contact with the substrate, and forming the second layer includes disposing the second polymer precursor in contact with first layer such that the first layer is sandwiched between the substrate and the second layer.

14. The method of claim 1 , wherein the substrate is removed before the second layer is removed.

Assignees

• Christian Benjamin R
• Abell Jeffrey A
• Weber Jessica E
• Gm Global Tech Operations Llc

Inventors

• Christian Benjamin R
• Abell Jeffrey A
• Weber Jessica E

Classifications

• C09J9/02

  Electrically-conducting adhesives · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B29C39/006 Primary

  Monomers or prepolymers (by reaction injection moulding B29C67/246) · CPC title

• Y10T428/23979

  Particular backing structure or composition · CPC title

• Y10T428/30

  Self-sustaining carbon mass or layer with impregnant or other layer · CPC title