Modified oxazine resin and use of a composition comprising the same

Patent metadata

Field	Value
Publication number	US-2016297779-A1
Application number	US-201615072416-A
Country	US
Kind code	A1
Filing date	Mar 17, 2016
Priority date	Apr 10, 2015
Publication date	Oct 13, 2016
Grant date	—

Abstract

The present disclosure is to provide a modified oxazine compound and use of a composition comprising the same.

First claim

1 . A modified oxazine compound having a structure represented by the following formula (1) or formula (2):

wherein
R is an aliphatic hydrocarbyl group or an aryl group;
R′ is selected from the group consisting of imino, allyl, a C 1 -C 20 aliphatic hydrocarbyl group, dicyclopentadienyl, and an aryl group;
A is selected from the group consisting of —CH 2 —, —CH(CH 3 )—, and —C(CH 3 ) 2 — and is the same or different at each occurrence;
B is an arylene group;
m is 0 to 4;
n is 0 to 1; and
a1, a2, a3 and b are each independently 0 or 1.

2 . The modified benzoxazine compound as claimed in claim 1 , which is selected from the group consisting of formula (6), formula (7), formula (8), formula (9), and formula (10):

3 . A method of producing a modified benzoxazine compound comprising: reacting a phthalaldehyde compound with an aminophenol compound in a solvent to form an azomethine group-containing phenol compound; and reacting the azomethine group-containing phenol compound with a primary amine and formaldehyde.

4 . The method as claimed in claim 3 , wherein the phthalaldehyde compound is one represented by formula (3):

wherein
R is an aliphatic hydrocarbyl group or an aryl group;
A is selected from the group consisting of —CH 2 —, —CH(CH 3 )—, and —C(CH 3 ) 2 — and is the same or different at each occurrence;
B is an arylene group;
m is 0 to 4; and
a1, a2, a3 and b are each independently 0 or 1.

5 . The method as claimed in claim 3 , wherein the aminophenol compound is one represented by formula (4) or formula (5):

wherein
R are each independently hydrogen, an aliphatic hydrocarbyl group or an aryl group;
A is selected from the group consisting of —CH 2 —, —CH(CH 3 )—, —C(CH 3 ) 2 —, an aliphatic hydrocarbylene group, and an arylene group; and
n is 0 or 1.

6 . The method as claimed in claim 3 , wherein the primary amine is one having a general formula: R′NH 2 , wherein R′ is selected from the group consisting of imino, allyl, a C 1 -C 20 aliphatic hydrocarbyl group, dicyclopentadienyl, and an aryl group.

7 . A resin composition, comprising: (A) a modified oxazine compound according to claim 1 or a prepolymer thereof or a mixture thereof; and (B) a crosslinking agent.

8 . The resin composition as claimed in claim 7 , wherein the crosslinking agent (B) is selected from the group consisting of an epoxy resin, a cyanate resin, isocyanate, a polyphenylene oxide resin, maleimide, a polyamide, a polyimide, a phenoxy resin, a styrene-maleic anhydride copolymer, a polyester, a polyolefin, a phenol resin, an amine-based curing agent, an anhydride-based curing agent, diallyl bisphenol A, and a combination thereof.

9 . The resin composition as claimed in claim 7 , further comprising a modifier selected from the group consisting of flame retardant, curing accelerator, inorganic filler, surfactant, solvent, and toughening agent.

10 . An article made from the resin composition according to claims 7 , wherein the article is a resin film, a prepreg, a laminate or a printed circuit board.

Assignees

• Elite Material Co Ltd

Inventors

• Hsieh Chen-Yu
• SHIH Hui-Ting

Classifications

• C08F222/08

  with vinyl aromatic monomers · CPC title

• C08L35/06

  Copolymers with vinyl aromatic monomers · CPC title

• C07D265/16

  with only hydrogen or carbon atoms directly attached in positions 2 and 4 · CPC title

• C08J2379/04

  Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors · CPC title

• C07D265/12 Primary

  condensed with carbocyclic rings or ring systems · CPC title