Epoxy-based resin composition for composite materials

Patent metadata

Field	Value
Publication number	US-2016168372-A1
Application number	US-201514968952-A
Country	US
Kind code	A1
Filing date	Dec 15, 2015
Priority date	Dec 16, 2014
Publication date	Jun 16, 2016
Grant date	—

Abstract

A curable, epoxy-based resin composition that can be combined with reinforcement fibers and then cured to form a cured product that is excellent in toughness and exhibits high Open-Hole Tensile (OHT) strength. According to one embodiment, the resin composition contains a Bisphenol F difunctional epoxy, an anthracyl compound, a tri-functional epoxy, a thermoplastic polymer, and an amine-containing curing agent.

First claim

What is claimed is:

1 . A curable epoxy-based resin composition comprising:
(A) an epoxy component comprising:
(i) a Bisphenol F difunctional epoxy represented by the following structure (I):

(ii) an anthracyl compound represented by the following structure (II):

and
(iii) a tri-functional epoxy;
(B) a thermoplastic polymer selected from: polyether sulphone (PES), polyetherether sulphone (PEES), PES-PEES copolymer with terminal amine groups; and
(C) an amine-containing curing agent;
wherein, per 100 parts by weight of the epoxy component, the tri-functional epoxy is present in an amount of less than 30 parts, and the difunctional epoxy is present in amount greater than that of the anthracyl compound, and
wherein, the ratio of epoxy component to amine-containing curing agent is such that there is 0.7-0.8 mole of amine-hydrogen group for every mole of epoxide group.

2 . The curable epoxy-based resin composition of claim 1 , wherein
the tri-functional epoxy resin is represented by the following structure (III):

3 . The curable epoxy-based resin composition of claim 1 , wherein the amine-containing curing agent is diaminodiphenylsulfone (DDS) or fluorene amine.

4 . The curable epoxy-based resin composition of claim 1 , wherein the weight ratio of anthracyl compound to di-functional epoxy is 0.4-0.6.

5 . The curable epoxy-based resin composition of claim 1 , comprising, per 100 parts by weight of the epoxy component:
49-51 parts di-functional epoxy, 24-26 parts anthracyl compound, and 23-25 parts tri-functional epoxy resin.

6 . The curable epoxy-based resin composition of claim 1 , wherein the thermoplastic polymer is a PES-PEES copolymer having terminal amine groups.

7 . The curable epoxy-based resin composition of claim 1 , wherein the tri-functional epoxy is present in an amount in the range of 20 to 29 parts.

8 . A composite material comprising reinforcement fibers embedded in or infused with the curable epoxy-based resin composition of claim 1 .

9 . The composite material of claim 8 , wherein the reinforcement fibers are selected from: carbon fibers, aramid fibers, and fiberglass fibers.

10 . A prepreg comprising unidirectional fibers impregnated with the curable epoxy-based resin composition of claim 1 .

11 . The prepreg of claim 10 , wherein the unidirectional fibers are selected from: carbon fibers, aramid fibers, and fiberglass fibers.

12 . A composite laminate comprising a plurality of prepregs arranged in a stacking arrangement, each prepreg comprising unidirectional fibers impregnated with the curable epoxy-based resin composition of claim 1 .

Assignees

• Cytec Ind Inc

Inventors

• Bonneau Mark Richard
• Billaud Claude

Classifications

• C08G59/3227

  Compounds containing acyclic nitrogen atoms · CPC title

• C08G59/24

  carbocyclic · CPC title

• C08G59/226 Primary

  Mixtures of di-epoxy compounds · CPC title

• C08L63/00 Primary

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title

• C08L81/06

  Polysulfones; Polyethersulfones · CPC title