Bed regeneration using low value steam

Patent metadata

Field	Value
Publication number	US-12544707-B2
Application number	US-202217647393-A
Country	US
Kind code	B2
Filing date	Jan 7, 2022
Priority date	Jan 22, 2021
Publication date	Feb 10, 2026
Grant date	Feb 10, 2026

Abstract

Systems and methods are provided for regenerating a bed containing absorbed and/or adsorbed CO 2 using a low value steam stream. The steam stream can have a pressure of 10 kPa-a to 50 kPa-a and a temperature of 46° C. to 81° C. The steam stream can be used to displace CO 2 from the bed, resulting in formation of a low pressure stream including water vapor and CO 2 . The stream containing water vapor and CO 2 is then passed through a liquid ring pump that includes an associated ring cooler. The ring pump provides the suction necessary to draw the low value steam stream through the bed to displace the CO 2 . Due to the nature of operation of the liquid ring pump, the majority of water in the steam containing H 2 O and CO 2 can be removed within the liquid ring pump, resulting in production of a stream comprising 90 vol % or more of CO 2 at a pressure of 90 kPa-a or more. An example of a bed that can be regenerated using a low value steam stream is a bed that corresponds to a liquid amine that is coated on/covering/impregnated into a porous solid, so that the liquid amine remains substantially in place during a cycle of sorption and desorption of CO 2 .

First claim

What is claimed is:

1 . A method for desorption of CO 2 from a sorbent bed, comprising:
exposing a steam stream comprising a steam pressure of 4 kPa to 50 kPa as a sweep gas to a sorbent bed comprising sorbed CO 2 and a first average sorbent bed temperature of 0° C. to 150° C. to form an exhaust stream comprising steam and at least a portion of the sorbed CO 2 , the steam stream comprising a temperature of 30° C. to 81° C. prior to entering the sorbent bed; and passing at least a portion of the exhaust stream through a liquid ring pump comprising an associated ring cooler to form a CO 2 -containing stream comprising 90 vol % or more CO 2 , and a liquid water stream, wherein the sorbent bed comprises an absorbent, the absorbent being infused or encapsulated on a solid surface, covering a solid surface, or a combination thereof, and wherein the absorbent infused or encapsulated on the solid surface, covering the solid surface, or a combination thereof, is in a liquid state.

2 . The method of claim 1 , wherein the steam stream comprises a total pressure of 4 kPa-a to 60 kPa-a, or wherein the steam stream comprises 95 vol % or more of steam, or a combination thereof.

3 . The method of claim 1 , wherein the CO 2 -containing stream comprises a pressure of 90 kPa-a or more.

4 . The method of claim 1 , wherein the liquid ring pump is operated at a pressure that is lower than the pressure of the steam stream by 1.0 kPa or more.

5 . The method of claim 1 , wherein the average sorbent bed temperature during exposing the steam stream to the sorbent bed is 50° C. to 150° C.

6 . The method of claim 1 , further comprising exposing an input stream comprising 0.01 vol % to 25 vol % CO 2 , relative to a volume of the input stream, to the sorbent bed at a second average sorbent bed temperature of 0° C. to 150° C. to adsorb CO 2 , absorb CO 2 , or a combination thereof, and to form a CO 2 -depleted stream comprising 10 mol % or less of the CO 2 from the input stream.

7 . The method of claim 6 , wherein exposing the input stream to the sorbent bed and exposing the steam stream to the sorbent bed comprise a cyclic process, and wherein exposing the steam stream to the sorbent bed comprises exposing the sorbent bed to a molar amount of steam comprising 1.0 times to 20.0 times a maximum CO 2 capacity of the sorbent bed.

8 . The method of claim 6 , wherein exposing the steam stream to the sorbent bed comprises exposing the sorbent bed to a molar amount of steam comprising 1.0 times to 20.0 times a molar amount of CO 2 that was sorbed by the sorbent bed during the exposing the sorbent bed to the input stream.

9 . The method of claim 6 , wherein the input stream comprises a combustion flue gas.

10 . The method of claim 6 , wherein the input stream comprises a flue gas from a combustion zone of a power plant, and wherein the steam stream comprises steam generated by heat exchange with at least a portion of the flue gas.

11 . The method of claim 1 , wherein the absorbent comprising a Performance Index of greater than 150 m −1 .

12 . The method of claim 1 , wherein the absorbent comprises a liquid amine.

13 . The method of claim 1 , wherein the solid surface comprises a surface area of 0.001 m 2 /g to 45 m 2 /g.

14 . The method of claim 1 , wherein the steam stream comprises steam generated by an exhaust of a standalone gas-fired steam turbine; or wherein the steam stream comprises steam generated by a boiler; or a combination thereof.

15 . A system for sorption and desorption of CO 2 using a sorbent bed, comprising:
a sorbent bed comprising a liquid amine absorbent infused or encapsulated on a solid surface, covering a solid surface, or a combination thereof, the sorbent bed comprising a first inlet, a steam inlet, a first outlet, and a desorption outlet; a combustion zone comprising a combustion outlet; a heat exchanger comprising a hot fluid inlet in fluid communication with the combustion outlet, a cooled fluid outlet, a water inlet, and a steam outlet, the first inlet of the sorbent bed being in fluid communication with the cooled fluid outlet, the steam inlet of the sorbent bed being in fluid communication with the steam outlet of the heat exchanger; and a liquid ring pump comprising an associated ring cooler in fluid communication with the desorption outlet, the liquid ring pump and associated ring cooler comprising a CO 2 outlet and a liquid water outlet.

16 . The system of claim 15 , wherein the absorbent comprises a Performance Index of greater than 150 m −1 .

17 . The system of claim 16 , wherein the solid surface comprises a surface area of 0.001 m 2 /g to 45 m 2 /g.

18 . The system of claim 15 , wherein the steam inlet of the sorbent bed being in indirect fluid communication with the steam outlet of the heat exchanger via one or more steam turbines.

Assignees

• Exxonmobil Technology & Engineering Company

Inventors

• Yeganeh Mohsen S
• Fulton Jr John W
• Narayanan Sundaresan
• Barckholtz Timothy A
• Weston Simon C

Classifications

• Y02C20/40

  of CO2 · CPC title

• F01K25/103

  Carbon dioxide (F01K25/065 takes precedence) · CPC title

• B01D2258/0283

  Flue gases · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D2252/204

  Amines · CPC title