Continuous chemical vapor deposition/infiltration coater

Patent metadata

Field	Value
Publication number	US-2016229758-A1
Application number	US-201514619320-A
Country	US
Kind code	A1
Filing date	Feb 11, 2015
Priority date	Feb 11, 2015
Publication date	Aug 11, 2016
Grant date	—

Abstract

A method to form a ceramic interface coating on ceramic matrix composite (CMC) precursor tape by a continuous process includes passing a ceramic fiber woven cloth tape or unidirectional tape of a first ceramic with a first and second surface through at least one reaction zone of a continuous vacuum chemical vapor deposition (CVD) or chemical vapor infiltration (CVI) reactor heated to a reaction temperature. The method further includes directing a flow of CVD or CVI reactant gas of a second ceramic at the first surface of the tape in a direction perpendicular to the tape such that the reactant gas passes through the tape in a forced flow process depositing the second ceramic on the fibers of the first ceramic thereby coating the fibers of the first ceramic tape with the second ceramic to interface coating form a coated fiber CMC precursor tape product.

First claim

1 . A method to form a ceramic interface coating on ceramic matrix composite (CMC) precursor tape by a continuous process comprising:
passing a tape, comprising a ceramic fiber woven cloth tape or unidirectional tape, of a first ceramic with a first and second surface through at least one reaction zone of a continuous vacuum chemical vapor deposition (CVD) or chemical vapor infiltration (CVI) reactor heated to a reaction temperature; and directing a flow of CVD or CVI reactant gas of a second ceramic at the first surface of the tape in a direction perpendicular to the tape such that the reactant gas passes through the tape in a forced flow process depositing the second ceramic on the fibers of the first ceramic thereby coating the fibers of the first ceramic tape with the second ceramic interface coating to form a coated fiber CMC precursor tape product.

2 . The method of claim 1 wherein a temperature of the first surface of the tape is equal to a temperature of the second surface of the tape.

3 . The method of claim 2 wherein the temperature of the first surface of the tape is lower than the temperature of the second surface of the tape.

4 . The method of claim 1 wherein a reactant gas pressure is higher at the first surface of the tape than at the second surface of the tape.

5 . The method of claim 1 wherein the method comprises at least two reaction zones.

6 . The method of claim 1 wherein the reaction temperature is from about 575° F. (302° C.) to about 2730° F. (1499° C.).

7 . The method of claim 1 wherein the width of the tape is from about 6 inches (15.24 cm) to about 60 inches (125.4 cm).

8 . The method of claim 1 wherein the thickness of the cloth sheet is from about 0.006 inches (152 microns) to about 0.25 inches (6352 microns).

9 . The method of claim 1 wherein the first ceramic comprises carbon, silicon carbide, boron carbide or aluminum oxide.

10 . The method of claim 1 wherein the second ceramic comprises carbon, doped carbon, silicon carbide, silicon nitride, boron nitride, silicon doped boron nitride, or boron carbide.

11 . An apparatus to continuously form ceramic interface coatings on ceramic matrix composite (CMC) precursor tape comprising:
a tape, comprising a ceramic fiber woven cloth tape or unidirectional tape, of a first ceramic with a first and second surface mounted on a supply spool in a storage chamber; a tension roller and a purge gas inlet in the storage chamber; a storage chamber tape outlet seal; at least one chemical vapor deposition (CVD) or chemical vapor infiltration (CVI) reaction zone comprising;
a vacuum chamber;
a tape inlet seal;
a reactant gas dispensing system directed at the first side of the tape in a direction perpendicular to the tape for forming a CVD or CVI coating of a second ceramic on the fibers to form an interface coating;
a purge gas inlet;
at least one heating element for heating the tape to a CVD or CVI reaction temperature;
a vacuum system;
high temperature insulation; and
a tape outlet seal;
a tape collection spool mounted on a drive shaft in a collection chamber; a tension roller, a purge gas inlet and a tape inlet seal in the collection chamber; and a variable speed drive attached to the collection spool to gather the coated CMC precursor tape product on the collection spool.

12 . The apparatus of claim 11 wherein heating elements provide a temperature of the second side of the tape equal to a temperature of the first side.

13 . The apparatus of claim 12 wherein the temperature of the first side of the tape is lower than the temperature of the second side of the tape.

14 . The apparatus of claim 11 wherein the reactant gas pressure at the first side of the tape is higher than at the second side of the tape.

15 . The apparatus of claim 12 wherein the heating elements are resistance heated graphite rods or plates positioned on one or both sides of the tape.

16 . The apparatus of claim 11 wherein the reaction temperature is from about 575° F. (302° C.) to about 2730° F. (1499° C.).

17 . The apparatus of claim 11 wherein the apparatus comprises at least two reaction zones.

18 . The apparatus of claim 11 wherein the first ceramic comprises carbon, silicon carbide, boron carbide or aluminum oxide.

19 . The apparatus of claim 11 wherein the second ceramic comprises carbon, doped carbon, silicon carbide, silicon nitride, boron nitride, silicon doped boron nitride, or boron carbide.

20 . The method of claim 11 wherein the width of the tape is from about 6 inches (15.24 cm) to about 60 inches (125.4 cm).

Assignees

• United Technologies Corp

Inventors

• Kmetz Michael A
• Newton Kirk C

Classifications

• C04B41/0018 Primary

  Coating or impregnating "in situ", e.g. impregnating of artificial stone by subsequent melting of a compound added to the artificial stone composition · CPC title

• C04B35/62844 Primary

  Coating fibres · CPC title

• C04B35/62868

  Boron nitride · CPC title

• C04B35/62873

  Carbon · CPC title

• C23C16/545

  for coating elongated substrates · CPC title