Halogen-free synergist

Patent metadata

Field	Value
Publication number	US-12565563-B2
Application number	US-202118018949-A
Country	US
Kind code	B2
Filing date	Aug 10, 2021
Priority date	Aug 12, 2020
Publication date	Mar 3, 2026
Grant date	Mar 3, 2026

Abstract

A polymer having a backbone and a side unit of 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide bonded thereto, where the backbone of the polymer includes at least one heterocyclic moiety. There is also provided a process for producing the polymer as defined herein as well as a flame retardant polyolefin formulation including the polymer as defined herein and a moulded article including the flame retardant polyolefin formulation as defined herein.

First claim

The invention claimed is:

1 . A flame retardant polyolefin composition comprising:
a polyolefin matrix, a polymer, and an inorganic flame retardant, wherein the polymer is blended with the inorganic flame retardant in a weight ratio of 1:3 to 1:4, wherein the polymer has a backbone and a side unit of 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide bonded thereto, wherein the backbone of the polymer comprises at least one heterocyclic moiety.

2 . The flame retardant polyolefin composition of claim 1 , wherein at least one heteroatom of the at least one heterocyclic moiety is selected from a group 15 element of the periodic table.

3 . The flame retardant polyolefin composition of claim 2 , wherein the polymer comprises at least 2 heteroatoms selected from the group 15 element of the periodic table in each repeating unit of the polymer.

4 . The flame retardant polyolefin composition of claim 2 , wherein the at least one heteroatom of the at least one heterocyclic moiety is nitrogen.

5 . The flame retardant polyolefin composition of claim 2 , wherein the at least one heteroatom of the at least one heterocyclic moiety is phosphorous.

6 . The flame retardant polyolefin composition of claim 1 , wherein the at least one heterocyclic moiety is selected from one or more of the group consisting of piperidinyl, pyridinyl, phosphaninyl, phosphininyl, diazinanyl, diazinyl, morpholinyl, oxazinyl, thiomorpholinyl, thiazinyl, triazinanyl, triazinyl, tetrazinyl, pentazinyl, cyclic 1,3-propanediol phosphoryl, and a combination thereof.

7 . The flame retardant polyolefin composition of claim 6 , wherein the diazinanyl is selected from the group consisting of 1,2-diazinanyl, 1,3-diazinanyl, 1,4-diazinanyl (piperazinyl), and a combination thereof.

8 . The flame retardant polyolefin composition of claim 1 , the polymer having the formula (I)

wherein m is an integer number ranging from 2 to 5000; and
* represents an attachment point.

9 . The flame retardant polyolefin composition of claim 1 , the polymer having the formula (II)

wherein n is an integer number ranging from 2 to 1000; and
* represents an attachment point.

10 . A process for producing the flame retardant polyolefin composition of claim 1 , comprising:
bonding 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide to a monomeric unit to obtain a polymerisation precursor; polymerizing the polymerisation precursor with at least one heterocyclic unit, wherein the backbone of the polymer is formed by the reaction product of the monomeric unit and the at least one heterocyclic unit; obtaining the polymer of claim 1 by precipitation; and mixing the polymer with a polyolefin matrix and an inorganic flame retardant, wherein the polymer is mixed with the inorganic flame retardant in a weight ratio of 1:3 to 1:4.

11 . The process of claim 10 , wherein bonding 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide to the monomeric unit comprises heating a mixture of two molecules of 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide with a monomeric unit at a temperature of 160° C. to 190° C.

12 . The process of claim 10 , wherein the polymerisation precursor is obtained by precipitation.

13 . The flame retardant polyolefin composition of claim 1 , wherein the polyolefin matrix is present in a weight percentage range of 20 wt % to 90 wt %.

14 . The flame retardant polyolefin composition of claim 1 , wherein the polyolefin matrix further comprises polypropylene having an anhydride grafted thereon.

15 . The flame retardant polyolefin composition of claim 1 , wherein the inorganic flame retardant is coated with a nitrogen-containing heterocyclic compound.

16 . The flame retardant polyolefin composition of claim 1 , wherein the inorganic flame retardant is a polymeric salt.

17 . The flame retardant polyolefin composition of claim 1 , wherein the inorganic flame retardant together with the polymer of claim 1 is present in the flame retardant polyolefin composition in 18 wt % to 21 wt %, based on the total weight of the flame retardant polyolefin composition.

18 . A moulded article comprising the flame retardant polyolefin composition of claim 1 .

Assignees

• Agency Science Tech & Res

Inventors

• Kong Junhua
• Liu Songlin
• Wang Suxi
• Lim Qi Feng
• Tan Beng Hoon Maureen Janet
• He Chaobin

Classifications

• C08L2201/02

  Flame or fire retardant/resistant · CPC title

• C08L23/12

  Polypropene · CPC title

• C08K2003/323

  Ammonium polyphosphate · CPC title

• C08K3/32

  Phosphorus-containing compounds · CPC title

• C08G65/4006

  (I) or (II) containing elements other than carbon, oxygen, hydrogen or halogen as leaving group (X) · CPC title