Method for sequestering CO2 from flue gas and preparing microfiber-reinforced cement

Patent metadata

Field	Value
Publication number	US-12528739-B2
Application number	US-202218060992-A
Country	US
Kind code	B2
Filing date	Dec 2, 2022
Priority date	Dec 3, 2021
Publication date	Jan 20, 2026
Grant date	Jan 20, 2026

Abstract

A method for sequestating carbon dioxide from flue gas by using a cement clinker. The products of this method can also be used to prepare microfiber-reinforced cement. The method of the present disclosure is capable of capturing and storing carbon dioxide in flue gas, such as cement kiln flue gas.

First claim

What is claimed is:

1 . A method for sequestrating carbon dioxide from a flue gas, the method comprising: reacting the flue gas with a cement clinker thereby sequestering at least a portion of the carbon dioxide from the flue gas in the cement clinker, wherein the flue gas comprises decomposition furnace flue gas, rotary kiln flue gas, cyclone preheater flue gas, or oxy-fuel combustion flue gas.

2 . The method of claim 1 , wherein the cement clinker is in the form of a powder.

3 . The method of claim 1 , wherein the step of reacting the flue gas and the cement clinker takes place in the presence of at least one of a reaction accelerator and a surfactant.

4 . The method of claim 3 , further comprising the step of mixing the reaction accelerator, the surfactant, and the cement clinker in water thereby forming a solid-liquid suspension slurry.

5 . The method of claim 1 further comprising the step of carrying out solid-liquid separation after the reaction between the flue gas and the solid-liquid suspension slurry thereby forming a solid and a liquid.

6 . The method of claim 5 further comprising the step of drying the solid to obtain a separated fibrous solid comprising calcium carbonate microfibers.

7 . The method of claim 3 , wherein the reaction accelerator comprises sodium ethylenediamine tetraacetate, polyvinyl alcohol, triethanolamine, or any combination thereof.

8 . The method of claim 3 , wherein the surfactant comprises sodium carboxymethyl cellulose, amino acid phosphate, soluble magnesium salt, magnesium hydroxide, phosphoric acid, soluble phosphate, soluble aluminum salt, or any combination thereof.

9 . The method of claim 1 , wherein the cement clinker is a Portland cement clinker.

10 . The method of claim 1 , wherein the cement clinker comprises Ca 3 SiO 5 , Ca 2 SiO 4 , Ca 3 Al 2 O 6 , and Ca 4 Al 2 Fe 2 O 10 .

11 . The method of claim 3 , wherein the powder has at least one of an average particle size of less than 0.075 mm, or has a specific surface area of at least 200 m 2 /kg.

12 . The method of claim 1 , wherein the solid-liquid suspension slurry is prepared by mixing the cement clinker with an aqueous solution comprising the reaction accelerator and the surfactant.

13 . The method of claim 4 , wherein the mass ratio of the cement clinker to the water in the solid-liquid suspension slurry is from 1:5 to 1:100.

14 . The method of claim 1 , wherein the solid-liquid suspension slurry is at least one of heated to 45° C.-100° C. and exposed to a pressure of to 0-2 atmosphere.

15 . The method of claim 1 , wherein the concentration of carbon dioxide in the flue gas is at least 5%; and the concentrations of NO x and SO 2 are optionally not higher than 400 mg/m 3 and 200 mg/m 3 , respectively.

16 . A method for preparing a microfiber-reinforced cement, comprising mixing the separated fibrous solid of claim 6 with gypsum and a mineral admixture comprising one or more of silica fume, fly ash, slag, metakaolin, and ground limestone powder.

17 . A microfiber-reinforced cement prepared according to the method of claim 16 .

18 . The microfiber-reinforced cement of claim 17 , wherein the microfiber-reinforced cement comprises the separated fibrous solid in an amount of 2-20% by weight of the microfiber-reinforced cement, the cement clinker in an amount of 50-90% by weight of the microfiber-reinforced cement, the gypsum in an amount of 1-3% by weight of the microfiber-reinforced cement, and the mineral admixture in an amount of 5-40% by weight of the microfiber-reinforced cement.

Assignees

• Univ Hong Kong Polytechnic

Inventors

• Shen Peiliang
• Lu Jianxin
• Xuan Dongxing
• Poon Chi-Sun

Classifications

• C04B14/46

  Rock wool {; Ceramic or silicate fibres (C04B14/40, C04B14/42 take precedence)} · CPC title

• C04B18/08

  Flue dust {, i.e. fly ash} · CPC title

• C04B28/14

  containing calcium sulfate cements {(gypsum-paper plates E04C)} · CPC title

• C04B14/28

  of calcium · CPC title

• C04B7/48

  Clinker treatment (C04B7/47 takes precedence) · CPC title