Method for producing a composite plastic part (ck)

Patent metadata

Field	Value
Publication number	US-2016207238-A1
Application number	US-201414913114-A
Country	US
Kind code	A1
Filing date	Aug 18, 2014
Priority date	Aug 21, 2013
Publication date	Jul 21, 2016
Grant date	—

Abstract

The invention relates to a method for producing a composite plastic part (CK). A first fiber material (F 1 ) is impregnated with a polyamide matrix polymer (PAM), thereby obtaining a matrix composition (MZ), onto which a surface composition (OZ) is applied, and a first plastic component (K 1 ) is obtained. In a second step, a second plastic component (K 2 ) is molded on the first plastic component (K 1 ), whereby the composite plastic part (CK) is obtained. The invention further relates to the composite plastic part (CK) which can be obtained using the method according to the invention. The invention additionally relates to the use of polyethyleneimine (PEI) for improving the impregnation of the first fiber material (F 1 ) with the polyamide matrix polymer (PAM).

First claim

1 .- 15 . (canceled)

16 . A process for producing a plastic composite component (CC), comprising the following steps:
a) producing a first plastic component (C 1 ) by a process comprising:
ia) impregnating a first fiber material (F 1 ) with a polyamide matrix polymer (PAM) to obtain a matrix composition (MC) and
ib) applying a surface composition (SC) comprising a polyamide surface polymer (PAS) to the matrix composition (MC) to obtain the first plastic component (C 1 ), the surface composition (SC) forming a surface of the first plastic component (C 1 ),
b) molding a second plastic component (C 2 ) comprising a polyamide molding polymer (PAA) onto the surface of (C 1 ),
wherein
the matrix composition (MC) comprises a polyethyleneimine (PEI).

17 . The process according to claim 16 , wherein the polyethyleneimine (PEI) has a weight-average molecular weight M W in the range from 600 to 300 000 g/mol.

18 . The process according to claim 16 wherein the polyethyleneimine (PEI) comprises primary, secondary and tertiary amino groups, where the ratio of primary to secondary to tertiary amino groups is in the range from 1:0.8:0.5 to 1:1.3:0.8.

19 . The process according to claim 16 , wherein the polyethyleneimine (PEI) is a hyperbranched polymer having a degree of branching DB in the range from 10% to 99%, where DB is defined as DB (%)=100×(T+Z)/(T+Z+L) where T is the mean number of terminal-bonded monomer units, Z is the mean number of monomer units that form branches and L is the mean number of linear-bonded monomer units in the polyethyleneimine (PEI).

20 . The process according to claim 16 , wherein the matrix composition (MC) comprises 0.01% to 5% by weight of polyethyleneimine (PEI), based on the total weight of the matrix composition (MC).

21 . The process according to claim 16 , wherein the first fiber material (F 1 ) is a continuous fiber material.

22 . The process according to claim 16 , wherein C 2 comprises a second fiber material (F 2 ).

23 . The process according to claim 22 , wherein the second fiber material (F 2 ) is a short fiber material.

24 . The process according to claim 16 , wherein, in step b), C 1 is placed into a mold and C 2 is injected into the mold in the molten state for molding.

25 . The process according to claim 16 , wherein the polyamide matrix polymer (PAM) is heated in process step ia) to temperatures in the range from 40° C. to 210° C.

26 . The process according to claim 16 , wherein the surface composition (SC) is heated in process step ib) to temperatures in the range from 40° C. to 210° C.

27 . The process according to claim 16 , wherein process steps ia) and ib) are conducted simultaneously in process step a).

28 . The process according to claim 16 , wherein only the matrix composition (MC) comprises a polyethyleneimine (PEI).

29 . A plastic composite component obtained by the process according to claim 16 .

30 . A method for improving the impregnation of a first fiber material (F 1 ) with a polyamide matrix polymer (PAM) in a process for producing a plastic composite component (CC), comprising the following steps:
a) producing a first plastic component (C 1 ), comprising the following steps:
ia) impregnating a first fiber material (F 1 ) with a polyamide matrix polymer (PAM) to obtain a matrix composition (MC) and
ib) applying a surface composition (SC) comprising a polyamide surface polymer (PAS) to the matrix composition (MC) to obtain the first plastic component (C 1 ), the surface composition (SC) forming a surface of the first plastic component (C 1 ),
b) molding a second plastic component (C 2 ) comprising a polyamide molding polymer (PAA) onto the surface of (C 1 );
the method comprising incorporating polyethyleneimine in the matrix composition (MC).

Assignees

• Basf Se

Inventors

• Habraken Gijsbrecht
• Prusty Manoranjan
• Radtke Andreas
• Kasaliwal Gaurav Ramanlal

Classifications

• C08J5/046 Primary

  with synthetic macromolecular fibrous material · CPC title

• B29K2077/00

  Use of {PA, i.e.} polyamides, e.g. polyesteramides {or derivatives thereof}, as moulding material · CPC title

• C08J5/10

  characterised by the additives used in the polymer mixture · CPC title

• C08J2377/00

  Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers · CPC title

• B29K2079/085

  Thermoplastic polyimides, e.g. polyesterimides, PEI, i.e. polyetherimides, or polyamideimides; Derivatives thereof · CPC title