Process for producing acrylic acid

Patent metadata

Field	Value
Publication number	US-12570596-B2
Application number	US-202117921168-A
Country	US
Kind code	B2
Filing date	Oct 27, 2021
Priority date	Nov 24, 2020
Publication date	Mar 10, 2026
Grant date	Mar 10, 2026

Abstract

Provided is a process for producing acrylic acid, the process comprising: (step 1) preparing a first aqueous lactic acid solution by diluting a lactic acid raw material with water; (step 2) heat exchanging the first aqueous lactic acid solution to form a vaporized second lactic acid vapor and an unvaporized third aqueous lactic acid solution; (step 3) including the unvaporized third aqueous lactic acid solution in the aqueous solution of the step 1; and (step 4) supplying and absorbing an absorption liquid to the vaporized second lactic acid vapor to form an absorbed fourth aqueous lactic acid solution and an unabsorbed fifth lactic acid vapor, wherein the absorption liquid is water or an aqueous lactic acid solution.

First claim

The invention claimed is:

1 . A process for producing acrylic acid, the process comprising:
(step 1) preparing a first aqueous lactic acid solution by diluting a lactic acid raw material with water; (step 2) heat exchanging the first aqueous lactic acid solution to form a vaporized second lactic acid vapor and an unvaporized third aqueous lactic acid solution; (step 3) including the unvaporized third aqueous lactic acid solution in the aqueous solution of the step 1; and (step 4) supplying and absorbing an absorption liquid to the vaporized second lactic acid vapor to form an absorbed fourth aqueous lactic acid solution and an unabsorbed fifth lactic acid vapor, wherein the absorption liquid is water or an aqueous lactic acid solution, wherein the step 4 includes a process of absorbing through an absorption device; and the absorption device has an inner pressure of greater than or equal to 0.3 bar and less than or equal to 3 bar and an inner temperature of higher than or equal to 100° C. and lower than or equal to 230° C.

2 . The process of claim 1 , wherein the step 2 includes a process of heat exchanging through a heat exchanger; and
the heat exchanger has an inner pressure of greater than or equal to 0.3 bar and less than or equal to 3 bar and an inner temperature of higher than or equal to 150° C. and lower than or equal to 300° C.

3 . The process of claim 1 , wherein the first aqueous lactic acid solution includes water and a lactic acid raw material;
the lactic acid raw material includes lactic acid and a lactic acid oligomer; and the lactic acid raw material is included in greater than or equal to 30 parts by weight and less than or equal to 99 parts by weight based on 100 parts by weight of the first aqueous lactic acid solution.

4 . The process of claim 3 , wherein a ratio of the lactic acid:lactic acid oligomer in the first aqueous lactic acid solution is from 1:99 to 30:70.

5 . The process of claim 1 , wherein a ratio of lactic acid:lactic acid oligomer in the second lactic acid vapor is from 80:20 to 95:5.

6 . The process of claim 1 , wherein a ratio of lactic acid:lactic acid oligomer in the fifth lactic acid vapor is from 100:0 to 90:10.

7 . The process of claim 1 , wherein the fifth lactic acid vapor includes water and a lactic acid raw material;
the lactic acid raw material includes lactic acid and a lactic acid oligomer; and the lactic acid raw material is included in greater than or equal to 10 parts by weight and less than or equal to 80 parts by weight based on 100 parts by weight of the fifth lactic acid vapor.

8 . The process of claim 1 , further comprising including the fourth aqueous lactic acid solution in the aqueous solution of the step 1.

9 . The process of claim 2 , wherein the heat exchanger is one or more selected from the group consisting of a falling film evaporator, a wiped film evaporator, a thermosyphon, and a forced circulation evaporator.

10 . The process of claim 1 , wherein the absorption device is one or more selected from the group consisting of a drum, a spray drum, a packing column, and a tray column.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Eunkyo
• Kim Mi Kyung
• Shin Joon Ho
• Kim Hyebin

Classifications

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• C07C51/377

  by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups {(C07C51/36 - C07C51/373 take precedence)} · CPC title

• C07C51/487 Primary

  by treatment giving rise to chemical modification (by chemisorption C07C51/47) · CPC title

• C07C51/47 Primary

  by solid-liquid treatment; by chemisorption · CPC title