Metal foam gas diffusion layers and polymer-electrolyte-membrane fuel cells with metal foam gas diffusion layers

Patent metadata

Field	Value
Publication number	US-12525617-B2
Application number	US-202217960243-A
Country	US
Kind code	B2
Filing date	Oct 5, 2022
Priority date	Apr 21, 2022
Publication date	Jan 13, 2026
Grant date	Jan 13, 2026

Abstract

A bipolar plate-gas diffusion layer (GDL) assembly for a polymer-electrolyte-membrane fuel cell includes a flat metallic bipolar plate and a porous metal GDL adjacent to and in direct contact with the flat metallic bipolar plate. The porous metal GDL includes flow channels defined by flow channel walls with flow channel surfaces. The flow channel walls and flow channel surfaces have an average porosity generally equal to an average porosity of an interior of the porous metal GDL.

First claim

What is claimed is:

1 . A bipolar plate-gas diffusion layer (GDL) assembly for a polymer-electrolyte-membrane fuel cell, the bipolar plate-gas diffusion layer (GDL) assembly comprising:
a flat metallic bipolar plate; and a porous metal foam GDL adjacent to and in direct contact with the flat metallic bipolar plate, the porous metal foam GDL comprising flow channels defined by flow channel walls and flow channel surfaces formed by CNC machining, laser machining or electrical discharge machining such that the flow channel walls and the flow channel surfaces have an average porosity generally equal to an average porosity of an interior of the porous metal foam GDL.

2 . The bipolar plate-GDL assembly according to claim 1 , wherein the flow channels are hollow flow channels.

3 . The bipolar plate-GDL assembly according to claim 1 , wherein the flow channel surfaces of the flow channel walls are hydrophilic with a contact angle between water droplets and the flow channel surfaces of the flow channel walls between about 60° and about 90°.

4 . The bipolar plate-GDL assembly according to claim 1 , wherein the porous metal GDL is formed from at least one of titanium, titanium alloy, iron, steel, stainless steel, nickel, a nickel alloy, aluminum, an aluminum alloy, copper, and a copper alloy.

5 . The bipolar plate-GDL assembly according to claim 1 , wherein the average porosity of the porous metal GDL is between about 65% and 85%.

6 . The bipolar plate-GDL assembly according to claim 1 , wherein the flow channels are formed by the laser machining such that the flow channel walls and the flow channel surfaces have the average porosity generally equal to the average porosity of the interior of the porous metal foam GDL.

7 . The bipolar plate-GDL assembly according to claim 1 , wherein the flow channels are formed by the CNC machining such that the flow channel walls and the flow channel surfaces have the average porosity generally equal to the average porosity of the interior of the porous metal foam GDL.

8 . The bipolar plate-GDL assembly according to claim 1 , wherein the flow channels are formed by the electrical discharge machining such that the flow channel walls and the flow channel surfaces have the average porosity generally equal to the average porosity of the interior of the porous metal foam GDL.

9 . The bipolar plate-GDL assembly according to claim 1 , wherein the porous metal GDL has a thickness between about 50 μm and 600 μm.

10 . The bipolar plate-GDL assembly according to claim 9 , wherein the flow channels have a width between about 0.3 mm and about 1.5 mm.

11 . The bipolar plate-GDL assembly according to claim 10 , wherein the flow channels have a depth between about 20 μm and about 300 μm.

12 . A polymer-electrolyte-membrane fuel cell comprising:
an anode; a membrane electrode assembly comprising a membrane, an anode catalyst layer, and a cathode catalyst layer; a porous metal foam gas diffusion layer (GDL) comprising an average porosity and flow channels defined by flow channel walls and flow channel surfaces; and a flat bipolar plate adjacent to and in direct contact with the porous metal foam GDL, wherein the flow channel walls and the flow channel surfaces formed by CNC machining, laser machining or electrical discharge machining such that the flow channel walls and the flow channel surfaces have an average porosity generally equal to the average porosity of an interior of the porous metal GDL.

13 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the flow channels are hollow flow channels.

14 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the flow channel surfaces of the flow channel walls are hydrophilic.

15 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the porous metal GDL is formed from at least one of titanium, titanium alloy, iron, steel, stainless steel, nickel, a nickel alloy, aluminum, an aluminum alloy, copper, and a copper alloy.

16 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the average porosity of the porous metal GDL is between about 65% and 85%.

17 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the flow channels are formed by the laser machining such that the flow channel walls and the flow channel surfaces have the average porosity generally equal to the average porosity of the interior of the porous metal foam GDL.

18 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the flow channels are formed by the CNC machining such that the flow channel walls and the flow channel surfaces have the average porosity generally equal to the average porosity of the interior of the porous metal foam GDL.

19 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the flow channels are formed by electrical discharge machining such that the flow channel walls and the flow channel surfaces have the average porosity generally equal to the average porosity of the interior of the porous metal foam GDL.

20 . The polymer-electrolyte-membrane fuel cell according to claim 12 , wherein the porous metal GDL has at least one of:
a thickness between about 50 μm and 600 μm; a width between about 0.3 mm and about 1.5 mm; and a depth between about 20 μm and about 300 μm.

Assignees

• Toyota Eng & Mfg North America
• Toyota Motor Co Ltd

Inventors

• Zhu Gaohua
• Wang Liang
• Zhou Yuqing
• Banerjee Debasish
• Jia Hongfei
• Dede Ercan Mehmet
• Kawai Hiroyuki
• Ando Masaki

Classifications

• H01M8/0258

  characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant · CPC title

• H01M8/0206

  Metals or alloys · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/1004 Primary

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title

• Y02E60/50

  Fuel cells · CPC title