Methods for producing acrylic acid and/or ester thereof and polymer of the acrylic acid and/or ester thereof

Patent metadata

Field	Value
Publication number	US-9029596-B2
Application number	US-201113997350-A
Country	US
Kind code	B2
Filing date	Dec 28, 2011
Priority date	Dec 28, 2010
Publication date	May 12, 2015
Grant date	May 12, 2015

Abstract

A method for producing acrylic acid and/or an ester thereof from a raw material composition containing hydroxypropionic acid and/or an ester thereof, the method including the steps of: (a) evaporating the raw material composition; and (b) dehydrating the evaporated raw material composition by contact with a dehydration catalyst, wherein the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (b) is controlled to be 70% by mass or more based on 100% by mass of the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (a).

First claim

The invention claimed is:

1. A method for producing acrylic acid and/or an ester thereof from a raw material composition containing hydroxypropionic acid and/or an ester thereof, the method comprising the steps of:
(a) evaporating the raw material composition; and
(b) dehydrating the evaporated raw material composition by contact with a dehydration catalyst,
wherein the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (b) is controlled to be 70% by mass or more based on 100% by mass of the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (a).

2. The production method according to claim 1 ,
wherein at least part or all of the hydroxypropionic acid in the raw material composition is hydroxypropionic acid obtainable by fermentation.

3. The production method according to claim 1 ,
wherein an inorganic compound in the raw material composition is 1% by mass or less based on 100% by mass of the total amount of the hydroxypropionic acid and/or an ester thereof.

4. The production method according to claim 1 , step (a) further comprises introducing water and/or an inert gas to the raw material composition, and
wherein the total amount of water and/or an inert gas supplied in the step (a) is 0.5 times by mole or more of the total amount of the hydroxypropionic acid and/or an ester thereof in the raw material composition.

5. The production method according to claim 1 ,
wherein the hydroxypropionic acid is 3-hydroxypropionic acid.

6. The production method according to claim 1 ,
wherein a carbonaceous substance formed on the dehydration catalyst in the step (b) is removed by contact with an oxidant.

7. The production method according to claim 6 ,
wherein the oxidant is a gaseous oxidant.

8. The production method according to claim 7 ,
wherein the carbonaceous substance is removed by introducing the gaseous oxidant into a reactor filled with the dehydration catalyst used in the step (b).

9. The production method according to claim 6 ,
wherein the method comprises:
a first hydroxypropionic acid reaction step including the step (a) and the step (b);
catalyst regeneration step for removing the carbonaceous substance on the dehydration catalyst; and
a second hydroxypropionic acid reaction step including the step (a) and the step (b) in which the dehydration catalyst regenerated in the catalyst regeneration step is used.

10. The production method according to claim 9 ,
wherein plural reactors are used in production of acrylic acid and/or an ester thereof, and,
while the catalyst regeneration step is performed in a first reactor, the first or second hydroxypropionic acid reaction step is performed in another reactor.

11. The production method according to claim 9 ,
wherein the method further includes a step of removing a carbonaceous substance formed in an evaporator in the step (a) by contact with an oxidant.

12. The production method according to claim 1 ,
wherein the method further includes a step of purifying acrylic acid and/or an ester thereof by crystallization.

13. A method for producing a hydrophilic resin comprising a step of
producing a monomer component containing an acrylic acid and/or an ester thereof from a raw material composition containing hydroxypropionic acid and/or an ester thereof, comprising the steps of:
(a) evaporating the raw material composition; and
(b) dehydrating the evaporated raw material composition by contact with a dehydration catalyst, wherein the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (b) is controlled to be 70% by mass or more based on 100% by mass of the total amount of hydroxypropionic acid and/or an ester thereof supplied in the step (a), and
polymerizing the monomer component containing the acrylic acid and/or an ester thereof.

14. The method for producing a hydrophilic resin according to claim 13 ,
wherein the hydrophilic resin is a water-absorbent resin.

Assignees

• Yoshida Hiroshi
• Kamei Hisashi
• Nippon Catalytic Chem Ind

Inventors

• Yoshida Hiroshi
• Kamei Hisashi

Classifications

• C07C59/01

  Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups · CPC title

• C07C51/377 Primary

  by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups {(C07C51/36 - C07C51/373 take precedence)} · CPC title

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• C08F2/00

  Processes of polymerisation · CPC title

• C07C51/347

  by reactions not involving formation of carboxyl groups · CPC title