Method for orienting one-dimensional objects and articles obtained therefrom

Patent metadata

Field	Value
Publication number	US-2016144401-A1
Application number	US-201514733259-A
Country	US
Kind code	A1
Filing date	Jun 8, 2015
Priority date	Jun 6, 2014
Publication date	May 26, 2016
Grant date	—

Abstract

Disclosed herein is a method comprising dispersing one-dimensional objects in a liquid to form a mixture; and disposing the mixture on a substrate that has channels disposed on it; where the channels are of a width of 4 to 90 percent of the length of the one-dimensional object. Disclosed herein is an article comprising a substrate; where the substrate has channels disposed thereon; each channel being bounded by a wall; and a plurality of one-dimensional objects that are oriented relative to the walls on the substrate; and where the channels are of a width of 4 to 90 percent of the smallest length of the plurality of one-dimensional objects.

First claim

What is claimed is:

1 . A method comprising:
dispersing one-dimensional objects in a liquid to form a mixture; and disposing the mixture on a substrate that has channels disposed on it; where the channels are of a width of 2 to 90 percent of the length of the one-dimensional object.

2 . The method of claim 1 , further comprising disposing the channels on the substrate; and where the channels are disposed on the substrate by nanoimprinting, roll-to-roll ultraviolet nanoimprinting, laser printing, embossing, lithography followed by etching, self-assembly of a copolymer followed by etching; photolithography followed by etching; surface wrinkling, creasing or buckling, nano-scribing, scratching, shadow deposition, transfer printing, interference lithography, immersion lithography, atomic force microscopy lithography, e-beam lithography, nano-scribing, or a combination thereof.

3 . The method of claim 1 , where the liquid in the mixture is 50 to 10000 weight percent of the weight of the one-dimensional objects.

4 . The method of claim 1 , where the liquid is polar.

5 . The method of claim 1 , where the liquid is non-polar.

6 . The method of claim 1 , where the one-dimensional object is a nanotube, nanowire, nanorod, whisker, microtube, microwire, microrod, or combinations thereof.

7 . The method of claim 1 , where the one-dimensional objects are inorganic materials.

8 . The method of claim 1 , where the one-dimensional objects are organic materials.

9 . The method of claim 7 , where the inorganic one-dimensional object is selected from the group consisting of elemental metals, metal alloys, metal oxides, metal sulfides, metal nitrides, metal borides, metal silicides, metal phosphides, metal carbides, or a combination comprising at least one of the foregoing inorganic materials.

10 . The method of claim 1 , where the one-dimensional object is selected from the group consisting of carbon nanotubes, carbon nanotubes having pendant organic or inorganic substituents, nucleic acids, polymeric fibers, nanotubes or nanowires or nanorods comprising molybdenum, silicon, boron nitride, tungsten disulfide, tin disulfide, vanadium oxide, aluminum oxide, titanium oxide, zinc oxide, manganese oxide, transition metal/chalcogen/halogenides having the formula TM 6 C y H z , where TM is a transition metal, C is a chalcogen, H is halogen and where 8.2<(y+z)<10, polyacetylene nanowires or microwires, polyacrylate nanowires or microwires, polyester nanowires or microwires, polystyrene nanowires or microwires, polycarbonate nanowires or microwires, polyimide nanowires or microwires, polyetherimide nanowires or microwires, polyetheroxide nanowires or microwires, polyether ketone nanowires or microwires, polysiloxane nanowires or microwires, polyfluoroethylene nanowires or microwires, cellulose nanowires or microwires, or combinations thereof.

11 . The method of claim 1 , where the liquid is selected from the group consisting of water, alcohols, ketones, glycol ethers, propylene carbonate, ethylene carbonate, butyrolactone, acetonitrile, benzonitrile, nitromethane, nitrobenzene, sulfolane, dimethylformamide, dimethylacetamide, N-methylpyrrolidone, nitromethane, methanol, ethanol, propanol, isopropanol, butanol, benzene, toluene, methylene chloride, carbon tetrachloride, hexane, diethyl ether, tetrahydrofuran, or combinations thereof.

12 . The method of claim 1 , further comprising drying the substrate.

13 . The method of claim 1 , further comprising preheating the substrate and drying the substrate.

14 . An article comprising:
a substrate; where the substrate has channels disposed thereon; each channel being bounded by a wall; and a plurality of one-dimensional objects that are oriented relative to the walls on the substrate; and where the channels are of a width of 2 to 90 percent of the smallest length of the plurality of one-dimensional objects.

15 . The article of claim 14 , where the one-dimensional object is a nanotube, nanowire, nanorod, whisker, microtube, microwire, microrod, or combinations thereof.

16 . The article of claim 14 , where the one-dimensional objects are inorganic materials.

17 . The article of claim 14 , where the one-dimensional objects are organic materials.

18 . The article of claim 16 , where the inorganic one-dimensional object is selected from the group consisting of elemental metals, metal alloys, metal oxides, metal sulfides, metal nitrides, metal borides, metal silicides, metal phosphides, metal carbides, or a combination comprising at least one of the foregoing inorganic materials.

19 . The article of claim 14 , where the one-dimensional object is selected from the group consisting of carbon nanotubes, carbon nanotubes having pendant organic or inorganic substituents, nucleic acids, polymeric fibers, nanotubes or nanowires or nanorods comprising molybdenum, silicon, boron nitride, tungsten disulfide, tin disulfide, vanadium oxide, aluminum oxide, titanium oxide, zinc oxide, manganese oxide, transition metal/chalcogen/halogenides having the formula TM6CyHz, where TM is a transition metal, C is a chalcogen, H is halogen and where 8.2<(y+z)<10, polyacetylene nanowires or microwires, polyacrylate nanowires or microwires, polyester nanowires or microwires, polystyrene nanowires or microwires, polycarbonate nanowires or microwires, polyimide nanowires or microwires, polyetherimide nanowires or microwires, polyetheroxide nanowires or microwires, polyether ketone nanowires or microwires, polysiloxane nanowires or microwires, polyfluoroethylene nanowires or microwires, cellulose nanowires or microwires, or combinations thereof.

20 . The article of claim 14 , where the substrate comprises a polymer.

21 . The article of claim 14 , where the substrate comprises a silicon wafer, glass, oxides, metal, paper, ceramic, composites, clothes, and the like.

22 . The article of claim 14 , where the one-dimensional objects are fused together.

23 . The article of claim 14 , where the one-dimensional objects are fused to the substrate.

24 . The article of claim 14 , where the one-dimensional objects are oriented approximately perpendicular to the walls.

25 . The article of claim 14 , where the substrate with the channels disposed thereon is naturally occurring.

26 . A method comprising:
dispersing one-dimensional objects in a liquid to form a mixture; and disposing the mixture on a first substrate that has channels disposed on it; each channel being bounded by pair of walls that are substantially parallel to each other at a first distance “x”; collecting one-dimensional objects that are not contained in the channels from the first substrate; disposing the one-dimensional objects so collected onto a second substrate that has channels disposed on it; each channel being bounded by pair of walls that are substantially parallel to each other at a first distance “y”; where y is greater than x; and collecting one-dimensional objects that are not contained in the channels from the second substrate.

27 . The method of claim 26 , further comprising collecting the one-dimensional objects contained in the channels of the first substrate separately from the one-dimensional objects contained in the channels of the second substrate.

28 . A method of manufacturing a device comprising:
disposing a first layer on a substrate; imprinting on

Assignees

• Univ Massachusetts

Inventors

• Carter Kenneth R
• John Jacob

Classifications

• B05D7/24 Primary

  for applying particular liquids or other fluent materials · CPC title

• C01B32/168 Primary

  After-treatment · CPC title

• H10K71/191 Primary

  characterised by provisions for the orientation or alignment of the layer to be deposited · CPC title

• H10K85/221

  Carbon nanotubes · CPC title