Phenoxycyclotriphosphazene active ester, halogen-free resin composition and uses thereof

Patent metadata

Field	Value
Publication number	US-2016244471-A1
Application number	US-201415027369-A
Country	US
Kind code	A1
Filing date	Jun 13, 2014
Priority date	Jun 13, 2014
Publication date	Aug 25, 2016
Grant date	—

Abstract

The present invention discloses a phenoxycyclotriphosphazene active ester, a halogen-free resin composition and uses thereof. The phenoxycyclotriphosphazene active ester comprises at least 65 mol. % of a substance having the following structural formula. The halogen-free resin composition comprises 5-50 parts by weight of a phenoxycyclotriphosphazene active ester, 15-85 parts by weight of a thermosetting resin, 1-35 parts by weight of a curing agent, 0-5 parts by weight of a curing accelerator and 0-100 parts by weight of an inorganic filler. The present invention discloses introducing phenoxycyclotriphosphazene active ester into a thermosetting resin, reacting active esters with thermosetting resins, such as epoxy resin, without producing hydroxy groups, which not only satisfies the requirements on being halogen-free and flame retardancy, but also improves the electrical properties (decreasing and stabilizing Dk and Df) of the system, so as to make non-halogenation of high frequency and high speed substrate materials possible.

First claim

1 . A phenoxycyclotriphosphazene active ester comprising at least 65 mol. % of a substance having the following structural formula:

wherein,

and n represents any number between 0.25 and 3.

2 . A halogen-free resin composition wherein the halogen-free resin composition comprises about 5 to about 50 parts by weight of the phenoxycyclotriphosphazene active ester in claim 1 , about 15 to about 85 parts by weight of a thermosetting resin, about 1 to about 35 parts by weight of a curing agent, about 0 to about 5 parts by weight of a curing accelerator and about 0 to about 100 parts by weight of an inorganic filler,
wherein the thermosetting resin is anyone selected from the group consisting of epoxy resin, benzoxazine resin, cyanate resin, bismaleimide resin, reactive polyphenyl ether resin or hydrocarbon resin, or a mixture of at least two selected therefrom.

3 . The halogen-free resin composition of claim 2 , wherein the thermosetting resin comprises dicyclopentadiene, biphenyl or naphthalene ring group.

4 . The halogen-free resin composition of claim 2 , characterized in that the epoxy resin is anyone selected from the group consisting of bisphenol A epoxy resin, bisphenol F epoxy resin, DCPD epoxy resin, triphenol epoxy resin, biphenyl epoxy resin or naphthol epoxy resin, or a mixture of at least two or more thereof.

5 . The halogen-free resin composition of claim 2 , wherein the epoxy resin is a phosphorous-containing epoxy resin containing about 1.5 to about 6.0 wt. % of phosphorous.

6 . The halogen-free resin composition of claim 2 , wherein the benzoxazine resin is selected from the group consisting of bisphenol A benzoxazine resin, bisphenol F benzoxazine resin, DCPD benzoxazine resin or phenothalin benzoxazine resin, or a mixture of at least two or more thereof.

7 . The halogen-free resin composition of claim 2 , wherein the cyanate resin is selected from the group consisting of bisphenol A cyanate resin, DCPD cyanate resin or phenolic aldehyde cyanate resin, or a mixture of at least two or more thereof.

8 . The halogen-free resin composition of claim 2 , wherein the bismaleimide resin comprises 4,4′-diphenylmethane bismaleimide, allyl-modified diphenylmethane bismaleimide, or a combination of two or more thereof.

9 . The halogen-free resin composition of claim 2 , wherein the reactive polyphenyl ether resin has an average molecular weight of about 1000 to about 7000, and has reactive groups of hydroxyl groups, double bonds, or both.

10 . The halogen-free resin composition of claim 2 , wherein the hydrocarbon resin is selected from the group consisting of vinyl styrene butadiene resin having a average molecular weight of about less than 11,000, vinyl polybutadiene resin having polar groups or maleic anhydride-grafted butadiene and styrene resin, or a copolymer of at least two or more thereof.

11 . The halogen-free resin composition of claim 2 , wherein the curing agent is selected from the group consisting of dicyandiamide, aromatic amine, anhydride, phenolic compounds, triene isocyanurate or phosphorous-containing phenolic aldehyde, or a mixture of at least two or more thereof.

12 . The halogen-free resin composition of claim 2 , wherein the curing accelerator is selected from the group consisting of 2-methylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole, pyridine, DMP-30, hexamethylenetetramine, dicumyl peroxide, t-butyl peroxybenzoate, 2,5-di(2-ethylhexanoylperoxy)-2,5-dimethylhexane, acetylacetonate or zincate, or a mixture of at least two or more thereof.

13 . The halogen-free resin composition of claim 2 , wherein the inorganic filler is selected from the group consisting of aluminum hydroxide, magnesium hydroxide, zeolite, wollastonite, silica, magnesium oxide, calcium silicate, calcium carbonate, clay, talc or mica, or a mixture of at least two or more thereof.

14 . The halogen-free resin composition of claim 2 , wherein the inorganic filler is in an amount of 25 to 100 parts by weight.

15 . A prepreg, wherein the prepreg comprises a reinforcing material and the halogen-free resin composition of claim 2 and attached thereon after impregnation and drying.

16 . A laminate, wherein the laminate comprises at least one prepreg of claim 15 .

17 . A printed wiring board, wherein the printed wiring board comprises at least one prepreg of claim 15 .

Assignees

• Shengyi Technology Co Ltd

Inventors

• He Yueshan

Classifications

• C08J2435/06

  Copolymers with vinyl aromatic monomers · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title

• C08L2201/22

  Halogen free composition · CPC title

• C08L75/00

  Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers · CPC title

• C08J5/24

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title