Phase change system and phase change crucible for the separation of rare earth elements

Patent metadata

Field	Value
Publication number	US-12540371-B2
Application number	US-202217873898-A
Country	US
Kind code	B2
Filing date	Jul 26, 2022
Priority date	Jul 26, 2022
Publication date	Feb 3, 2026
Grant date	Feb 3, 2026

Abstract

A phase change crucible that includes an inner chamber comprising an inner chamber wall extending from an inner chamber floor to an inner chamber upper end, an outer chamber comprising an outer chamber wall extending from an outer chamber floor to an outer chamber upper end, wherein the inner chamber upper end terminates beyond the outer chamber upper end and the outer chamber wall encircles the inner chamber wall, an inner collection region formed by the inner chamber wall and the inner chamber floor, and an outer collection region formed by the outer chamber wall, the inner chamber wall, and the outer chamber floor.

First claim

What is claimed is:

1 . A method of separating rare earth elements, the method comprising
heating a composition comprising a first element and a second element in an inner chamber of a phase change crucible, wherein heating the composition phase separates the second element from the first element leaving a higher weight percentage of the first element in the inner chamber than was present in the composition and wherein the phase change crucible comprises:
the inner chamber comprising an inner chamber wall extending from an inner chamber floor to an inner chamber upper end;
an outer chamber comprising an outer chamber wall extending from an outer chamber floor to an outer chamber upper end, wherein the inner chamber upper end terminates beyond the outer chamber upper end and the outer chamber wall encircles the inner chamber wall;
an inner collection region formed by the inner chamber wall and the inner chamber floor, the inner collection region housing the composition; and
an outer collection region formed by the outer chamber wall, the inner chamber wall, and the outer chamber floor; and
collecting the second element on a collection substrate positioned above the inner chamber of the phase change crucible.

2 . The method of claim 1 , wherein the first element comprises a first rare earth element and the second element comprises a second rare earth element.

3 . The method of claim 2 , wherein the first rare earth element comprises lutetium and the second rare earth element comprises ytterbium.

4 . The method of claim 1 , wherein a baffle cap is removably positioned on the inner chamber covering the inner chamber floor, wherein the baffle cap comprises one or more openings and the baffle cap is configured to impede a line of sight between the composition disposed in the inner chamber of the phase change crucible and the collection substrate and provides a fluid pathway between the inner chamber floor and the collection substrate.

5 . The method of claim 1 , further comprising collecting a portion of the first element in the outer collection region of the phase change crucible.

6 . The method of claim 1 , wherein heating the composition comprises inductively heating the composition.

7 . The method of claim 1 , wherein heating the composition comprises retaining a temperature of the composition in a temperature range of from 400° C. to 2000° C. to leave a first element composition comprising a higher weight percentage of the first element than was present in the composition.

8 . The method of claim 1 , wherein when heating the composition, the phase change crucible is positioned in an inert or reduced pressure environment.

Assignees

• Shine Technologies Llc

Inventors

• Van Abel Eric
• Vaughan Tim
• Shackett Charles
• Childs Zach
• Underhill Shawn
• Szymski Matthew
• Kearney Kenny

Classifications

• B01D1/0023

  Induction heating · CPC title

• C22B59/00 Primary

  Obtaining rare earth metals · CPC title

• C22B9/02

  Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action {including acoustic waves; (C22B9/003, C22B9/006, C22B9/05, C22B9/22 take precedence)} · CPC title

• B01D7/00

  Sublimation (B01D8/00 takes precedence; freeze-drying F26) · CPC title