Lithium-sulfur secondary battery

US2016285135A1 · US · A1

Patent metadata
FieldValue
Publication numberUS-2016285135-A1
Application numberUS-201415032830-A
CountryUS
Kind codeA1
Filing dateOct 15, 2014
Priority dateDec 3, 2013
Publication dateSep 29, 2016
Grant date

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  1. Title

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Abstract

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Provided is a lithium-sulfur secondary battery capable of suppressing diffusion of a polysulfide eluted into an electrolyte, into a negative electrode and capable of suppressing lowering of a charge-discharge efficiency. In a lithium-sulfur secondary battery (B) of the invention, having a positive electrode (P) including a positive electrode active material containing sulfur, a negative electrode (N) including a negative electrode active material containing lithium, and a separator (5) which is disposed between the positive electrode and the negative electrode and which allows a lithium ion of an electrolyte (L) to pass therethrough, a cation-exchange membrane (CE) is formed on one of a positive electrode-side surface of the separator and a negative electrode-side surface thereof.

First claim

Opening claim text (preview).

1 . A lithium-sulfur secondary battery comprising: a positive electrode including a positive electrode active material containing sulfur; a negative electrode including a negative electrode active material containing lithium; and a separator which is disposed between the positive electrode and the negative electrode and which allows a lithium ion of an electrolyte to pass therethrough, characterized in that a cation-exchange membrane is formed on at least one of a positive electrode-side surface of the separator and a negative electrode-side surface of the separator. 2 . The lithium-sulfur secondary battery according to claim 1 , wherein the cation-exchange membrane is selected from a perfluorosulfonic acid polymer, an aromatic polyether polymer, and a hydrocarbon block copolymer containing a hydrophobic segment containing no sulfonic acid group and a hydrophilic segment containing a sulfonic acid group. 3 . The lithium-sulfur secondary battery according to claim 2 , wherein the hydrophobic segment is formed of a polyether sulfone or a polyether ketone, and the hydrophilic segment is formed of a sulfonated polyether sulfone or a sulfonated polyether ketone. 4 . The lithium-sulfur secondary battery according to claim 1 , wherein the positive electrode includes: a current collector; a plurality of carbon nanotubes which are grown on a surface of the current collector such that the current collector-surface side serves as a base end and so as to be oriented in a direction perpendicular to the surface of the current collector; and sulfur covering a surface of each of the carbon nanotubes. 5 . The lithium-sulfur secondary battery according to claim 2 , wherein the positive electrode includes: a current collector; a plurality of carbon nanotubes which are grown on a surface of the current collector such that the current collector-surface side serves as a base end and so as to be oriented in a direction perpendicular to the surface of the current collector; and sulfur covering a surface of each of the carbon nanotubes. 6 . The lithium-sulfur secondary battery according to claim 3 , wherein the positive electrode includes: a current collector; a plurality of carbon nanotubes which are grown on a surface of the current collector such that the current collector-surface side serves as a base end and so as to be oriented in a direction perpendicular to the surface of the current collector; and sulfur covering a surface of each of the carbon nanotubes. 7 . The lithium-sulfur secondary battery according to claim 2 , wherein the cation-exchange membrane is polytetrafluoroethylene perfluoro sulfonic acid.

Assignees

Inventors

Classifications

  • Electricity · mapped topic

  • Sulfides · CPC title

  • characterised by shape or form · CPC title

  • H01M10/399Primary

    Cells with molten salts · CPC title

  • containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres · CPC title

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What does patent US2016285135A1 cover?
Provided is a lithium-sulfur secondary battery capable of suppressing diffusion of a polysulfide eluted into an electrolyte, into a negative electrode and capable of suppressing lowering of a charge-discharge efficiency. In a lithium-sulfur secondary battery (B) of the invention, having a positive electrode (P) including a positive electrode active material containing sulfur, a negative electro…
Who is the assignee on this patent?
Ulvac Inc
What technology area does this patent fall under?
Primary CPC classification H01M10/399. Mapped technology areas include Electricity.
When was this patent published?
Publication date Thu Sep 29 2016 00:00:00 GMT+0000 (Coordinated Universal Time) (A1). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 8 related publications on this page (citations in our corpus or others sharing the same primary CPC).