Method for Producing a Solid Oxide Fuel Cell

Patent metadata

Field	Value
Publication number	US-2016254561-A1
Application number	US-201615149746-A
Country	US
Kind code	A1
Filing date	May 9, 2016
Priority date	May 18, 2011
Publication date	Sep 1, 2016
Grant date	—

Abstract

Provided is a method for producing a solid oxide fuel cell comprising the following: a fuel gas flow path, a fuel electrode layer provided around the fuel gas flow path and containing an iron group element and a ceramic, a solid electrolyte layer provided around the fuel electrode layer, and an air electrode layer provided around the solid electrolyte layer. In a high-temperature state where the temperature of the solid oxide fuel cell, in which a fuel gas is supplied from one side of the fuel gas flow path and exhausted through an opening provided on the other side of the fuel gas flow path, is close to a power generation temperature, the solid oxide fuel cell is subjected to a process for regulating oxidation expansion rate of the fuel electrode layer, the oxidation expansion occurring when an oxidant gas flows in through the opening. As a result, it has become possible to provide a solid oxide fuel cell in which cracks in the electrolyte and cell breakage are prevented even when air flows into the fuel electrode side at the suspension of operations of the fuel cell.

First claim

1 . A method for producing a solid oxide fuel cell comprising:
a fuel gas flow path; a fuel electrode layer provided around the fuel gas flow path and containing an iron group element and a ceramic; a solid electrolyte layer provided around the fuel electrode layer; and an air electrode layer provided around the solid electrolyte layer, wherein a fuel gas is supplied from one side of the fuel gas flow path and exhausted through an opening provided on the other side of the fuel gas flow path, the method comprising:
performing a process for regulating oxidation expansion rate of the fuel electrode layer, the oxidation expansion occurring when an oxidant gas flows into the fuel gas flow path through the opening and the solid oxide fuel cell has a high temperature that is close to a temperature during power generation, and
extruding a composite material obtained by drying a slurry in which a metal oxide powder containing the iron group element and a powder containing the ceramic are dispersed in a solvent to obtain the fuel electrode layer,
wherein the process for regulating oxidation expansion rate comprises applying a shear force to the composite material during the extrusion to crush the composite material into primary particles.

2 . The method according to claim 1 , comprising obtaining the fuel electrode layer comprising a composite material obtained by drying a slurry that is prepared by dispersing a metal oxide powder containing the iron group element and a powder containing the ceramic in a solvent, wherein the regulation process comprises adjusting a dispersed particle size of the slurry to less than 10 μm.

3 . The method according to claim 1 , wherein a linear expansion coefficient per minute of the fuel electrode is 0.09% or less in a period after the oxidant gas begins to flow into the fuel gas flow path through the opening.

4 . The method according to claim 1 , wherein the iron group element comprises nickel.

5 . The method according to claim 1 , wherein the ceramic comprises a stabilized zirconia.

6 . The method according to claim 5 , wherein the stabilized zirconia comprises yttria-stabilized zirconia.

7 . The method according to claim 1 , wherein the opening is provided with a regulation unit that regulates oxidant gas flow and increases a pressure loss of the oxidant gas flows into the opening.

8 . The method according to claim 7 , wherein
the regulation unit comprises an oxidant gas flow regulation path having a smaller cross section than the opening, and the oxidant gas flow regulation path communicating with the fuel gas flow path.

9 . The solid oxide fuel cell according to claim 8 , wherein the regulation unit has a body covering at least the opening and a reduced diameter portion extending from the body in a projecting manner and having a smaller diameter than that of the body.

Assignees

• Toto Ltd

Inventors

• Shiono Mitsunobu
• FURUYA Seiki
• Takashio Minoru
• Ando Shigeru
• Shirahama Hiroshi
• Shimazu Megumi
• Kawakami Akira

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M8/1246

  the electrolyte consisting of oxides · CPC title

• H01M4/8875

  Methods for shaping the electrode into free-standing bodies, like sheets, films or grids, e.g. moulding, hot-pressing, casting without support, extrusion without support · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/126

  the electrolyte containing cerium oxide · CPC title