Spinning and weaving method for making antimicrobial cotton

Patent metadata

Field	Value
Publication number	US-12509817-B2
Application number	US-202418802362-A
Country	US
Kind code	B2
Filing date	Aug 13, 2024
Priority date	Oct 16, 2018
Publication date	Dec 30, 2025
Grant date	Dec 30, 2025

Abstract

A method of making an antimicrobial textile comprising TiO2 nanoparticles is described. The TiO2 nanoparticles are immobilized by first treating a textile with a base, and then contacting with TiO2 nanoparticles in a solution of an alcohol and acid. The textile may be subsequently irradiated with UV light prior to use. The antimicrobial textile shows high effectiveness against the growth and proliferation of microorganisms transmitted within indoor environments.

First claim

The invention claimed is:

1 . Spinning and weaving method for making an antimicrobial cotton textile, the method comprising:
spinning cotton fibers to form filaments, weaving the filaments to form a cotton textile material; treating the cotton textile material with an inorganic base to produce a treated cotton textile material; rinsing the treated cotton textile material to produce a rinsed cotton textile; depositing a TiO 2 coating composition onto the rinsed cotton textile, wherein the TiO 2 coating composition contains TiO 2 nanoparticles, methanol, and an organic acid, and the depositing forms a coated textile, wherein the TiO 2 coating composition fully coats the rinsed cotton textile during the depositing; and irradiating the coated textile with a UV light to form the antimicrobial cotton textile, wherein the irradiating forms hydrogen bonds between the TiO 2 nanoparticles and surfaces of individual fibrils of the cotton textile, wherein the TiO 2 coating composition contains the TiO 2 nanoparticles at a concentration of 10-100 ppm by weight, and the TiO 2 nanoparticles are anatase TiO 2 nanoparticles having an average particle diameter of less than 21 nm.

2 . The method of claim 1 , wherein the TiO 2 coating composition contains 60-90 wt % of the organic acid and 10-40 wt % of the methanol relative to a total weight of the TiO 2 coating composition.

3 . The method of claim 1 , wherein the rinsed cotton textile and the TiO 2 nanoparticles are not contacted with a binding agent, and the TiO 2 coating composition does not comprise a binding agent.

4 . The method of claim 1 , wherein the antimicrobial cotton textile contains the TiO 2 nanoparticles at a weight percentage of 0.01-2.00 wt % relative to a total weight of the antimicrobial textile.

5 . The method of claim 1 , wherein the cotton textile material consists essentially of cotton fiber.

6 . The method of claim 1 , wherein the antimicrobial cotton textile comprises fibers having a surface area in which 15-40% of the surface area is covered by TiO 2 nanoparticles.

7 . The method of claim 1 , wherein the antimicrobial cotton textile has an antimicrobial activity at least 100 times greater than a second cotton textile that was treated with an essentially identical method that did not have TiO 2 nanoparticles, when the antimicrobial textile and the second textile are contacted with similar bacteria and/or fungal cells and a growth medium.

8 . The method of claim 7 , wherein the antimicrobial cotton textile and the second cotton textile are contacted with similar bacteria, which are gram-positive cocci.

9 . The method of claim 7 , wherein the antimicrobial cotton textile and the second cotton textile are contacted with similar fungal cells, which are yeast cells.

10 . The method of claim 1 , wherein the antimicrobial cotton textile is a component of a bandage, a cast, a gown, a lab coat, a mask, a shoe covering, a face covering, a curtain, a bedcovering, a carpeting, and/or a head covering.

Assignees

• Univ Imam Abdulrahman Bin Faisal

Inventors

• Salama Khaled
• Al Jindan Reem Y

Classifications

• D06M13/188

  Monocarboxylic acids; Anhydrides, halides or salts thereof {(D06M13/1845 takes precedence)} · CPC title

• D06M10/08

  Organic compounds · CPC title

• D06M10/06

  Inorganic compounds or elements · CPC title

• D06M10/001

  Treatment with visible light, infrared or ultraviolet, X-rays · CPC title

• D06M2101/06

  cellulosic · CPC title